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Copolymerization of 4′-vinylbenzo-15-crown-5 with Di(ethylene glycol) Ethyl Ether Acrylate  

Jin, Long Yi (Department of Textile Engineering, Inha University)
Mah, Soukil (Department of Textile Engineering, Inha University)
Publication Information
Fibers and Polymers / v.3, no.2, 2002 , pp. 49-54 More about this Journal
Abstract
Radical copolymerization behavior of 4'-vinylbenzo-15-crown-5, a vinyl monomer having a pendant 15-membared crown ether unit (VCE) with di(ethylene glycol) ethyl ether acrylate (DEGEEA) was carried out in toluene solution using 2,2-azobisisobutyronitrile (AIBN) as an initiator. The copolymers were characterized by means of FT-IR, $^1{H-NMR}$, and $^{13}{C-NMR}$ . The reactivity ratio of VCE and DEGEEA, determined by Fineman-Ross and Kelen-Tudos method, gave values 0.55 for VCE, and 0.11 for DEGEEA respectively.
Keywords
radical polymerization; Vinyl crown ether; Di(ethylene glycol) ethyl ether acrylate; Complex; Reactivity ratio;
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