• Title/Summary/Keyword: Quantum-mechanical

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Effect of gadolinium and boron addition on the texture development and magnetic properties of 23Cr-10NiCu duplex stainless steels

  • Baik, Youl;Kang, Bo Kyeong;Choi, Yong;Woo, Wan Chuck
    • Nuclear Engineering and Technology
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    • v.53 no.6
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    • pp.1887-1892
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    • 2021
  • The effect of gadolinium and boron on the texture development and magnetic properties of the texture controlled 23Cr-10NiCu duplex stainless steels were studied to develop a high performance neutron and electromagnetic shielding material. The 23Cr-10NiCu base alloy is composed of 60% of austenite and 40% of ferrite, whereas, the 23Cr-10NiCu-0.5Gd-0.8B modified alloy is composed of 66% of austenite, 27% of ferrite and 7% of CrFeB intermetallic compounds. The gadolinium and boron addition to the 23Cr-10NiCu base alloy increased mechanical properties. Microstructure observation showed that the small addition of 0.5 wt% gadolinium and 0.8 wt% boron to the alloy retarded to form texture at the same hot rolling conditions, and improved the maximum magnetism, residual magnetism and coercive force about 3%, 122% and 120%, respectively.

Fabrication of Carbon Microneedle Arrays with High Aspect Ratios and The Control of Hydrophobicity of These Arrays for Bio-Applications (고종횡비 탄소 마이크로니들 어레이의 제조 및 생체응용을 위한 소수성 표면의 제어)

  • Lee, Jung-A;Lee, Seok-Woo;Lee, Seung-Seob;Park, Se-Il;Lee, Kwang-Cheol
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.34 no.11
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    • pp.1721-1725
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    • 2010
  • This paper reports the fabrication of geometry-controlled carbon microneedles by a backside exposure method and pyrolysis. The SU-8 microneedles are a polymer precursor in a carbonization process, which geometries such as base diameter, spacing, and aspect ratio can be controlled in a photolithography step. Using this fabrication method, highly reproducible carbon microneedles, which have high aspect ratios of more than 10 and very sharp nanotips, can be realized. The quartz surface with carbon microneedles becomes very hydrophilic and its wettability is adjusted by carrying out the silane treatment. In the carbon microneedle array ($3\;{\mu}m{\times}3\;{\mu}m$), the contact angle is extremly enhanced (${\sim}180^{\circ}$); this will be advantageous in developing low-drag microfluidics and labs-on-a-chip as well as in other bio-applications.

Numerical Calculation of Energy Release Rates by Virtual Crack Closure Technique

  • Choi, Jae-Boong;Kim, Young-Jin;Yagawa, Genki
    • Journal of Mechanical Science and Technology
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    • v.18 no.11
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    • pp.1996-2008
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    • 2004
  • A seamless analysis of material behavior incorporating complex geometry and crack- tip modeling is one of greatly interesting topics in engineering and computational fracture mechanics fields. However, there are still large gaps between the industrial applications and fundamental academic studies due to a time consuming detailed modeling. In order to resolve this problem, a numerical method to calculate an energy release rate by virtual crack closure technique was proposed in this paper. Both free mesh method and finite element method have been utilized and, thereafter, robust local and global elements for various geometries and boundary conditions were generated. A validity of the proposed method has been demonstrated through a series of fracture mechanics analyses without tedious crack-tip meshing.

CdSe Nanocrystal Quantum Dots Based Hybrid Heterojunction Solar Cell

  • Jeong, So-Myung;Eom, S.;Park, H.;Lee, Soo-Hyoung;Han, Chang-Soo;Jeong, So-Hee
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.93-93
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    • 2010
  • Semiconductor nanocrystal quantum dots (NQDs) have recently attracted considerable interest for use in photovoltaics. Band gaps of NQDs can be tuned over a considerable range by varying the particle size thereby allowing enhance absorption of solar spectrum. NQDs, synthesized using colloidal routes, are solution processable and promise for a large-area fabrication. Recent advancements in multiple-exciton generation in NQD solutions have afforded possible efficiency improvements. Various architectures have attempted to utilize the NQDs in photovoltaics, such as NQD-sensitized solar cell, NQD-bulk-heterojuction solar cell and etc. Here we have fabricated CdSe NQDs with the band gap of 1.8 eV to 2.1 eV on thin-layers of p-type organic crystallites (1.61 eV) to realize a donor-acceptor type heterojuction solar cell. Simple structure as it was, we could control the interface of electrode-p-layer, and n-p-layer and monitor the following efficiency changes. Specifically, surface molecules adsorbed on the NQDs were critical to enhance the carrier transfer among the n-layer where we could verify by measuring the photo-response from the NQD layers only. Further modifying the annealing temperature after the deposition of NQDs on p-layers allowed higher conversion efficiencies in the device.

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Numerical Simulation of Deposition Chamber for Aerosol Nanoparticles Upward 300 mm Wafer (300 mm 웨이퍼 위의 에어로졸 나노 입자의 증착 장비 개발을 위한 수치 해석적 연구)

  • Ahn, Kang-Ho;Ahn, Jin-Hong;Lee, Kwan-Soo;Lim, Kwang-Ok;Kang, Yoon-Ho
    • Journal of the Semiconductor & Display Technology
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    • v.4 no.1 s.10
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    • pp.49-53
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    • 2005
  • The nanoparticle deposition chamber, which is used for quantum dot semiconductor memory applications, is designed by means of numerical simulation. In this research, the numerical simulations for deposition chamber were performed by commercial software, FLUENT. The deposition of nanoparticles is calculated by diffusion force, thermophoresis and electrophoresis of particles. As a results, when the diffusion force was considered, the most of particles deposited in the wall of deposition chamber. But as considering thermophoresis and electrophoresis of particles, the particles were deposited wafer surface, perfectly.

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Local Structure and Magnetic Properties of Fe-Mn Nanocrystalline Alloys Fabricated by Mechanical Alloying Technique as a Function of Milling Time

  • Tarigan, Kontan;Yang, Dong Seok;Yu, Seong Cho
    • Journal of Magnetics
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    • v.18 no.1
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    • pp.1-4
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    • 2013
  • Structural and magnetic properties of $Fe_{50}Mn_{50}$ nanocrystalline alloys prepared by the mechanical alloying technique (using commercial Fe and Mn powders as the precursors) are studied as a function of milling time, 1 hr to 48 hrs. The nano-crystallite size and shape are examined by using scanning electron microscopy (SEM). The effect of milling time on structural characterization was investigated using X-ray diffractometer (XRD) and extended X-ray absorption fine structure spectroscopy (EXAFS). Both XRD and EXAFS studies showed that the alloying process should be completed after 36 hrs milling. Concerning the magnetic behavior, the data obtained from superconducting quantum interference devices (SQUID) exhibited both magnetic saturation ($M_s$) and coercivity ($H_c$) depend strongly on the milling time, which are related to the changes in the crystallite size and magnetic dilution.

Evaluation of Tensile Property of Austenitic Alloys Exposed to High-Temperature S-CO2 Environment (고온 S-CO2 환경에 노출된 오스테나이트계 합금의 인장특성 평가)

  • Kim, Hyunmyung;Lee, Ho Jung;Jang, Changheui
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.38 no.12
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    • pp.1415-1420
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    • 2014
  • Super-critical $CO_2$ ($S-CO_2$) Brayton cycle has been considered to replace the current steam Rankine cycle in Sodium-cooled Fast Reactor (SFR) in order to improve the inherent safety and thermal efficiency. Several austenitic alloys are considered as the structural materials for high temperature $S-CO_2$ environment.. Microstructural change after long-term exposure to high temperature $S-CO_2$ environment could affect to the mechanical properties. In this study, candidate materials (austenitic stainless steels and Alloy 800HT) were exposed to $S-CO_2$ to assess oxidation resistance and the change in tensile properties. Loss of ductility was observed for some austenitic stainless steels even after 250 h exposure. The contribution of $S-CO_2$ environment on such changes was analyzed based on the characterization of the surface oxide and carburization of the materials in which 316H and 800H showed different oxidation behaviors.

Mechanical characterization of 100 nm-thick Au thin film using strip bending test (띠 굽힘 시험을 통한 100 nm 두께 금 박막의 기계적 특성 평가)

  • Kim, J.H.;Lee, H.J.;Han, S.W.;Baek, C.W.;Kim, J.M.;Kim, Y.K.
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.252-257
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    • 2004
  • Nanometer-sized structures are being applied to many devices including micro/nano electronics, optoelectronics, quantum devices, MEMS/NEMS, biosensors, etc. Especially, the thin film with submicron thickness is a basic structure for fabricating these devices, but its mechanical behaviors are not well understood. The mechanical properties of the thin film are different from those of the bulk structure and are difficult to measure because of its handling inconvenience. Several techniques have been applied to mechanical characterization of the thin film, such as nanoindentation test, micro/nano tensile test, strip bending test, etc. In this study, we focus on the strip bending test because of its high accuracy and moderate specimen preparation efforts, and measure Au thin film, which is a very popular material in micro/nano electronic devices. Au film is deposited on Si substrate by evaporation process, of which thickness is 100nm. Using the strip bending test, we obtain elastic modulus, yield and ultimate tensile strength, and residual stress of Au thin film.

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CONSTRUCTION OF UNBOUNDED DIRICHLET FOR ON STANDARD FORMS OF VON NEUMANN ALGEBRAS

  • Bahn, Chang-Soo;Ko, Chul-Ki
    • Journal of the Korean Mathematical Society
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    • v.39 no.6
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    • pp.931-951
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    • 2002
  • We extend the construction of Dirichlet forms and Markovian semigroups on standard forms of von Neumann algebra given in [13] to the case of unbounded operators satiated with the von Neumann algebra. We then apply our result to give Dirichlet forms associated to the momentum and position operators on quantum mechanical systems.