Fibers and Polymers

The Korean Fiber Society (한국섬유공학회)
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Copolymerization of 4′-vinylbenzo-15-crown-5 with Di(ethylene glycol) Ethyl Ether Acrylate

  • Jin, Long Yi (Department of Textile Engineering, Inha University) ;
  • Mah, Soukil (Department of Textile Engineering, Inha University)
  • Published : 2002.06.01
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Abstract

Radical copolymerization behavior of 4'-vinylbenzo-15-crown-5, a vinyl monomer having a pendant 15-membared crown ether unit (VCE) with di(ethylene glycol) ethyl ether acrylate (DEGEEA) was carried out in toluene solution using 2,2-azobisisobutyronitrile (AIBN) as an initiator. The copolymers were characterized by means of FT-IR, $^1{H-NMR}$, and $^{13}{C-NMR}$ . The reactivity ratio of VCE and DEGEEA, determined by Fineman-Ross and Kelen-Tudos method, gave values 0.55 for VCE, and 0.11 for DEGEEA respectively.

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References

  1. E. Blasius, K. P. Janzen, W. Klein, H. Klotz, V. B. Nguyen, T. Nguyen-Tien, R. Pfeiffer, G. Scholten, H. Simon, H. Stockemer, and A. Toussaint, J. Chromatogr., 201, 127 (1980)2. E. Blas
  2. E. Blasius and P. G. Maurer, Makromol. Chem., 178, 649 (1977) https://doi.org/10.1002/macp.1977.021780302
  3. E. Blasius, K. P. Janzen, M. Keller, H. Lander, T. Nguyen-Tien, and G. Scholten, Talanta, 27, 107 (1980) https://doi.org/10.1016/0039-9140(80)80026-9
  4. E. Blasius, K. P. Janzen, W. Adrian, W. Klein, H. Klotz, H. Luxenburger, E. Memke, V. B. Nguyen, T. Nguyen-Tien, R. Rausch, J. Stockemer, and A. Toussaint, Talanta, 27, 127(1980) https://doi.org/10.1016/0039-9140(80)80027-0
  5. S. K-opolow, T. E. Hogen Esch, and J. Smid, Macromolecules,6,133(1973) https://doi.org/10.1021/ma60031a021
  6. G. Manecke and P. Reuter, Makromol. Chem., 182, 1973(1981) https://doi.org/10.1002/macp.1981.021820710
  7. S. Kopolow, T. E. Hogen Esch, and J. Smid, Macromolecules, 4, 359 (1971) https://doi.org/10.1021/ma60021a024
  8. T. Maeda, K. Kimura, and T. Shono, BuII. Chem. Soc.Jpn., 55, 3506 (1982) https://doi.org/10.1246/bcsj.55.3506
  9. K. Kimura, H. Tamura, T. Maeda, and T. Shono, Polym. Bull., 1, 403 (1979) https://doi.org/10.1007/BF00284410
  10. Y. Delaviz and H. W. Gibson, Macromolecules, 25, 18(1992) https://doi.org/10.1021/ma00027a004
  11. U. Tunca and Y. Yagci, Prog. Polym. Sci., 19, 233 (1994) https://doi.org/10.1016/0079-6700(94)90007-8
  12. N. Yamaguchi and H. W. Gibson, Macromol. Chem. Phys., 201, 815 (2000) https://doi.org/10.1002/(SICI)1521-3935(20000401)201:7<815::AID-MACP815>3.0.CO;2-#
  13. K. L. Thunhorst, R. D. Noble, and C. N. Bowman, J. Membrane. Sci., 156, 293 (1999) https://doi.org/10.1016/S0376-7388(98)00358-5
  14. C. J. Pedersen, J. Am. Chem. Soc., 89, 7017 (1967) https://doi.org/10.1021/ja01002a035
  15. T. Ando, T. S. Kwon, A. Kitagawa, T. Tanemura, S. Kondo, H. Kunisada, and Y. Yuki, Macromol. Chem Phys., 197, 2803 (1996)
  16. W. Parish and P. Stott, J. Org. Chem., 43,4577 (1978) https://doi.org/10.1021/jo00418a006
  17. M. Fineman and S. D. Ross, J. Polym. Sci., 5, 259 (1950) https://doi.org/10.1002/pol.1950.120050210
  18. G. Odian, 'Principles of Poly-nerizatioa', pp.467-470, Wiley & Sons Inc., New York, 1991
  19. C. W. Pyun, J. Polym. Sci., Part A-2, Polym. Phys., 8, 1111 (1970) https://doi.org/10.1002/pol.1970.160080707