• Elastomers and Composites
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• v.58 no.2
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• pp.70-80
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• 2023

The effect of phenylphosphonic acid (PPOA) on polyurethane (PU) thermal stability was studied through Fourier transform infrared spectroscopy and Thermogravimetric analysis. To synthesize PPOA-modified PUs (PPOA-PUs), polyether-type diols (Mw=62, 106, 190, 419, 605) were chemically modified with PPOA and then reacted with 4,4'-dicyclohexylmethane diisocyanate (H₁₂MDI) and 4,4-diphenylmethane diisocyanate (MDI). During thermal decomposition in air, the PPOA embedded in the PUs formed intumescent phosphocarbonaceous char. Below 400℃, PPOA-H₁₂MDI-PUs were more unstable, as PPOA decomposed at lower temperatures than phenyl groups and aliphatic ethers. Above 550℃, the thermal stability of PUs followed this order: PPOA-MDI-PUs > PPOA-H₁₂MDI-PUs > MDI-PUs > H₁₂MDI-PUs. At 700℃, unmodified PUs had no residue, while the PPOA-MDI-PU residue was 4.4~23.0 wt.% and the PPOA-H₁₂MDI-PU residue was 1.5~17.5 wt.%. The enhanced thermal stability of PPOA-MDI-PUs at high temperatures can be attributed to the synergetic effect of PPOA and phenyl groups on the formation of phosphocarbonaceous char.

• Journal of Navigation and Port Research
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• v.35 no.2
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• pp.121-130
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• 2011

The localization of vehicle is an important part of an unmanned vehicle control problem. Pseudolite ultrasonic system(PUS) is the method to find an absolute position with a high accuracy by using ultrasonic sensor. And Gyro is the inertial sensor to measure yaw angle of vehicle. PUS can be able to estimate the position of mobile robot precisely, in which errors are not accumulated. And Gyro is a more faster measure method than PUS. In this paper, we suggest a more accuracy method of calculating PUS which is numerical analysis approach named Newtonian method. And also propose the fusion method to increase the accuracy of estimated angle on moving vehicle by using PUS and Gyro integrated system by Kalman filtering. To control the 4WS unmanned vehicle, the trajectory following algorithm is suggested. And the new concept arbitration of goal controller is suggested. This method considers the desirability function of vehicle state. Finally, the performances of Newtonian method and designed controller were verified from the experimental results with the 4WS vehicle scaled 1/10.

• The Journal of the Korea Contents Association
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• v.16 no.2
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• pp.117-128
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• 2016

The growing socio-economic effect caused by science and technology requires public to participate in policy-making process, which makes government to boost public understanding of science(PUS). Government has also exerted to construct infra for PUS. However results are not so meaningful. The government-funded science museum has mainly provided the program for students. Besides, science broadcasting channel has recorded the worst viewing rate. Meanwhile, some of the private sector-manufactured contents have attracted public attention in recent years, which is realized by considering elements such as an interesting topic selection, use of outside experts, two-way communication system, level adjusting for public through flexible running system. This study analyze podcast based program, face to face lectures, display contents by private industry, fab lab etc. on the base of the reciprocal PUS model to sort out the reason they have successful results. Futhermore, it argues that government should intensify support for private sector and create synergy effect by cultivate collaboration system between government and private sector to enhance the efficiency of PUS and offers public policy to realize the plan.

• KSII Transactions on Internet and Information Systems (TIIS)
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• v.8 no.7
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• pp.2212-2230
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• 2014

Cognitive radio (CR) users, known as secondary users (SUs), should avoid interference with primary users (PUs) who own the licensed band, while trying to access it; when the licensed band is unused by the PUs. To detect PUs, spectrum sensing should be performed over in-band channels that are currently in use by SUs. If PUs return to access the band, SUs need to vacate it, disrupting the SUs' communication unless a non-utilized band is discovered. Obtaining a non-utilized band in a short period facilitate seamless communication for SUs and avoid interference on PUs by vacating from the channel immediately. Searching for a non-utilized band can be done through proactive out-of-band (OB) sensing. In this paper, we suggest a proactive OB sensing scheme that minimizes the time required to discover a non-utilized spectrum in order to continue communication. Although, the duration spent on OB sensing reduces the throughput of the CR networks that can be achieved on band being utilized, the lost throughput can be compensated in the new discovered band. We demonstrate that, the effect of our proposed scheme on the throughput owing to OB sensing is insignificant, while exhibiting a very short channel discovery time.

• Transactions on Electrical and Electronic Materials
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• v.18 no.4
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• pp.211-216
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• 2017

The dielectric properties of two polyurethanes (PUs) with different hard segments, i.e., aromatic methylene di-p-phenyl diisocyanate (MDI) and aliphatic hexamethylene diisocyanate (HDI), were investigated in the temperature range of -100 to $100^{\circ}C$ and in the frequency range of 1 Hz to 3 kHz. The ${\alpha}$-relaxations induced by the glass transition of the equivalent soft segments in the two PUs occurred at relaxation times of ${\tau}=3.46{\times}10^{-3}s$ for MDI-PU and ${\tau}=3.39{\times}10^{-2}s$ for HDI-PU at $-20^{\circ}C$, in accord with the temperature-frequency superposition principle, resulting in similar shifting factors. However, different I-relaxations were observed for the two PUs. The I-relaxation of MDI-PU occurred due to the mobility of the chain extenders near $80^{\circ}C$ with a slower shifting rate than the ${\alpha}$-relaxation. On the other hand, I-relaxation arising from both the extender and the unconstrained hard segments of HDI-PU occurred at $70{\sim}100^{\circ}C$, indicating complicated dielectric behavior due to partial interaction with the ${\alpha}$-relaxation at high frequencies. Thus, the I-relaxation of HDI-PU did not follow the superposition principle. The dielectric behaviors of the PUs were mainly influenced by their phase transitions, which were affected by the structure and components of the materials.

• Multiscale and Multiphysics Mechanics
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• v.1 no.4
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• pp.327-340
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• 2016

Poly(${\epsilon}$-caprolactone) (PCL) diol, with good biodegradation and biocompatibility, is one of the widely used soft segments (SSs) in composing bio-polyester-urethanes (Bio-PUs), which show great potential in both biomedical and tissue engineering applications. Properties of Bio-PUs are tunable by combining SS monomers with different molecular weights, structures, modifications, and ratio of components. Although numbers of research have reported many Bio-PUs properties, few studies have been done at the molecular scale. In this study, we use molecular dynamic (MD) simulation to construct atomistic models for two commonly used PCL diol SSs with different molecular weights 1247.58 Da and 1932.42 Da. We compare the simulation results by using two widely used classical force fields for organic molecules: Consistent Valence Force Field (CVFF) and CHARMM General Force Field (CGenFF), and discuss the validity and accuracy. Melt density, volume, polymer conformations, transition temperature, and mechanical properties of PCL diols are calculated and compared with experiments. Our results show that both force fields provide accurate predictions on the properties of PCL diol system at the molecular scale and could help the design of future Bio-PUs.

• Journal of the Korea Institute of Building Construction
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• v.12 no.2
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• pp.230-242
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• 2012

Recently the Permanent Uni-wall System (PUS) has been developed which improved the disadvantage of the Cast-In-Place Concrete Pile (CIP) and could be used as permanent retaining wall. In this study, joints between PUS and floor systems were developed. From analyses of the characteristics of design and construction of PUS, shear friction reinforcements with couplers were adopted for shear design of the joints. Twelve types of joints were developed which were classified according to the types of floor structures, wale, and piles of PUS. Two typical joints were tested and the joints showed satisfactory behaviors on the points of shear strength, stiffness, and serviceability. Especially the shear strengths were much higher than the design strengths due to the shear keys which were by-products in splicing shear reinforcements. However, the shear strength of the joint is recommended to be designed by only shear friction reinforcement because shear key is not reliable and too brittle.

• KSII Transactions on Internet and Information Systems (TIIS)
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• v.5 no.7
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• pp.1214-1229
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• 2011

Power control is a key technique in spectrum underlay cognitive network to guarantee the interference temperature limit of the primary users (PUs) and the quality of service of the secondary users (SUs). In this paper, a robust power control scheme via link gain pricing with $H_{\infty}$ estimator is proposed. The scheme guarantees the interference temperature of the PUs through operating in the network-centric manner, and keeps the fairness between the SUs through link gain pricing. Furthermore, the $H_{\infty}$ filter is also used in the proposed scheme to estimate the channel variation, and thus the power control scheme is robust to the severe channel fading. Plenty of simulations are taken, and prove its superior robust performance against the channel fading, and its effectiveness in guaranteeing the interference temperature limit of the PUs.

• The Journal of Korean Medicine Ophthalmology and Otolaryngology and Dermatology
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• v.10 no.1
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• pp.306-331
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• 1997

A difference in a views of the Ong(癰) and juh(疽). In the Ong-juh(癰疽) of the Young-Chu(靈樞), if the Ki(氣) and Hul(血) are blocked in a man's body, the heat(熱) generated consists of Pus(膿). Pus(膿) which goes into the man's body and doesn't deteriorate the five viscera(五臟) is Ong(癰). Juh(疽) is pus(膿) which goes deeply into the man's body does hurt the muscle and bone. Tal-Juh(脫疽) is an ailment in the toe. It is a sort of the gangrene of the extremities. In a literature study oh the Tal- Juh(脫疽), it obtained some opinions, so it is report.

• Korean Journal of Biological Psychiatry
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• v.28 no.2
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• pp.58-69
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• 2021

Objectives The aim of this study was to examine the association between the sleep pattern, chronotype (midpoint of sleep on free days) and the depressive symptoms in adults aged 19 years and over in Korea. This study also investigated the mediating effect of perceived usual stress (PUS) and self-rated health (SRH) on the association between chronotype and depressive symptoms. Methods Among the subjects of the 7th Korea National Health and Nutrition Examination Survey (KNHANES) 2016 and 2018, 16142 adults aged 19 or over responded to the survey and finally 8604 were analyzed according to the exclusion conditions. Logistic regression analysis was conducted to see the risk of depressive symptoms, suicidal ideation over sleep pattern, chronotype. Finally, mediation analysis was performed in order to clarify how PUS and SRH are associated to chronoytpe and depression. Results After controlling for potential covariates, weekly sleep duration < 5 hours, ≥ 10 hours was associated with depressive symptoms. And late bed time sleeping after am 1:00 and later midpoints of sleep was associated with a higher level of depressive symptoms. Additionally, the PUS and SRH between chronotype and depressive symptoms showed a serial multiple mediation effect. Conclusions Short or long sleep duration, late bed time and later midpoints of sleep on free days are associated with depressive symptoms. Furthermore, the mechanism between chronotype and depressive symptoms needs to be further clarified by identifying the serial multiple mediation effects of PUS and SRH.