• Title/Summary/Keyword: Quantum Dot

Search Result 426, Processing Time 0.026 seconds

Microbead-based bio-assay using quantum dot fluorescence in a microfluidic chip (미소유체 칩 상에서 Quantum Dot 및 마이크로 비드를 이용한 생체물질 분석)

  • Yun, Kwang-Seok;Lee, Do-Hoon;Kim, Hak-Sung;Yoon, Eui-Sik
    • Journal of Sensor Science and Technology
    • /
    • v.14 no.5
    • /
    • pp.308-312
    • /
    • 2005
  • We present a microfluidic chip designed for the detection of antibody by using quantum dots fluorescence and a microbead-based assay. A custom designed PDMS microfluidic chip with multi-layer channel is utilized for capturing microbeads; antibody injection into each micro-well; QD injection; and fluorescence detection. The experiment using the fabricated microfluidic chip has been performed on solutions with various concentrations of antibody and has shown correlated fluorescent intensities.

Flexible Cu-In-Se Quantum Dot-Sensitized Solar Cells Based on Nanotube Electrodes (나노튜브 전극을 기반으로 한 플렉서블 양자점 감응 태양전지)

  • Kim, Jae-Yup
    • Journal of Powder Materials
    • /
    • v.26 no.1
    • /
    • pp.45-48
    • /
    • 2019
  • Quantum dots (QDs) are an attractive material for application in solar energy conversion devices because of their unique properties including facile band-gap tuning, a high-absorption coefficient, low-cost processing, and the potential multiple exciton generation effect. Recently, highly efficient quantum dot-sensitized solar cells (QDSCs) have been developed based on CdSe, PbS, CdS, and Cu-In-Se QDs. However, for the commercialization and wide application of these QDSCs, replacing the conventional rigid glass substrates with flexible substrates is required. Here, we demonstrate flexible CISe QDSCs based on vertically aligned $TiO_2$ nanotube (NT) electrodes. The highly uniform $TiO_2$ NT electrodes are prepared by two-step anodic oxidation. Using these flexible photoanodes and semi-transparent Pt counter electrodes, we fabricate the QDSCs and examine their photovoltaic properties. In particular, photovoltaic performances are optimized by controlling the nanostructure of $TiO_2$ NT electrodes.

Synthesis of Ultra-small PbS Nanocrystal Quantum Dots for Energy Applications

  • Choe, Hye-Gyeong;Jeong, So-Hui
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2012.02a
    • /
    • pp.535-535
    • /
    • 2012
  • We present a new synthetic route and characterization for ultra small sized PbS quantum dots in extreme quantum confinement with 1.5 to 2.9 nm in diameter. We obtained a series of nanocrystals with first absorption wavelength ranging from 580 to 820 nm (2.1-1.5 eV). To get this result, PbS quantum dots size is finely controlled by adjusting the growth temperature in the range of $70-95^{\circ}C$. We demonstrate that photoluminescence (PL) shows a red shift with respect to the first absorption peak that increases with decreasing PbS quantum dots size and ranges from about 500 to 125 meV as the mean PbS quantum dots diameter increases from 1.5 to 2.9 nm. We further created the assembled PbS quantum dot solids and investigated the transport properties for energy applications.

  • PDF

All-optical Polarization Phase Modulation in Coupled Quantum Dots

  • Je, Ku Chul;Kyhm, Kwangseuk
    • Current Optics and Photonics
    • /
    • v.1 no.1
    • /
    • pp.60-64
    • /
    • 2017
  • We have considered optical nonlinearities of coupled quantum dots theoretically, where an exciton dipole-dipole interaction is mediated between the adjacent large and small quantum dots. For increasing a pump pulse area in resonance with the large quantum dot exciton the induced nonlinear refractive index of the small quantum dot exciton has been obtained. As the exciton dipole-dipole interaction depends on the relative orientation of two exciton dipoles, the optical nonlinearities for the directions parallel and perpendicular to the coupling axis of the two quantum dots are compared. The directional imbalance of optical nonlinearities in coupled quantum dots can be utilized for a polarization phase modulator by controlling a pump pulse area and propagation length.

CdSe Quantum Dots Sensitized TiO2 Electrodes for Photovoltaic Cells

  • Yum, Jun-Ho;Choi, Sang-Hyun;Kim, Seok-Soon;Kim, Dong-Yu;Sung, Yung-Eun
    • Journal of the Korean Electrochemical Society
    • /
    • v.10 no.4
    • /
    • pp.257-261
    • /
    • 2007
  • The electronic properties of quantum dots can be tuned by changing the size of particles without any change in their chemical composition. CdSe quantum dots, the sizes of which were controlled by changing the concentrations of Cd and Se precursors, were adsorbed on $TiO_2$ photoelectrodes and used as sensitizers for photovoltaic cells. For applications of CdSe quantum dot as sensitizers, $CdSe/TiO_2$ films on conducting glass were employed in a sandwich-type cell that incorporated a platinum-coated conductive glass and an electrolyte consisting of an $I^-/I_3^-$ redox. The fill factor (FF) and efficiency for energy conversion ($\c{c}$) of the photovoltaic cell was 62 % and 0.32 %, respectively.

Flexible quantum dot solar cells with PbS-MIx/PbS-BuDT bilayers

  • Choe, Geun-Pyo;Yang, Yeong-U;Yun, Ha-Jin;Im, Sang-Gyu
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2016.02a
    • /
    • pp.347.2-347.2
    • /
    • 2016
  • Recently, in order to improve the performance of the colloidal quantum dot solar cells (CQDSCs), various efforts such as the modification of the cell architecture and surface treatment for quantum dot (QD) passivation have been made. Especially, the incorporation of halides into the QD matrix was reported to improve the performances significantly via passivating QD trap states that lower the life-time of the minority-carrier. In this work, we fabricated a lead sulfide (PbS) QD bilayer treated with different ligands and utilized it as a photoactive layer of the CQDSCs. The bottom and top PbS layer was treated using metal iodide ($MI_x$ and butanedithiol (BuDT), respectively. All the depositions and ligand treatments were carried out in air using layer-by-layer spin-coating process. The fabrication of the active layers as well as the n-type zinc oxide (ZnO) layer was successfully carried out on the bendable indium-tin-oxide (ITO)-coated polyethylene terephthalate (PET) substrate, which implies that this technique can be applied to the fabrication of flexible and/or wearable solar cells. The power conversion efficiency (PCE) of the CQDSCs with the architecture of $PET/ITO/ZnO/PbS-MI_x/PbS-BuDT/MoO_x/Ag$ reached 4.2 %, which is significantly larger than that of the cells with single QD (PbS-BuDT) layer.

  • PDF

Design of PCA Architecture Based on Quantum-Dot Cellular Automata (QCA 기반의 효율적인 PCA 구조 설계)

  • Shin, Sang-Ho;Lee, Gil-Je;Yoo, Kee-Young
    • Journal of Advanced Navigation Technology
    • /
    • v.18 no.2
    • /
    • pp.178-184
    • /
    • 2014
  • CMOS technology based on PCA is very efficient at an implementation of memory or ALU. However, there has been a growing interest in quantum-dot cellular automata (QCA) because of the limitation of CMOS scaling. In this paper, we propose a design of PCA architecture based on QCA. In the proposed PCA design, we utilize D flip-flop and XOR logic gate without wire crossing technique, and design a input and rule control switches. In experiment, we perform the simulation of the proposed PCA architecture by QCADesigner. As the result, we confirm the efficiency the proposed architecture.

Digital Logic Extraction from Quantum-dot Cellular Automata Designs (Quantum-dot Cellular Automata 회로로부터 디지털 논리 추출)

  • Oh, Youn-Bo;Lee, Eun-Choul;Kim, Kyo-Sun
    • Proceedings of the KIEE Conference
    • /
    • 2006.10c
    • /
    • pp.139-141
    • /
    • 2006
  • Quantum-dot Cellular Automata (QCA) is one of the most promising next generation nano-electronic devices which will inherit the throne of CMOS which is the domineering implementation technology of large scale low power digital systems. In late 1990s, the basic operations of the QCA cell were already demonstrated on a hardware implementation. Also, design tools and simulators were developed. Nevertheless, its design technology is not quite ready for ultra large scale designs. This paper proposes a new approach which enables the QCA designs to inherit the verification methodologies and tools of CMOS designs, as well. First, a set of disciplinary rules strictly restrict the cell arrangement not to deviate from the predefined structures but to guarantee the deterministic digital behaviors. After the gate and interconnect structures of the QCA design are identified, the signal integrity requirements including the input path balancing of majority gates, and the prevention of the noise amplification are checked. And then the digital logic is extracted and stored in the OpenAccess common engineering database which provides a connection to a large pool of CMOS design verification tools. Towards validating the proposed approach, we designed a 2-bit QCA adder. The digital logic is extracted, translated into the Verilog net list, and then simulated using a commercial software.

  • PDF

Preparation of CuS Counter Electrodes Using Electroplating for Quantum Dot-sensitized Solar Cells (전기 도금 공정을 활용한 양자점 감응 태양전지 CuS 상대 전극 제작)

  • SEUNG BEOM HA; IN-HEE CHOI;JAE-YUP KIM
    • Transactions of the Korean hydrogen and new energy society
    • /
    • v.34 no.6
    • /
    • pp.785-791
    • /
    • 2023
  • Copper sulfide (CuxS) has been extensively utilized as a counter electrode (CE) material for quantum dot solar cells (QDSCs) due to its exceptional catalytic activity for polysulfide electrolytes. The typical fabrication method of Cu2S CEs based on brass substrate is dangerous, involving the use of a highly concentrated hydrochloric acid solution in a relatively high temperature. In contrast, electroplating presents a safer alternative by employing a less acidic solution at a room temperature. In addition, the electroplating method increases the probability of obtaining CEs of consistent quality compared to the brass method. In this study, the optimized electroplating cycle for CuS CEs in QDSCs has been studied for the highly efficient photovoltaic performances. The QDSCs, featuring electroplated CuS CEs, achieved an impressive efficiency of 7.18%, surpassing the conventional method employing brass CEs, which yielded an efficiency of 6.62%.