• Title/Summary/Keyword: Quenching parameter

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Correlation between Electrical Conduction and Dielectric Relaxation in the Glass System $Cul-Cu_2S-Cu_2O-MoO_3$ ($Cul-Cu_2S-Cu_2O-MoO_3$계 유리의 전기전도 및 유전환화와의 상관)

  • 이재형;임기조
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.43 no.7
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    • pp.1152-1157
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    • 1994
  • The glasses were prpared in the system CuI-CuS12TS-CuS12TO-MoOS13T by rapid quenching technique. These glasses have high ionic conductivities at 2$0^{\circ}C$ in the range of 10S0-1T[S/m], and the conductivities increase with increasing CuI and CuS12TS content. The value of activation energy for dielectric relaxation is nearly identical with that for conductivity. The cole-Cole parameter $\beta$ for representation of the distribution of dielectric relaxation times varies the range from 0.92 to 0.96. This parameter has a weak dependence on the composition of glass, and is independent of temperature. The correlation factors P for the glasses shows from 1.1 to 1.7.

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Effects of Ultraviolet-B Radiation on Photosynthesis in Tobacco (Nicotiana tabacum cv. Petit Havana SR1) Leaves (자외선-B 스트레스에 대한 담배 잎의 광합성 능의 변화)

  • Lee, Hae-Youn;Park, Youn-Il;Hong, Young-Nam
    • Korean Journal of Environmental Agriculture
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    • v.26 no.3
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    • pp.239-245
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    • 2007
  • The effect of ultraviolet-B (UV-B) radiation on photosynthesis was studied by the simultaneous measurements of $O_2$ evolution and chlorophyll (Chl) fluorescence in tobacco leaves. When the tobacco leaves were teated with UV-B (1 $W{\cdot}m^{-2}$), the maximal photosynthetic $O_2$, evolution (Pmax; 4.60 ${\mu}mol{\cdot}m^{-2}{\cdot}s^{-1}$) at 200 ${\mu}mol{\cdot}m^{-2}{\cdot}s^{-1}$) was decreased with increasing time of UV-B treatment showing 80% decline after 4 h treatment. Chl fluorescence parameters were also affected by ultraviolet-B. Fo was increased while both Fm and Fv were decreased, resulted in the decreased of photochemical efficiency of PSII (Fv/Fm). Non-radiative dissipation of absorbed light as heat as estimated as NPQ (Fm/Fm' - 1) was also decreased with increasing time of UV-B treatment while the extent of photochemical quenching (qP) was not changed. Thus, the ratio of (1-qP)/NPQ parameter was also increased with increasing time of UV-B treatment indicating PSII is under the threat of photoinhibition. The result indicate that UV-B primarily decreases the capacity to dissipate excitation energy by trans-thylakoid pH, which in turn inhibits PSII activity.

Effects of Parathyroid Hormone on the Fluidity of the Plasma Membrane Vesicles of Cultured Osteoblasts

  • Kang, Jung-Sook
    • Journal of Photoscience
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    • v.8 no.3_4
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    • pp.87-92
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    • 2001
  • Intramolecular excimer formation of 1,3-di(1-pyrenyl)propane (Py-3-Py) and fluorescence polarization of 1,6-diphenyl-1,3,5-hexatriene (DPH) were used to investigate the effects of parathyroid hormone (PTH) on the bulk bilayer fluidity of the plasma membrane vesicles isolated from cultured osteoblasts (OB-PMV). In a dose-dependent manner, rat PTH-(1-34) [rPTH-(1-34)] increased the excimer to monomer fluorescence intensity ratio (I'/I) of Py-3-Py and decreased the anisotropy (r) of DPH in OB-PMV. This indicates that PTH increased both the lateral and rotational diffusion of the probes in OB-PMY. Selective quenching of DPH fluorescence by trinitrophenyl groups was utilized to examine the transbilayer fluidity asymmetry of OB-PMV. The anisotropy, limiting anisotropy, and order parameter of DPH in the inner monolayer were 0.024, 0.032, and 0.062 greater than calculated for the outer monolayer of OB-PMY. Selective quenching of DPH fluorescence by trinitrophenyl groups was also utilized to examine the transbilayer effects of PTH on the fluidity of OB-PMV. rPTH-(1-34) had a greater fluidizing effect on the outer monolayer as compared to the inner monolayer of OB-PMV. Thus, it has been proven that PTH exhibits a selective rather than nonselective fluidizing effect within transbilayer domains of OB-PMV.

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Transbilayer Effects of n-Alkanols on the Fluidity of Phospholipid Model Membranes

  • Yun, Il;Kang, Jung-Sook
    • Archives of Pharmacal Research
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    • v.15 no.2
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    • pp.152-161
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    • 1992
  • Selective quenching of 1, 6-diphenyl-1, 3, 5-hexatriene (DPH) by trinitrophenyl groups was utilized to examine the transbilayer fluidity asymmetry of model membranes of phospholipids (SPMVPL) extracted from synaptosomal plasma membrane vesicles (SPMV). The polarization (P), anisotropy (r), limiting anisotropy $(r_\infty$), and order parameter (S) of DPH in the inner monolayer were 0.019, 0.014, 0.018, and 0.047, respectively, greater than calculated for the outer monolayer of SPMVPL. Selective quenching of DPH by trinitrophenyl groups was also utilized to examine the effects of n-alkanols on the individual monolayer structure of SPMVPL. n-Alkanols fluidized the hydrocarbon region of bulk SPMVPL and the potencies of n-alkanols up to 1-nonanon increased with carbon chain length. It appears that the potencies in bilayer fluidization increase by 1 order of magnitude as the carbon chain length increases by two carbon atoms. The cut-off phenomenon was reached at 1-decanol, where further increase in hydrocarbon length resulted in a decrease in pharmacological activity. The n-alkanols had greater fluidizing effects on the outer monolayer as compared to the inner monolayer of SPMVPL, even though these selective effects tended to become weaker as the carbon chain length increased. Thus, it has been proven that n-alkanols exhibit selective rather than nonselective fludizing effects within transbilayer domains of SPMVPL.

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Effects of Barbiturates on Transbilayer Fluidity Domains of Phospholipid Model Membrane Monolayers (Barbiturates가 소의 대뇌피질 Synaptosomal Plasma Membrane Vesicles로 부터 추출 제제한 총지질 및 총인지질 인공세포막에 형성된 비대칭적 유동성에 미치는 비대칭적 영향)

  • Yun, Il;Kang, Jung-Sook
    • The Korean Journal of Pharmacology
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    • v.28 no.1
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    • pp.103-114
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    • 1992
  • Selective quenching of 1,6-diphenyl-1,3,5-hexatriene (DPH) by trinitrophenyl groups was utilized to examine the transbilayer fluidity domains of the model membranes of total lipids (SPMVTL) and phospholipids (SPMVPL) extracted from synaptosomal plasma membrane vesicles. At $37^{\circ}C$, all anisotropy (r), limiting anisotropy $(r_{\infty})$, and order parameter (S) values of DPH in the SPMVTL were larger than those in SPMVPL. The anisotropy, limiting anisotropy, and order parameter of DPH in the inner monolayer were 0.025, 0.033, and 0.070, respectively, greater than calculated for the outer monolayer of SPMVTL. In SPMVPL, the anisotropy, limiting anisotropy, and order parameter of DPH in the inner monolayer were 0.014, 0.018, and 0.047, respectively, greater than calculated for the outer monolayer. Selective quenching of DPH by trinitrophenyl groups was also utilized to examine the effects of barbiturates on the transbilayer fluidity domains of SPMVTL and SPMVPL. Barbiturates did not affect the anisotropy of DPH in the transbilayer domains of SPMVTL. In contrast, barbiturates increased the fluorescence anisotropy, limiting anisotropy, and order parameter of DPH in the SPMVPL in a dose-dependent manner. Barbiturates showed a greater ordering effect on the outer monolayer as compared to the inner monolayer of SPMVPL. Hence, it has been demonstrated for the first time that the Sheetz-Singer hypothesis (1974) may be valid for phospholipid model membranes.

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Design of Cross Wedge Rolling Die for a Non-heat-treated Cold Steel using CAD and CAE (CAD/CAE를 이용한 냉간 비조질강용 회전전조 금형설계)

  • Lee H. W.;Yoon D. J.;Lee G. A.;Choi S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2004.05a
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    • pp.400-403
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    • 2004
  • A non-heat기leafed steel does not need quenching and tempering processes that are called a heat treatment differently from conventional steel. Since the tensile strength of this steel is higher than 900MPa, a conventional forming process should be changed to incremental forming process such as a cross wedge rolling that requires lower load capacity than conventional ones. In this paper, the cold cross wedge rolling (CWR) die has been designed using CAD/CAE In order to produce near-net-shaped component of ball stud of non-heat-treated cold steel. Finite element analyses were applied in order to investigate process parameters of CWR. Results provide that the stretching angle and the forming angie at knifing zone in CWR process is important parameter to be the stable process under the low friction coefficient condition.

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A study on mathematical modeling by neural networks (신경회로망을 이용한 수학적 모델에 관한 연구)

  • 이영진;이권순
    • 제어로봇시스템학회:학술대회논문집
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    • 1992.10a
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    • pp.624-627
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    • 1992
  • Mathematical modeling is majorly divided into three parts: the derivation of models, the fitting of models to data, and the simulation of data from models. This paper focuses on the parameter optimization which is necessary for the fitting of models to data. The method of simulated annealing(SA) is a technique that has recently attracted significant attention as suitable for optimization problem of very large scale. If the temperature is too high, then some of the structure created by the heuristic will be destroyed and unnecessary extra work will be done. If it is too low then solution is lost, similar to the case of a quenching cooling schedule in the SA phase. In this study, therfore, we propose a technique of determination of the starting temperature and cooling schedule for SA phase.

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Effect of Welding Variables for EBW Process in AISI 4130 by Taguchi Method (다구찌 방법을 이용한 AISI 4130재료에서 EBW공정의 용접 변수 영향)

  • Kim, Won-Hoon
    • Journal of Welding and Joining
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    • v.15 no.6
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    • pp.66-77
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    • 1997
  • In the present work, Taguchi method for electron beam welding(EBW) process in AISI 4130 steel plate has been adopted for investigating the contribution of effect of welding variables. $A L_8(2^7)$ orthogonal array is adopted to obtain the effect of adjustment parameters. The adjustment parameters consist of accelerating voltage, beam current, travel speed and focus currrent. And the quality features selected for the EBW process are bead width of weldment, reinforcement, penetration depth, undercut and area of weld metal. Variance analysis is performed in order to check the effect of adjustment parameters on EBW. The mechanical properties of electron beam welded joints for each heat treatment conditions are investigated in comparison with those of base metal, especially from the view point of tensile and impact properties.

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Effects of Cu impurity on the switching characteristics of the optically controlled bistable semiconductor switches (광제어 쌍안정 반도체 스위치에서 구리 불순물이 스위치특성에 미치는 영향)

  • 고성택
    • Electrical & Electronic Materials
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    • v.7 no.3
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    • pp.213-219
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    • 1994
  • Cu compensated Si doped GaAs (GaAs :Si:Cu has been chosen as the switch material. The GaAs material has been characterized by DLTS(Deep Level Transient Spectroscopy) technique and the obtained data were used in the computer simulation. Simulation studies are performed on several GaAs switch systems, composed of different densities of Cu, to investigate the influence of deep traps in the switch systems. The computed results demonstrates important aspect of the switch, the existence of two stable states and fast optical quenching. An important parameter optimum Cu density for the switch are also determined.

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Study on Long-term Deterioration Properties of Porcelain Insulators with Aluminous System (알루미나계 자기애자의 장기 피로특성에 관한 연구)

  • Han, Se-Won;Cho, Han-Goo;Lee, Dong-Il;Cho, In-Hyuk
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.562-563
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    • 2005
  • In case of aged porcelain, the failure in basic performance tests happened in cool-heat tests. Based on this characteristic, we studied the method predicting failure phenomena through more severe accelerated cool-heat ageing and accelerating thermal mechanical performance tests. Test results indicated that the thermal stress by temperature gradient was more severe parameter than thermal stress by quenching cycles within a category of standard or accelerating methods. And there is no the deterioration of statistic strength, but the deterioration of strength according to accelerating tests is serious.

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