• Bulletin of the Korean Chemical Society
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• v.20 no.10
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• pp.1213-1217
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• 1999

Hydrolysis reactions of 2-phenyl-4H,5H,6H-3-methyl-3-thiazinium perchlorate (PTP) and its derivatives at various pH have been investigated kinetically. The hydrolysis is quantitative, producing N-3-mercaptopropyl-N-methylbenzamide as the only product in the all pH ranges. The observed rate of hydrolysis of PTP was always of the first-order. For hydrolysis from PTP, Hammett ρvalues were 0.53, 0.84 and 1.13 for pH 5.0, 8.0, and 10.0, respectively. Bronsted βvalue was 0.53 for general base catalysis. This reaction is catalyzed by general w acetate concentration. However, as the amount of base becomes larger, the rate of hydrolysis reaction approaches the limiting values. The plot of log k vs. pH shows that the rate constants (kt) are two different regions in the profile; one part is directly proportional to hydroxide ion concentration and the other is not. On the bases of these result, the plausible hydrolysis mechanism and a reaction equation were proposed: Below pH 4.5, the hydrolysis was initiated by the addition of water to α-carbon. Above pH 9.0, the hydrolysis was proceeded by the addition of hydroxide ion to α-carbon. However, in the range of pH 4.5-8.0, these two reactions occured competitively.

• Ocean Systems Engineering
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• v.5 no.3
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• pp.161-179
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• 2015

An emergency response system (ERS) for vessel oil spills is a complex and dynamic system comprising a number of subsystems and activities. Failures may occur during the emergency response operations, this has negative impacts on the effectiveness of the ERS. Of the classes of problems in analyzing failures, the lack of quantitative data is fundamental. In fact, most of the empirical data collected via questionnaire survey is subjective in nature and is inevitably associated with uncertainties caused by the human being's inability to provide complete judgement. In addition, incomplete information and/or vagueness of the meaning about the failures add difficulties in evaluating the effectiveness of the system. Therefore this paper proposes a framework to evaluate the ERS effectiveness by using the combination of fuzzy reasoning and evidential synthesis approaches. Based on analyzing the procedure of ERS for oil spills, the failures in the system could be identified, using Analytic Hierarchy Process(AHP)to determine the relative weight of identified failures. Fuzzy reasoning combined with evidential synthesis is applied to evaluate the effectiveness of ERS for oil spills under uncertainties last. The proposed method is capable of dealing with uncertainties in data including ignorance and vagueness which traditional methods cannot effectively handle. A case study is used to illustrate the application of the proposed method.

• Bulletin of the Society of Naval Architects of Korea
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• v.27 no.3
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• pp.100-106
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• 1990

Microcracking of type 304 stainless steel at $593^{\circ}C(1,100^{\circ}F)$ has been studied, in particular, initiation, growth, and coalescence of fatigue and creep microcracks on smooth specimens and small notch specimens via surface replicas and photomicrographs. Quantitative information, such as, initiation period, growth, and coalescence behavior, statistical distributions of crack length, density of cracks, distribution patterns and crack growth properties, were obtained. From this study, the fracture process, fatigue life, and creep life prediction characterized by the growth of surface microcracks have been analysed by a new approach unifying the conventional approaches based on the final fracture of materials with the fracture mechanics approach. Knowledge of these parameters is critical for the application of fracture mechanics to fatigue and creep life assessment, and the damage evaluation of structures at elevated temperature.

• Nuclear Engineering and Technology
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• v.46 no.1
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• pp.73-80
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• 2014

A concrete cask is an option for spent nuclear fuel interim storage. A concrete cask usually consists of a metallic canister which confines the spent nuclear fuel assemblies and a concrete overpack. When the overpack undergoes a missile impact, which might be caused by a tornado or an aircraft crash, it should sustain an acceptable level of structural integrity so that its radiation shielding capability and the retrievability of the canister are maintained. A missile impact against a concrete overpack produces two damage modes, local damage and global damage. In conventional approaches [1], those two damage modes are decoupled and evaluated separately. The local damage of concrete is usually evaluated by empirical formulas, while the global damage is evaluated by finite element analysis. However, this decoupled approach may lead to a very conservative estimation of both damages. In this research, finite element analysis with material failure models and element erosion is applied to the evaluation of local and global damage of concrete overpacks under high speed missile impacts. Two types of concrete overpacks with different configurations are considered. The numerical simulation results are compared with test results, and it is shown that the finite element analysis predicts both local and global damage qualitatively well, but the quantitative accuracy of the results are highly dependent on the fine-tuning of material and failure parameters.

• Journal of Interdisciplinary Genomics
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• v.3 no.2
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• pp.41-46
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• 2021

Inherited platelet function disorders (IPFDs) are a disease group of heterogeneous bleeding disorders associated with congenital defects of platelet functions. Normal platelets essential role for primary hemostasis by adhesion, activation, secretion of granules, aggregation, and procoagulant activity of platelets. The accurate diagnosis of IPFDs is challenging due to unavailability of important testing methods, including light transmission aggregometry and flow cytometry, in several medical centers in Korea. Among several IPFDs, Glanzmann thrombasthenia (GT) is a most representative IPFD and is relatively frequently found compare to the other types of rarer IPFDs. GT is an autosomal recessive disorder caused by mutations of ITGA2B or ITGB3. There are quantitative or qualitative defects of the GPIIb/IIIa complex in platelet, which is the binding receptor for fibrinogen, von Willbrand factor, and fibronectin in GT patients. Therefore, patients with GT have normal platelet count and normal platelet morphology, but they have severely decreased platelet aggregation. Thus, GT patients have a very severe hemorrhagic phenotypes that begins at a very early age and persists throughout life. In this article, the general contents about platelet functions and respective IPFDs, the overall contents of GT, and the current status of genetic diagnosis of GT in Korea will be reviewed.

• The Journal of Asian Finance, Economics and Business
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• v.8 no.5
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• pp.315-324
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• 2021

The study aims to investigate new theoretical approaches in an effort to resolve conceptual contradictions regarding the impact of organizational culture on developing culture for change, first by providing socio-structural frameworks supporting intrapreneurship, and second through encouraging professional culture behavior with management practices or organizational members acting as agents of change forming a deeper culture of values and behavior. The design of this research is quantitative. This study employs survey data of managers and section heads, which met the sampling requirements. Data analysis in this research used structural equation modeling (SEM) with the help of the AMOS program. The results show that all hypotheses are supported. The findings of this study suggest that the organizational culture transformation and dyadic social intrapreneurship based on professional culture (DSIBPC) have significant positive influence as antecedents of competitive advantage. This research also shows that DSIBPC is able to act as an important mediator that fills a gap in the relationship between organizational culture transformation toward competitive advantage, as well as being an alternative strategy for organizations in an effort to increase their competitive advantage. Referring to the results of this research, organizations need to focus and pay attention to the DSIBPC.

• Nuclear Engineering and Technology
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• v.53 no.11
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• pp.3505-3516
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• 2021

During nuclear facility decommissioning, workers are continuously exposed to high-level radiation. Hence, adequate path planning is critical to protect workers from unnecessary radiation exposure. This work discusses recent development in radioactive path planning and the algorithms recommended for the task. Specifically, we review the conventional methods for nuclear decommissioning path planning, analyze the techniques utilized in developing algorithms, and enumerate the decision factors that should be considered to optimize path planning algorithms. As a major contribution, we present the quantitative performance comparison of different algorithms utilized in solving path planning problems in nuclear decommissioning and highlight their merits and drawbacks. Also, we discuss techniques and critical consideration necessary for efficient application of robots and robotic path planning algorithms in nuclear facility decommissioning. Moreover, we analyze the influence of obstacles and the environmental/radioactive source dynamics on algorithms' efficiency. Finally, we recommend future research focus and highlight critical improvements required for the existing approaches towards a safer and cost-effective nuclear-decommissioning project.

• Asia-Pacific Journal of Business
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• v.11 no.3
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• pp.261-271
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• 2020

Purpose - This study was to establish a unified tourism management class for university students based on Gangwon-do. Community based learning(CBL) was applied to provide a tangible and intangible resource of tourism resources the theoretical approaches and the actual experiences of the community. Design/methodology/approach - In order to design a unified tourism management module, this study applied qualitative research and quantitative research methods to collect information on the direction of the module. the study conducted in-depth interviews and then an online survey. Findings - According to the results of the study, the main parts should include necessity of unification, inter-Korean tourism, inter-Korean cooperation, inter-Korean economy, and international relations. Research implications or Originality - The overall composition of the unification tourism management class should be designed as the unification tourism management theory to acquire the subject knowledge, the field trip to the border area for experiential learning, and the assignment of the field study task to understand the community.

• Proceedings of the Korea Water Resources Association Conference
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• 2016.05a
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• pp.578-578
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• 2016

In the past decade, many countries developed varies promising theories, methodologies and technologies for water resources management, such as Smart Water in Korea, eWater in Australia, Intelligent Water in Untied States, and Internet of Water in China. It is no exaggeration to say that Smart Water Management(SWM) will have a major role to play in addressing the global water challenges in the background of climate change, population growth and rapid urbanization. As a result, we can see major shifts taking place in the structure of the water industry, with a need for new approaches, skills, and water management policies. All these point towards a brighter future for the smart water sector and a new water paradigm, with applications and potential throughout the water cycle. However, each countries have their technology and industry standard system which may swift similar innovation and technology into different channels. In that sense, developing a common performance index and standard docking adapter for assessing Smart Water Management Initiatives(SWMI) is crucial for drawing a linkage of SWMI and SWMs to a way to implement advanced technology across Asia and Pacific. The performance index and standard docking adapter will facilitate quantitative and qualitative effects of utilized SWM techniques.

• The Journal of Asian Finance, Economics and Business
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• v.8 no.4
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• pp.33-42
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• 2021

This study aims to investigate the relationship between foreign direct investment (FDI) and economic growth at the provincial level by using time-series data in Binh Dinh from 1997 to 2019. We applied the quantitative approaches Vector Autoregression (VAR) and Autoregressive Distributed Lags (ARDL) in the model, which includes economic growth, real foreign direct investment capital, ratio of trained workers, and infrastructure. The results show that all these variables are stationary at the first difference. In ARDL analysis, we found that the economic growth positively affects FDI attraction. However, there is no evidence of the effect of FDI on economic growth in the condition of low capital implemented. Moreover, findings also show that the impact of FDI on economic growth is influenced by two factors: infrastructure and human capital. The lack of human capital, which is trained personnel and infrastructure, is the main barrier hindering and inhibiting FDI's contribution to local economic growth. In order to improve the efficiency of FDI on economic growth in the future, it is suggested that the Binh Dinh government should have proper policies in terms of the infrastructure, the human capital investment. They would allow Binh Dinh to enhance the capital absorptive capacity and capital efficiency.