• Title/Summary/Keyword: R- phase

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The Relation between the Phase-Shift Profile for the Intermediate Frequencies and the Langmuir Adsorption Isotherm (중간주파수에서 위상이동 변화와 Langmuir흡착등온식 사이의 관계)

  • Chun Jang Ho;Mun Kyeong Hyeon;Cho Chong Dug
    • Journal of the Korean Electrochemical Society
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    • v.3 no.1
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    • pp.25-30
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    • 2000
  • The relation between the phase-shift profile for the intermediate frequencies and the Langmuir adsorption isotherm at the poly-$Pt/0.1\;M\;H_2SO_4$ aqueous electrolyte interface has been studied using ac impedance measurements, i.e., the phase-shift methods. The suggested interfacial equivalent circuit consists of the serial connection of the electrolyte resistance ($R_S$), the faradaic resistance $(R_F)$ and the equivalent circuit element $(C_P)$ of the adsorption pseudocapacitance $(C_\varphi)$. The delayed phase shift $(\varphi)$ depends on both the cathode potential (E) and frequency (f), and is given by $\varphi=-tan^{-1}[1/2{\pi}f(R_s+R_F)C_p]$. The phase-shift profile $(\varphi\;vs.\;E)$ for the intermediate frequency (ca. 6Hz) can be used as an experimental method to determine the Langmuir adsorption isotherm (9 vs. E). The equilibrium constant (K) for H adsorption and the standard free energy $({\Delta}G_{ads})$ of H adsorption at the poly-$Pt/0.1\;M\;H_2SO_4$ electrolyte interface are $1.8\times10^{-4}\;and\;21.4kJ/mol$, respectively. The H adsorption is attributed to the over-potentially deposited hydrogen (OPD H).

Two-phase Flow Characteristics of Refrigerant in T-branch with Horizontal and Vertical Inlet Tube (T형 수평 및 수직 입구 분지관 내 냉매 2상 유동 특성)

  • 태상진;조금남
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.14 no.9
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    • pp.741-748
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    • 2002
  • The present study investigated the two-phase flow characteristics of refrigerant R-22 in T-branch with horizontal and vertical inlet tube The key experimental parameters were the orientation of inlet and branch tubes (horizontal and vertical), diameter ratio of branch tube to inlet tube (1 and 0.61), inlet mass flux (200~500 kg/$m^2$s) and inlet quality (0.1~0.4). Predicted pressure profile agreed with the measured data within 25.4%. The flow distribution ratio decreased as the mass flux increased. The flow distribution ratio decreased by 12~25% as the tube diameter ratio decreased from 1 to 0.61, and decreased by 38~47% as the orientation of branch changed from horizontal to vertical upward for horizontal inlet tubes. As the orientation of inlet tube changed from horizontal to vertical upward for horizontal branch, the flow distribution ratio increased by 15~68%, but the quality in the branch tube decreased by 28~92% due to phase separation.

A Study on Motion of Single Ball with Low Reynolds Number at Performed Interface Layers (액상 계면층을 이용한 저 레이놀즈수 단일강구의 운동연구)

  • 김시영
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.23 no.3
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    • pp.117-126
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    • 1987
  • The author has analysed profile of flow in rear of motion with single ball with low Reynolds number performed interface layers. For each system whose viscosity of the lower phase is as large as or large that of the upper phase, the profile has based on the thickness of the ball in the lower phase is nearly independent of both the ball single and the physical properties of the upper phase of the solution. The examine of the characteristics between Darwin's total displacement of the fluid and data obtained in this study, the averaged volume of each cases was corrected by the viscosity in the lower phase. When the viscosity in the lower phase is less than that of the upper phase, the volume based on the displacement of the fluid in rear region of ball are influenced by both ball size and the viscosity ratio of the upper phase to the lower phase. In the range of the Reynolds number less than a constant values, the volume ratio is influenced by both Reynolds number and Moltion number but mainly Reynolds. In range of Reynolds number over than the value, the volume ratio is independent of Reynolds number, but influenced by Moltion number.

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The Study on Phase Transition Pressure of Donor doped Pb(Zr0.52Ti0.48)O3 Ceramics with Diamond Anvil Cell (다이아몬드 엔빌 셀을 이용한 Donor doped Pb(Zr0.52Ti0.48)O3 세라믹스의 상전이 압력 연구)

  • Cho, Kyung-Ho;Ko, Young-Ho;Seo, Chang-Eui;Kim, Kwang-Joo
    • Journal of the Korean Ceramic Society
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    • v.48 no.5
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    • pp.471-478
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    • 2011
  • Investigations of crystal structure and phase transition of $Pb(Zr_{0.52}Ti_{0.48})O_3$ ceramics doped with A-site substitution impurity (La, Nd) or B-site substitution impurity (Sb, Nb) at 2 mol% concentration were carried out. X-ray diffraction patterns of impurities doped $Pb(Zr_{0.52}Ti_{0.48})O_3$ ceramics have been measured at pressures up to ~5 GPa with diamond anvil cell and synchrotron radiation. The patterns were obtained at room temperature using methanol-ethanol mixture as pressure-transmitting media. In order to refine the crystal structure, Rietveld analysis has been performed. The structures of impurities doped $Pb(Zr_{0.52}Ti_{0.48})O_3$ ceramics are tetragonal in space group P4mm at ambient pressure and are transformed into a cubic phase in space group Pm$\bar{3}$m as the pressure increases. In this study, when A-site substitution donor $La^{3+}$ or $Nd^{3+}$ ion was added to $Pb(Zr_{0.52}Ti_{0.48})O_3$ ceramics, the phase transition phenomena showed up at the pressure of 2.5~4.6 GPa, but when B-site substitution donor $Nb^{5+}$ or $Sb^{5+}$ ion was added to it, the phase transition appeared at relatively lower pressure of 1.7~2.6 GPa.

An R package UnifiedDoseFinding for continuous and ordinal outcomes in Phase I dose-finding trials

  • Pan, Haitao;Mu, Rongji;Hsu, Chia-Wei;Zhou, Shouhao
    • Communications for Statistical Applications and Methods
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    • v.29 no.4
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    • pp.421-439
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    • 2022
  • Phase I dose-finding trials are essential in drug development. By finding the maximum tolerated dose (MTD) of a new drug or treatment, a Phase I trial establishes the recommended doses for later-phase testing. The primary toxicity endpoint of interest is often a binary variable, which describes an event of a patient who experiences dose-limiting toxicity. However, there is a growing interest in dose-finding studies regarding non-binary outcomes, defined by either the weighted sum of rates of various toxicity grades or a continuous outcome. Although several novel methods have been proposed in the literature, accessible software is still lacking to implement these methods. This study introduces a newly developed R package, UnifiedDoseFinding, which implements three phase I dose-finding methods with non-binary outcomes (Quasi- and Robust Quasi-CRM designs by Yuan et al. (2007) and Pan et al. (2014), gBOIN design by Mu et al. (2019), and by a method by Ivanova and Kim (2009)). For each of the methods, UnifiedDoseFinding provides corresponding functions that begin with next that determines the dose for the next cohort of patients, select, which selects the MTD defined by the non-binary toxicity endpoint when the trial is completed, and get oc, which obtains the operating characteristics. Three real examples are provided to help practitioners use these methods. The R package UnifiedDoseFinding, which is accessible in R CRAN, provides a user-friendly tool to facilitate the implementation of innovative dose-finding studies with nonbinary outcomes.

The in-control performance of the CCC-r chart with estimated parameters (추정된 모수를 사용한 CCC-r 관리도에서 관리상태의 성능)

  • Kim, Jaeyeon;Kim, Minji;Lee, Jaeheon
    • The Korean Journal of Applied Statistics
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    • v.31 no.4
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    • pp.485-495
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    • 2018
  • The CCC-r chart is more effective than traditional attribute control charts for monitoring high-quality processes. In-control process parameters are typically unknown and should be estimated when implementing a CCC-r chart. Phase II control chart performance can deteriorate due to the effect of the estimation error. In this paper, we used the standard deviation of average run length (ARL) as well as the average of ARL to quantify the between-practitioner variability in the CCC-r chart performance. The results indicate that the CCC-r chart requires larger Phase I data than previously recommended in the literature in order to have consistent chart in-control performance among practitioners.

A Study on Low Noise Frequency Synthesizer Design with Compact Size for Multi-Band (소형 다대역 저잡음 주파수 합성기 설계에 관한 연구)

  • Kim, Taeyoung;Han, Jonghoon
    • Journal of the Korea Institute of Military Science and Technology
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    • v.20 no.5
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    • pp.673-680
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    • 2017
  • In the proposed paper, we designed low noise frequency synthesizer with compact size for Multi-Band. The proposed frequency synthesizer consists of fundamental frequency band(2 GHz) and harmonic frequency band(4 GHz). To improve the phase noise and spurious level of frequency synthesizer, we analyze how the configuration of frequency synthesizer affect the phase noise and design the multi-band's structure. The implemented frequency synthesizer reduce both the phase noise and spurious level. The phase noise is -92.17 dBc/Hz at 1 kHz frequency offset in 2 GHz and -90.50 dBc/Hz at 1 kHz frequency offset in 4 GHz. All spurious signals including fundamental frequency are suppressed at least 20 dBc than the second harmonic frequency.

Phase Characteristics of Approximated Head-related Transfer Functions(HRTFS) Using IIR Filters on the Sound Localization

  • Kanazawa, Kenichi;Hasegawa, Hiroshi;Kasuga, Masao;Matsumoto, Shuichi;Koike, Atsushi;Yamamoto, Hideo
    • Proceedings of the IEEK Conference
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    • 2000.07a
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    • pp.237-240
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    • 2000
  • We have proposed a simple method based on IIR filters for realizing sound image localization. How-ever the nonlinearity of phase characteristics of the IIR filters, which are used for sound image localization, cause decrease of the localization accuracy. In this paper we investigate the influence of phase characteristics on the sound localization. Head-related transfer functions (HRTFs) of a dummy-head are approximated by the IIR filter. We carried out sound image localization experiment with 2-loudspeaker reproduction using the approximated HRTFs. Then the errors which obtained from experiments were compared with the theoretical values which were estimated from the phase shifts of the IIR filters. As a result there was little influence of the nonlinear phase characteristics of the IIR fitters in the localization on the horizontal plane.

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A NOVEL ANTI-MICROBIAL COLLOIDAL SILVER SYSTEM AND ITS APPLICATION FOR COSMETICS

  • Kim, Jin-Woong;Kim, Su-Jin;Han, Sang-Hoon;Chang, Ih-Seop;Kang, Hak-Hee;Lee, Ok-Sub
    • Proceedings of the SCSK Conference
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    • 2003.09a
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    • pp.686-697
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    • 2003
  • A new colloidal silver (Ag) system is present in which a fine colloidal Ag is in situ deposited onto functionalized porous poly (ethylene glycol dimethacrylate) (poly (EGDMA)) microspheres. The effectiveness of Ag deposition was investigated considering the surface characteristics of poly (EGDMA) microspheres. The result reported in this study illustrates that the control of surface area and surface functionality (in this study, a hydroxyl group) of poly (EGDMA) microspheres is an important factor that determines practically the degree of deposition of colloidal Ag. The x-ray analysis showed that Ag nanoparticles were dispersed evenly inner and outer surfaces and had a face center cubic (fee) phase. In the preservative efficacy test, the Ag-containing poly (EGDMA) microspheres had a powerful anti-bacterial activity, showing a high potential for a new preservative in cosmetic industry.

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OLED display manufacturing by Organic Vapor Phase Deposition

  • Marheineke, B.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1676-1681
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    • 2006
  • We report on Organic Vapor Phase Deposition $(OVPD^{(R)})$ an innovative deposition technology for organic light emitting device (OLED) and organic semiconductor manufacturing. The combination of $OVPD^{(R)}$ with Close Coupled Showerhead (CCS) technology results in manufacturing equipment with vast potential for cost effective manufacturing of OLED displays commercially competitive to LCD. The actual $OVPD^{(R)}$ equipment concept and design is discussed: Computational Fluid Dynamic (CFD) modeling is compared with experimental results proving the excellent controllability of the deposition process. Further other production relevant deposition properties are being reviewed e.g. high deposition rates and high organic material utilization efficiency of the $OVPD^{(R)}$ - Technology. Data from devices made by $OVPD^{(R)}$ show comparable/ superior performance to those fabricated with conventional vacuum thermal evaporation (VTE) techniques. An outlook on further potentials of $OVPD^{(R)}$ with respect to enabling advanced organic device structures is given.

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