• 제목/요약/키워드: Pure Potential

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Correlation between Structures and Magnetism in Iron: Ferromagnetism and Antiferromagnetism

  • Lee, Dong-Kook;Hong, Soon-Cheol
    • Journal of Magnetics
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    • 제12권2호
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    • pp.68-71
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    • 2007
  • Even a pure bulk Fe has a complicated magnetic phase and its magnetism is still needed to be clarified. In this study we investigated the magnetism of bcc and fcc bulk Fe with total energy calculations as functions of atomic volume. The full-potential linearized augmented plane wave method was adopted within a generalized gradient approximation. The ground state of bulk Fe is confirmed to be of ferromagnetic (FM) bcc. For fcc structured Fe an antiferromagnetic (AFM) state is more stable compared to FM states which exist as low spin and high spin states. The stable AFM states were found to accompany a tetragonal distortion, while the FM states remained in a cubic symmetry. At an expanded lattice constant a high spin FM state was calculated to be able to be stabilized with significant enhanced magnetic moment compared to the value of the ground state, bcc FM.

Temperature Dependence of the Rate Constants of the VV Energy Exchange for N$_2$(v=1)+O$_2$(v=0)$\rightarrow$N$_2$(v=0)+O$_2$(v=1)

  • Ree, Jong-Baik;Chung, Keun-Ho;Kim, Hae-Jin
    • Bulletin of the Korean Chemical Society
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    • 제7권3호
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    • pp.241-245
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    • 1986
  • The vibration-vibration energy exchange of $N_2(v=1)+O_2(v=0){\to}N_2(v=0)+O_2(v=1)$ has been investigated, in particular, at low temperatures. The energy exchange rate constants are calculated by use of the solution of the time-dependent Schrodinger equation with the interaction potential of the colliding molecule as a perturbation term. The predicted rate constants are significantly agree with a experimental values in the range of 295∼$90^{\circ}K$. The consideration of the VV-VT coupling decreases the predicted pure VV energy exchange value by a factor of ∼2. When the collision frequency correction is introduced, the VV-VT rate constant is consistent with the observed value in the liquid phase. The consideration of the population of the rotational energy level increases the VV-VT value significantly.

Studies on the Interaction of Alkyl Thiophosphinate with Precious Metals

  • 김동수
    • Bulletin of the Korean Chemical Society
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    • 제16권4호
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    • pp.321-325
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    • 1995
  • Adsorption mechanisms of diisobutyl dithiophosphinate (DIBDTPI) and diisobutyl monothiophosphinate (DIBMTPI) on gold and gold-silver alloys (80:20 and 50:50) have been studied. The adsorption mechanisms on gold-silver alloys can be explained by the EC mechanism involving an electron transfer step and a chemical reaction step. Thus, the adsorption should be controlled by the E of the electrochemical oxidation of the electrode involved and the pK of the metal collector complex. Both di- and mono- thiophosphinate adsorb on 50:50 Au-Ag alloy at lower potential than on 80:20 Au-Ag alloy surface. There are no significant differences between the reactivities of DIBDTPI and DIBMTPI with precious metals except that the dithio- compound can be oxidized to dimer on gold at high potentials, while the monothio- homologue cannot. In this regard, DIBDTPI may be a better surface active reagent for pure gold than DIBMTPI.

지능형 물류/농업분야의 로봇작업지능 기술 동향 (Technical Trends of Robot Task Intelligence in Intelligent Logistics/Agriculture)

  • 유원필;이유철;김동형
    • 전자통신동향분석
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    • 제36권2호
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    • pp.22-31
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    • 2021
  • This report introduces a definition for robot task intelligence and explains the basis of the challenges associated with implementing robot task intelligence in real-world problems. Two fundamental elements of this intelligence, robot manipulation and navigation, are introduced herein. We describe the existing trends and industrial applications of the robot task intelligence in logistics and agricultural automation. Furthermore, as an underpinning technology for this intelligence, we review the existing three-dimensional position estimation techniques and summarize the difficulties associated with applying pure SLAM technology to real-world applications. Finally, we discuss the prospects of the robot task intelligence research and its potential for solving real-world problems.

CHANGING RELATIONSHIP BETWEEN SETS USING CONVOLUTION SUMS OF RESTRICTED DIVISOR FUNCTIONS

  • ISMAIL NACI CANGUL;DAEYEOUL KIM
    • Journal of applied mathematics & informatics
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    • 제41권3호
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    • pp.553-567
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    • 2023
  • There are real life situations in our lives where the things are changing continuously or from time to time. It is a very important problem for one whether to continue the existing relationship or to form a new one after some occasions. That is, people, companies, cities, countries, etc. may change their opinion or position rapidly. In this work, we think of the problem of changing relationships from a mathematical point of view and think of an answer. In some sense, we comment these changes as power changes. Our number theoretical model will be based on this idea. Using the convolution sum of the restricted divisor function E, we obtain the answer to this problem.

Mixed matrix membranes for dye removal

  • Evrim Celik-Madenli;Dilara Kesiktas
    • Membrane and Water Treatment
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    • 제14권4호
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    • pp.175-180
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    • 2023
  • Mixed matrix membranes (MMMs) can be a promising alternative for the solution of dye removal from coloured effluents. Polymeric membranes are widely used due to their good film-forming ability, flexibility, separation properties, and cost. However, they have low mechanical, chemical, and thermal resistances. Moreover, the fouling of polymeric membranes is high because of their hydrophobic nature. Hence, there is an increasing interest in organic-inorganic hybrid membranes as a new-generation membrane material. It has been shown that carbon nanotubes have the potential to increase the material properties of polymers with their low density, high strength, hardness, and exceptional aspect ratio. In this work, carbon nanotubes blended MMMs were prepared and methyl orange removal efficiency of them was investigated. Compared to the bare membranes, MMMs showed not only increased hydrophilicity, water content, and pure water flux but also increased methyl orange rejection and flux recovery

Transaminases for Green Chemistry: Recent Progress and Future Prospects

  • Shreya Pandya;Akshaya Gupte
    • 한국미생물·생명공학회지
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    • 제51권4호
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    • pp.333-352
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    • 2023
  • Transaminase represents the most important biocatalysts used for the synthesis of chiral amines due to their stereoselectivity. They allow asymmetric synthesis with high yields and enantioselectivity from their corresponding ketones. Due to their environmentally friendly access for the preparation of chiral amines, they have attracted growing attention in recent times. Thus, the production of chiral compounds by transaminase catalysed reactions is considered as an important application in synthetic organic chemistry. Therefore, transaminase is considered to be an important enzyme in the pharmaceutical and chemical industries. ω-Transaminase holds great potential because of its wide substrate specificity thus making it a suitable enzyme to be used at an industrial scale. This review highlights the reaction mechanism, classification, substrate specificity, and biochemical properties. The review also showcases the application of ω-transaminase in organic chemistry with a focus on the production of active pharmaceutical ingredients (APIs).

Research on the Mechanical Properties of Some New Aluminum Alloy Composite Structures in Construction Engineering

  • Mengting Fan;Xuan Wang
    • 한국재료학회지
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    • 제34권2호
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    • pp.72-78
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    • 2024
  • The lightweight and high strength characteristics of aluminum alloy materials make them have promising prospects in the field of construction engineering. This paper primarily focuses on aluminum alloy materials. Aluminum alloy was combined with concrete, wood and carbon fiber reinforced plastic (CFRP) cloth to create a composite column. The axial compression test was then conducted to understand the mechanical properties of different composite structures. It was found that the pure aluminum tube exhibited poor performance in the axial compression test, with an ultimate load of only 302.56 kN. However, the performance of the various composite columns showed varying degrees of improvement. With the increase of the load, the displacement and strain of each specimen rapidly increased, and after reaching the ultimate load, both load and strain gradually decreased. In comparison, the aluminum alloy-concrete composite column performed better than the aluminum alloy-wood composite column, while the aluminum alloy-wood-CFRP cloth composite column demonstrated superior performance. These results highlight excellent performance potential for aluminum alloy-wood-CFRP composite columns in practical applications.

백서에서 삼차신경 유발전위의 특성과 경로 분석 (Characteristics of Trigeminal Evoked Potential and It's Pathway in the Rat)

  • 김세혁;조춘식;권오규;이배환;박용구;정상섭
    • Journal of Korean Neurosurgical Society
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    • 제29권8호
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    • pp.985-994
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    • 2000
  • Objective : There are some advantages of trigeminal evoked potential(TEP) recording compared to other somatosensory evoked potential(SSEP) recordings. The trigeminal sensory pathway has a pure sensory nerve branch, a broader receptive field in cerebral cortex, and a shorter pathway. Despite these advantages, there is little agreement as to what constitutes a normal response and what wave forms truly characterize the intraoperative TEP. This study presents the normative data of TEP recorded on the epidural surface of the rat with a platinum ball electrode. Materials & Methods : Under general anesthesia with urethane, the adult Sprague-Dawley male rats(300-350g) were given electrical stimulation with two stainless steel electrodes which were inserted into the subcutaneous layer of the area around whiskers. A reference electrode was positioned in the temporalis muscle ipsilateral to the recording site. Results : TEPs were recorded in the Par I area of somatosensory cortex and recorded most apparently on the point of 2mm posterior from the bregma and 6mm lateral from the midline. The typical wave form consisted of 5 peaks (N1-P1-N2-P2-N3 according to emerging order, upward negativity). Each latency to corresponding peaks was not influenced by the different intensities of stimulation, especially from 1 to 5mA. Average latencies of 5 peaks were in the following order ; 7.7, 11.1, 15, 22.3, 29.4ms. There was also no significant difference between latencies before and after administration of muscle relaxant(pancuronium). For the electrophysiological localization of recorded waves, the action potential of a single unit was recorded with glass microelectrode(filled with 2M NaCl, $3-5M{\Omega}$) in the thalamus of rat. A sharp wave was recorded in the VPM nucleus, in which the latency was shorter than that of N1. This suggests that all 5 peaks were generated by neural activities in the suprathalamic pathway. Conclusion : In terms of recording near-field potentials, our data also suggests that TEP in the rat may be superior to other SSEPs. In overall, these results may afford normative data for the studies of supratentorial lesions such as hydrocephalus or cerebral ischemia which can have an influence on near-field potentials.

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Effect of Ni dopant on the multiferroicity of BiFeO3 ceramic

  • Hwang, J.S.;Yoo, Y.J.;Kang, J.H.;Lee, K.H.;Lee, B.W.;Park, S.Y.;Lee, Y.P.
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.139.1-139.1
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    • 2016
  • Multiferroic materials are of great interest because of its potential applications in the design of devices combining magnetic, electronic and optical functionalities. Among various multiferroic materials, $BiFeO_3$(BFO) is known to be one of the intensively focused mainly due to the possibility of multiferroism at device working temperature (> $200^{\circ}C$). However, leakage current and weak polarization resulting from oxygen deficiency and crystalline defect should be resolved. Furthermore the magnetic ordering of pure BFO mainly prefers to have antiferromagnetic coupling. Up to now many attempts have been performed to improve the ferromagnetic and the ferroelectric properties of BFO by doping. In this work, we investigated the effects of Ni substitution on the multiferroism of bulk BFO. Four BFO samples (a pure BFO and three Ni-doped BFO's; $BiFe_{0.99}Ni_{0.01}O_3$, $BiFe_{0.98}Ni_{0.02}O_3$ and $BiFe_{0.97}Ni_{0.03}O_3$) were synthesized by the standard solid-state reaction and rapid sintering technique. The XRD results reveal that Ni atoms are substituted into Fe-sites and give rise to phase transition of cubic to rhombohedal. By using vibrating sample magnetometer and standard ferroelectric tester, the multiferroic properties at room temperature were characterized. We found that the magnetic moment of Ni-doped BFO turned out to be maximized for 3% of Ni dopant.

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