• Title/Summary/Keyword: R/C structure

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Association of MC4R Gene Polymorphisms with Growth and Body Composition Traits in Chicken

  • Li, Chun-Yu;Li, Hui
    • Asian-Australasian Journal of Animal Sciences
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    • v.19 no.6
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    • pp.763-768
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    • 2006
  • Genetic and pharmacological studies in mice have demonstrated a complementary role for the melanocortin 4 receptor (MC4R) in the control of food intake, energy balance and body weight. This study was designed to investigate the associations of a MC4R gene polymorphism on chicken growth and body composition traits in broiler lines divergently selected for abdominal fat. A SNP (G54C) was found in CDS region of chicken MC4R gene. The analysis of the least squares and variance revealed a significant association between the G54C SNP and BW, CW and SL at 7 wk of age, and there were significant differences in different genotypes (p<0.05). The results from protein secondary structure prediction and tertiary structure prediction showed that it appeared a helix in $13^{th}$ amino acid and two strands at $14^{th}$ and $15^{th}$ amino acid in mutant protein, respectively. It maybe induce the change of the activity or function of MC4R gene in poultry.

REAL HYPERSURFACES OF THE JACOBI OPERATOR WITH RESPECT TO THE STRUCTURE VECTOR FIELD IN A COMPLEX SPACE FORM

  • AHN, SEONG-SOO
    • Bulletin of the Korean Mathematical Society
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    • v.42 no.2
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    • pp.279-294
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    • 2005
  • We study a real hypersurface M satisfying $L_{\xi}S=0\;and\;R_{\xi}S=SR_{\xi}$ in a complex hyperbolic space $H_n\mathbb{C}$, where S is the Ricci tensor of type (1,1) on M, $L_{\xi}\;and\;R_{\xi}$ denotes the operator of the Lie derivative and the Jacobi operator with respect to the structure vector field e respectively.

Nanofibers Comprising Mo2C/Mo2N Nanoparticles and Reduced Graphene Oxide as Functional Interlayers for Lithium-Sulfur Batteries (Mo2C/Mo2N 나노 입자와 환원된 그래핀 옥사이드가 복합된 나노 섬유 중간층이 적용된 리튬-황 전지)

  • Lee, Jae Seob;Yang, Ji Hoon;Cho, Jung Sang
    • Korean Chemical Engineering Research
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    • v.60 no.4
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    • pp.574-581
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    • 2022
  • Nanofibers comprising reduced graphene oxide (rGO) and Mo2C/Mo2N nanoparticles (Mo2C/Mo2N rGO NFs) were prepared for a functional interlayer of Li-S batteries (LSBs). The well-dispersed Mo2C and Mo2N nanoparticles in the nanofiber structure served as active polar sites for efficient immobilization of dissolved lithium polysulfide. The rGO nanosheets in the structure also provide conductive channels for fast ion/electron transport during charging-discharging and ensured reuse of lithium polysulfide during redox reactions through a fast charge transfer process. As a result, the cell assembled with Mo2C/Mo2N rGO NFs-coated separator and pure sulfur electrode (70 wt% of sulfur content and 2.1 mg cm-2 of sulfur loading) showed a stable discharge capacity of 476 mA h g-1 after 400 charge-discharge cycles at 0.1 C. Furthermore, it exhibited a discharge capacity of 574 mA h g-1 even at a high current density of 1.0 C. Therefore, we believe that the proposed unique nanostructure synthesis strategy could provide new insights into the development of sustainable and highly conductive polar materials as functional interlayers for high performance LSBs.

Synthesis and Cation Binding Properties of Triester Calix[4]arenes and Calix[4]quinones

  • 남계천;강성옥;전종철
    • Bulletin of the Korean Chemical Society
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    • v.18 no.10
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    • pp.1050-1052
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    • 1997
  • The complexes M(CO)4-1,2-(PPh2)2-1,2-C2B10H10 (M=Cr 2a, Mo 2b, W 2c) have been prepared in good yields from readily available bis-diphenylphosphino-o-carboranyl ligand, closo-1,2-(PPh2)2-1,2-C2B10H10 (1), by direct reaction with Group Ⅵ metal carbonyls. The infrared spectra of the complexes indicate that there is an octahedral disposition of chelate bis-diphenylphosphino-o-carboranyl ligand around the metal atom. The crystal structure of 2a was determined by X-ray diffraction. Complex 2a crystallizes in the monoclinic space group P21/n with cell parameters a = 12.2360(7), b = 17.156(1), c = 16.2040(6) Å, V = 3354.1(3) Å3, and Z =4. Of the reflections measured a total of 2514 unique reflections with F2 > 3σ(F2) was used during subsequent structure refinement. Refinement converged to R1 = 0.066 and R2 = 0.071. Structural studies showed that the chromium atom had a slightly distorted pseudo-octahedral configuration about the metal center with two phosphine groups of o-carborane occupying the equatorial plane cis-orientation to each other. These metal carbonyl complexes are rapidly converted to the corresponding metal carbene complexes, [(CO)3M=C(OCH3)(CH3)]-1,2-(PPh2)2-1,2-C2B10H10 (M= Cr 3a, Mo 3b, W 3c), via alkylation with methyllithium followed by O-methylation with CF3SO3CH3.

Charge Neutral Quasi-Free-Standing Graphene on 6H-SiC(0001) Surface by Pd Silicidation and Intercalation

  • Song, In-Gyeong;Sin, Ha-Cheol;Park, Jong-Yun;An, Jong-Ryeol
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.128-128
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    • 2012
  • We investigated the atomic and electronic properties of graphene grown by Pd silicidation and intercalation using LEED, STM, and ARPES. Pd was deposited on the 6H-SiC(0001) surface at RT. The formation of Pd silicide gives rise to breaking of Si-C bonds of the SiC crystal, which enables to release C atoms at low temperature. The C atoms are transformed into graphene from $860^{\circ}C$ according to the LEED patterns as a function of annealing temperature. Even though the graphene spots were observed in the LEED pattern and the Fourier transformed STM images after annealing at $870^{\circ}C$, the topography images showed various superstructures so that graphene is covered with Pd silicide residue. After annealing at $950^{\circ}C$, monolayer graphene was revealed at the surface. The growth of graphene is not limited by surface obstacles such as steps and defects. In addition, we observed that six protrusions consisting of the honeycomb network of graphene has same intensity meaning non-broken AB-symmetry of graphene. The ARPES results in the vicinity of K point showed the non-doped linear ${\pi}$ band structure indicating monolayer graphene decoupled from the SiC substrate electronically. Note that the charge neutrality of graphene grown by Pd silicidation and intercalation was sustained regardless of annealing temperature in contrast with quasi-free- standing graphene induced by H and Au intercalation. Further annealing above $1,000^{\circ}C$ accelerates sublimation of the Pd silicide layer underneath graphene. This results in appearance of the $(6r3x6r3)R30^{\circ}$ structure and dissolution of the ${\pi}$ bands for quasi-free-standing graphene.

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A Combined Rietveld Refinement on the Crystal Structure of a Magnetoelectric Aurivillius Phase $Bi_5Ti_3FeO_{15}$ Using Neutron and X-ray Powder Diffractions

  • Ko, Tae-Gyung;Jun, Chang-Ho;Lee, Jeong-Soo
    • The Korean Journal of Ceramics
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    • v.5 no.4
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    • pp.341-347
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    • 1999
  • An ambiguity on the correct room temperature structure of $Bi_5Ti_3FeO_{15}$ was resolved using a combined Rietveld refinement of neutron and X-ray diffraction. The structure of this compound has been reported to have a space group of F2mm (adopting 2-fold rotation symmetry along the c-axis) or A21am. However, our diffraction, study reveals that some reflections would violate F-centering and confirm that the belong to $A2_1$am. Out refinement with the space group of $A2_1$am converged at $R_p=6.85%, R_wp=9.23%$ and $\chi^2$=1.66 for an isotropic temperature model with 85 variables. The lattice constants are a=5.4677(1) $\AA$, b=5.4396(1) $\AA$, and c=41.2475(8)$\AA$. In structure, Ti/Fe atoms at the oxygen octahedral sites of the perovskite unit are completely disordered, resulting in that these atoms are transparent in neutron diffraction. The octahedra of the perovskite unit are relatively displaced along the a-axis against the Bi atoms, which contribute as a major component to the spontaneous polarization of $Bi_5Ti_3FeO_{15}$.

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A Study on the Thermal Stability of Duplex High Mn-Steel Structure (고 망간강 2상 혼합조직의 열적 안정성에 관한 연구)

  • Wey, Myeong Yong
    • Journal of the Korean Society for Heat Treatment
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    • v.5 no.1
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    • pp.13-22
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    • 1992
  • The thermal stability of duplex high Mn-steel structure have been investigated using 15%Mn~1.0~2.4%C steels which are composed of ${\gamma}$-and ${\theta}$-phases in the range of temperature from 900 to $1100^{\circ}C$, and time from 50 to 300h. The results are as follows ; 1) The grain growth in single-phase region proceeds by grain boundary migration and the relation between mean radius $\bar{r}$ and annealing time t is described as follows ; $\bar{r}^2-{\bar{r}_0}^2=k_0{\cdot}t$ 2) The grain growth of duplex, (${\gamma}+{\theta}$), strucrure is slower than that single phase because the chemical composition of ${\gamma}$-and ${\theta}$-phases differs esch others. 3) The grain of (${\gamma}+{\theta}$) duplex structure grow slowly in a mode of Ostwald ripening. Because grain boundaries of ${\gamma}$-phase migrate under a restriction of pinning by ${\theta}$-phases. 4) In the duplex structures. the dispersed structures change to the dual-structures, as the volume fraction of the dispersed second-phase increase. Consequently, the growth-law, which is controlled by boundary-diffusion change to that of the volume diffusion-mechanism.

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DVB-S2-based T4 class common data link performance improvement plan for UAV system application (무인기 체계 적용을 위한 DVB-S2 기반 T4급 공용데이터링크 성능 개선방안)

  • Bae, Jongtae;Baek, Seongho;Oh, Jimyung;Lee, Sangpill;Song, Choongho
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.26 no.12
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    • pp.1846-1854
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    • 2022
  • The sophistication and diversification of mission equipment for surveillance and reconnaissance is leading to a demand for large-capacity public data links. Overseas, a T4 class(274Mbps) common data link was applied to the Global hwak, a high-altitude unmanned aerial vehicle, and various research and development are being conducted in Korea. In this paper, we propose a structure in which pilot is additionally applied to improve SNR performance while minimizing data transmission rate loss in the DVB-S2 frame structure, which is a european satellite broadcasting standard, for high-capacity transmission of T4 class or higher in the common data link. For the performance evaluation of the proposed structure, the performance of the DVB-S2 was compared and analyzed by simulating the UAV data link channel environment. As a result of simulation, 0.15% of transmission rate loss occurred at T4 class transmission rate compared to DVB-S2 in the proposed structure, but improved SNR reception performance of 0.2~0.3dB was confirmed in the UAV channel environment.