• Title/Summary/Keyword: Py

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Evaluation of Thermal Effect on the Concrete Pylon of a Cable-stayed Bridge (사장교 콘크리트 주탑의 온도영향 평가)

  • Park Jong Chil;Kim Young Jin;Choi Sung Kwon;Lee Chung Pyo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05a
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    • pp.355-358
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    • 2005
  • In this paper, an actual behavior of the pylon of Seohae Grand Bridge which is a cable stayed bridge and has been constructed 4 years ago was analyzed by using data acquisition system. As a result, the pylon of cable stayed bridge behaved normally with respect to the change of temperature. The annual displacement of the top of pylon(PY1) ranged from -71.4mm to +181.7mm in the longitudinal direction of the bridge. In the case of the longitudinal displacement, the displacement of PY1 was bigger than that of PY2 because PY1 is movable and PY2 is fixed in terms of the constraint condition of super structure. For the long term, PY1 will be sloped gently to the direction of Dangjin and PY2 will be also sloped gently to the direction of Pyongtaek by the effect of creep and shrinkage in the case of the longitudinal direction. The result of structural analysis showed good agreement with the result mentioned above.

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Study of Functional Verification to Abiotic Stress through Antioxidant Gene Transformation of Pyropia yezoensis (Bangiales, Rhodophyta) APX and MnSOD in Chlamydomonas

  • Lee, Hak-Jyung;Yang, Ho yeon;Choi, Jong-il
    • Journal of Microbiology and Biotechnology
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    • v.28 no.7
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    • pp.1217-1224
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    • 2018
  • Seaweeds produce antioxidants to counteract environmental stresses, and these antioxidant genes are regarded as important defense strategies for marine algae. In this study, the expression of Pyropia yezoensis (Bangiales, Rhodophyta) ascorbate peroxidase (PyAPX) and manganese-superoxide dismutase (PyMnSOD) was examined by qRT-PCR in P. yezoensis blades under abiotic stress conditions. Furthermore, the functional relevance of these genes was explored by overexpressing them in Chlamydomonas. A comparison of the different expression levels of PyAPX and PyMnSOD after exposure to each stress revealed that both genes were induced by high salt and UVB exposure, being increased approximately 3-fold after 12 h. The expression of the PyAPX and PyMnSOD genes also increased following exposure to $H_2O_2$. When these two genes were overexpressed in Chlamydomonas, the cells had a higher growth rate than control cells under conditions of hydrogen peroxide-induced oxidative stress, increased salinity, and UV exposure. These data suggest that Chlamydomonas is a suitable model for studying the function of stress genes, and that PyAPX and PyMnSOD genes are involved in the adaptation and defense against stresses that alter metabolism.

1-OH-Pyrene and 3-OH-Phenanthrene in Urine Show Good Relationship with their Parent Polycyclic Aromatic Hydrocarbons in Muscle in Dairy Cattle

  • Kang, Hwan-Goo;Jeong, Sang-Hee
    • Toxicological Research
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    • v.27 no.1
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    • pp.15-18
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    • 2011
  • The toxicities of phenanthrene (PH) and pyrene (PY) are less than benzo(a)pyrene (BaP), but both compounds are found in higher concentrations in the air, feed, and food. Most PAHs are metabolized to hydroxylated compounds by the hepatic cytochrome P450 monooxigenases system. Metabolites are excreted into urine and feces. We determined concentrations of PH, PY and BaP in muscle and hydroxylated metabolites, 3-OH-PH, 1-OH-PY, and 3-OH-BaP, respectively, in urine from dairy cattle (n = 24). We also evaluated the relationship between parent compounds in muscle and their metabolites in urine. Concentrations of PH and PY in muscle ranged from 0.7~4.8 ng/g ($1.8{\pm}1.7$) and 0.4~4.1 ng/g ($1.2{\pm}1.2$), respectively. Concentrations of 3-OH-PH and 1-OH-PY in urine ranged from 0.1~5.9 ng/ml ($2.9{\pm}3.7$) and 0.5~3.6 ng/ml ($1.9{\pm}2.3$), respectively. Correlation coefficient for PY concentration in muscle versus 1-OH-PY in urine was 0.657 and for PH concentration in muscle versus 3-OH-PH in urine was 0.579. Coefficient determination for PY and PH concentrations in muscle was 0.886 and for 1-OH-PY and 3-OH-PH in urine was 0.834. This study suggests that 1-OH-PY and 3-OH-PH could be used as biomarkers for PAHs exposure in dairy cattle.

PyStudy : Python based Self-Study Helper Software (PyStudy : Python 학습 도우미 소프트웨어 개발)

  • Jo, YeongChang;Kim, HyeHyeon;Kim, HoonSik;Han, SeongUk;Lee, Hyung-Woo
    • Journal of Internet of Things and Convergence
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    • v.2 no.1
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    • pp.41-48
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    • 2016
  • The Korea Internet of Things Society. In this paper, we developed 'PyStudy' system as a python based self-study helper software. Proposed PyStudy system is consisted with several components such as PyStudy console, self-study window, helper and self-coding window. User can refer helper function to find questionable python libraries at on-line connection quickly. And self-progress checking on python study also provided on integrated PyStudy IDE software. The PyStudy software provides the information necessary to learn the Python language efficiently. Proposed software can be applicable to an advanced Python language education course.

Downregulation of PyHRG1, encoding a novel secretory protein in the red alga Pyropia yezoensis, enhances heat tolerance

  • Han, Narae;Wi, Jiwoong;Im, Sungoh;Lim, Ka-Min;Lee, Hun-Dong;Jeong, Won-Joong;Kim, Geun-Joong;Kim, Chan Song;Park, Eun-Jeong;Hwang, Mi Sook;Choi, Dong-Woog
    • ALGAE
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    • v.36 no.3
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    • pp.207-217
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    • 2021
  • An increase in seawater temperature owing to global warming is expected to substantially limit the growth of marine algae, including Pyropia yezoensis, a commercially valuable red alga. To improve our knowledge of the genes involved in the acquisition of heat tolerance in P. yezoensis, transcriptomes sequences were obtained from both the wild-type SG104 P. yezoensis and heat-tolerant mutant Gy500. We selected 1,251 differentially expressed genes that were up- or downregulated in response to the heat stress condition and in the heat-tolerant mutant Gy500, based on fragment per million reads expression values. Among them, PyHRG1 was downregulated under heat stress in SG104 and expressed at a low level in Gy500. PyHRG1 encodes a secretory protein of 26.5 kDa. PyHRG1 shows no significant sequence homology with any known genes deposited in public databases to date. However, PyHRG1 homologs were found in other red algae, including other Pyropia species. When PyHRG1 was introduced into the single-cell green alga Chlamydomonas reinhardtii, transformed cells overexpressing PyHRG1 showed severely retarded growth. These results demonstrate that PyHRG1 encodes a novel red algae-specific protein and plays a role in heat tolerance in algae. The transcriptome sequences obtained in this study, which include PyHRG1, will facilitate future studies to understand the molecular mechanisms involved in heat tolerance in red algae.

Structure of $[cis-ReCl_4(py)(N-C_6H_3-2,6-i-Pr_2)\cdot(NH_2-C_6H_3-2,6-i-Pr_2)]$ (py=pyridine) ($[cis-ReCl_4(py)(N-C_6H_3-2,6-i-Pr_2)\cdot(NH_2-C_6H_3-2,6-i-Pr_2)]$ 착물의 구조(py=pyridine))

  • 최남선;이순원
    • Korean Journal of Crystallography
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    • v.10 no.2
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    • pp.105-109
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    • 1999
  • Ar 기류 하에서 Re(N-C6H3-2,6-i-Pr2)2Cl3(py) (1)과 propionaldehyde (C2H5CHO)가 반응하여 생성된 혼합물에서, [cis-ReCl4(py)(N-C6H3-2,6-i-Pr2)·(NH2-C6H3-2,6-i-Pr2)] (2)가 분리되었다. 이 화합물의 구조가 X-ray 회절법으로 규명되었다. 착물 2의 결정학 자료: 단사정계 공간군 P21/n, a=11.555(1) Å, b=27.066(3) Å, c=11.881(1) Å, β=117.991(8)°, Z=4, R(wR2)=0.0332(0.0851.

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Molecular Switching Coordination Polymers. 4.4'-Chalcogenobispyridine Bridged Cobalt Benzoquinone Complexes

  • 조두환;정종화;여환진;손윤수;정옥상
    • Bulletin of the Korean Chemical Society
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    • v.16 no.6
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    • pp.504-507
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    • 1995
  • The reaction of Co2(CO)8 with 3,6-di-tert-butyl-1,2-benzoquinone in the presence of the respective 4,4'-chalcogenobispyridine results in the coordination polymers of [CoⅢ(4,4'-X(Py)2)(DBSQ)(DBCat)]n (X=S, Se, Te; Py=pyridine; DBSQ=3,6-di-tert-butylsemiquinone; DBCat=3,6-di-tert-butylcatechol). The title compounds undergo an intramolecular Cat → Co electron transfer, and thus change toward the [CoⅡ(4,4'-X(Py)2)(DBSQ)2]n at elevated temperature. The temperature-switching properties of the compounds directly depend upon the electronegativity of the chalcogen atom of the 4,4'-chalcogenobispyridine coligands. The spectroscopic data disclose that the properties of [CoⅢ(4,4'-S(Py)2)(DBSQ)(DBCat)]n and [CoⅢ(4,4'-Se(Py)2)(DBSQ)(DBCat)]n are similar each other in contrast to those of [CoⅢ(4,4'-Te(Py)2)(DBSQ)(DBCat)]n.

Mechanism of Electropolymerization of Pyrrole in Acidic Aqueous Solutions

  • Kim, Kang-Jin;Song, Hyung-Soo;Kim, Jin-Doo;Chon, Jung-Kyoon
    • Bulletin of the Korean Chemical Society
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    • v.9 no.4
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    • pp.248-251
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    • 1988
  • Mechanism of electrochemical polymerization of pyrrole (Py) on a Pt electrode in acidic aqueous solutions was studied by means of potentiostatic measurements, cyclic voltammetry and chronopotentiometry. Pyrrole molecule appeared to be initially oxidized via two-electron transfer step to produce oxidized pyrrole ion ($Py^+$), which was coupled with a non-oxidized pyrrole to yield a dimerized species, Py-Py. The Py-Py thus formed was further oxidized again via two-electron transfer step, which was followed by coupling with non-oxidized monomer and by concomitant expulsion of a $H^+$. Then the latter chain extension process was repeated. The chain extension and polypyrrole oxidation reactions occurred competitively.

Analyze the possibility of current PyScript in practical application (현재 PyScript의 실제 응용 가능성)

  • Yin, Zhen;Lee, Scott Uk-Jin
    • Proceedings of the Korean Society of Computer Information Conference
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    • 2022.07a
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    • pp.133-134
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    • 2022
  • With the advent of PyScript, there are more and more topics in practice. However, the official guideline has not provided a detailed description. This paper investigates the practical application about PyScript. The research results show that the current functions in PyScript cannot be well handled in web pages, and even cannot use the advantage model of Python, which is not suitable for practical application in the short term. However, it may be widely used in web development in the future since writing functions through Wasm can improve the efficiency of program execution.

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Molecular Strands and Related Properties of Silver(Ⅰ) Triflate with 3,3'-Oxybispyridine vs 3,3'-Thiobispyridine

  • Kim, Yu-Ju;Lee, Young-A;Park, Ki-Min;Chae, Hee K.;Jung, Ok-Sang
    • Bulletin of the Korean Chemical Society
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    • v.23 no.8
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    • pp.1106-1109
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    • 2002
  • Studies on subtle spacer ligand effects of AgCF3SO3 with 3,3'-Py2X (X = O vs S) have been carried out. The reaction of AgCF3SO3 with 3,3'-Py2O and 3,3'-Py2S produces [Ag(CF3SO3)(3,3'-Py2O)] and [Ag(3,3'-Py2S)] (CF3SO3), respectively. Crystallographic characterization of [Ag(CF3SO3)(3,3'-Py2O)] (monoclinic P1, a =8.405(2) $\AA$, b = 10.714(2) $\AA$, c = 18.031(2) $\AA$, $\alpha=$ 77.36(2), $\beta=107.83(2)^{\circ}$, $\gamma=$ 66.92(2), V = 1438.0(5) $\AA3$ , Z =2,R = 0.0486) reveals that the skeletal structure is an anion-bridged double-strand. The double-strands are packed like a plywood. The framework of [Ag(3,3'-Py2S)](CF3SO3) (orthorhombic Pcab, a = 17.330(2) $\AA$, b = 8.640(1) $\AA$, c = 19.933(6) $\AA$, V = 2985(1) $\AA3$ , Z =8, R = 0.0437) is a sinusoidal single-strand. The formation of each coordination polymer appears to be primarily associated with the donating ability and the confor ma-tional energy barrier of the spacer ligands. Thermal analyses indicate that [Ag(CF3SO3)(3,3'-Py2O)] and [Ag(3,3'-Py2S)](CF3SO3) are stable up to 250 $^{\circ}C$ and 210 $^{\circ}C$, respectively. For the anion exchangeability, the nature of the spacer ligand is more significant factor than the distance of silver(Ⅰ)···triflate.