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A Study on the Change of the Plant Community Structure for Five years in Puk′ansan National Park (북한산 국립공원 삼림군집구조의 5년간 변화 연구)

  • 최송현;이경재
    • Korean Journal of Environment and Ecology
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    • v.7 no.1
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    • pp.35-48
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    • 1993
  • To compare ecological succession stage between 1987 and 1992, this study was executed in Mt. Puk'an. 26 sample plots of 500$m^2$ were set up. The results were summarized as follows; 1. To analysis plant community structure, the classification by TWINSPAN and CCA, DCA and RA ordination were applied to the study area. That of Mt. Puk'an was divided 4 groups by altitude. The dividing groups are Robinia pseudo-acacia-Quercus spp. community, mixed forest community, Q. serrata community, and Q. mongolica community. The successional trends of tree species over 500m seem to be from Pinus densiflora to Q. mongolica and below 500m in altitude seem to be from Robinia pseudo-acacia through Quercus acutissima, Q. mongolica, Prunus sargentii, Sorbus alnifolia to Q. serrata in the canopy layer. In the case of understory and shrub layer, the successional trends to be from Corylus sieboldiana, Zanthoxylum schinifolium through Rhus trichocarpa, Rhododendron mucronulatum, Rh. schlippenbachii to Acer pseudo-sieboldianum. 2. In comparing successional trends with 1987', the advanced data was not obtained in 1992. It was postulated that succession is not progressed by human disturbance and air pollution.

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An Investigative Study on the Characterization of Cefaclor Decomposition in UV/H$_2$O$_2$ Process (UV/H$_2$O$_2$공정에 의한 Cefaclor 분해 특성에 관한 기초연구)

  • Cho, Chun-Ki;Han, Ihn-Sup
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.10
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    • pp.1039-1046
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    • 2008
  • The combining process of UV irradiation and H$_2$O$_2$ was used to investigate characteristics of cefaclor decomposition in the aquatic environment. The separate mixing tank was used to minimize the decreasing effective of contact area caused by sampling. Four baffles were installed inside the UV reactor for the complete mixing of the sample and outside of the reactor was wrapped with aluminum foil to protect the emission of photon energy. Production of OH radical was measured using pCBA(p-Chlorobenzoic acid) indirectly and rate constants were withdrawn pseudo-frist order reaction. Optimum condition for the maximum production of OH radical was found to be pH 3, hydrogen peroxide of 5 mmol/L and recirculation rate of 400 mL/min. Pseudo-frist order reaction rate constant was 0.1051 min$^{-1}$. In the optimum condition, cefaclor was completely decomposed within 40 min and rate constant was 0.093 min$^{-1}$. Decomposition by OH radical producted intermediate anions such as chloride, nitrate, sulfite and acetic acid and phenylglycine. After 6 hr most cefaclor was decomposed by UV/H$_2$O$_2$ process and converted to CO$_2$ and H$_2$O, resulting of operation in the decrease of TOC and acetic acid and the disappearance of phenylglycine.

Analysis of the variability of deflection of a prestressed composite bridge deck

  • Staquet, Stephanie;Detandt, Henri;Espion, Bernard
    • Steel and Composite Structures
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    • v.4 no.5
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    • pp.385-402
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    • 2004
  • Nearly 400 composite railway bridge decks of a new kind belonging to the trough type with U-shaped cross section have been constructed in Belgium over the last fifteen years. The construction of these bridge decks is rather complex with the preflexion of precambered steel girders, the prestressing of a concrete slab and the addition of a 2nd phase concrete. Until now, they have been designed with a classical computation method using a pseudo-elastic analysis with modular ratios. Globally, they perform according to the expectations but variability has been observed between the measured and the computed camber of these bridge decks just after the transfer of prestressing and also at long-term. A statistical analysis of the variability of the relative difference between the measured camber and the computed camber is made for a sample of 36 bridge decks using no less than 10 variables. The most significant variables to explain this variability at prestressing are the ratio between the maximum tensile stress reached in the steel girders during the preflexion and the yield strength and the type of steel girder. For the same sample, the long-term camber under permanent loading is computed by two methods and compared with measurements taken one or two years after the construction. The camber computed by the step-by-step method shows a better agreement with the measured camber than the camber computed by the classical method. The purpose of the paper is to report on the statistical analysis which was used to determine the most significant parameters to consider in the modeling in order to improve the prediction of the behaviour of these composite railway bridge decks.

Microstructures and Thermal Properties of Water Quenched Thermoelectric Material in Bi2Te3-PbTe System (급속 응고 된 Bi2Te3-PbTe계 열전소재의 미세구조와 열전 특성)

  • Yim, Ju-Hyuk;Jung, Kyoo-Ho;You, Hyun-Woo;Kim, Kwang-Chon;Kim, Jin-Sang
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.6
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    • pp.502-507
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    • 2010
  • In order to design nano structured materials with enhanced thermoelectric properties, the alloys in the pseudo-binary $Bi_2Te_3$-PbTe system are investigated for their micro structure properties. For this synthesis, the liquid alloys are cooled by the water quenching method. Micro structure images are obtained by using an electron probe micro analyzer(EPMA). Dendritic and lamellar structures are clearly observed with the variation in the composition ratio between $Bi_2Te_3$ and PbTe. The increase in the $Bi_2Te_3$ composition ratio causes to change of the structure from dendritic to lamellar. The Seebeck coefficient of sample 5, in which the mixture rate of $Bi_2Te_3$ is 83%, is measured as the highest value. In contrast, the others decrease with the increase of the $Bi_2Te_3$ composition ratio. Meanwhile, p-type characteristics are observed in sample 6, at 91%-$Bi_2Te_3$ mixture rate. The power factors of the all samples are calculated with the Seebeck coefficient and resistivity.

Classification of Pollution Patterns in High School Classrooms using Disjoint Principal Component Analysis (분산주성분 분석을 이용한 고등학교교실 내 오염패턴분류에 관한 연구)

  • Jang, Choul-Soon;Lee, Tae-Jung;Kim, Dong-Sool
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.6
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    • pp.808-820
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    • 2006
  • In regard to indoor air quality patterns, the government introduced various polices that were about managing and monitoring quality of indoor air as a major assignment, and also executed 'Indoor Air Quality Management Act' which was presented in the May, 2004. However, among the multi-usage facilities controlled by the Act, the school was not included yet. This study goal was to investigate PM 10 pollution patterns of the high school classrooms using a pattern recognition method based on cluster analysis and disjoint principal component analysis, and further to survey levels of inorganic elements in May, June, and September, 2004. A hierarchical clustering method was examined to obtain possible objects in pseudo homogeneous sample classes by transformation raw data and by applying various distance. Following the analysis, the disjoint principal component analysis was used to define homogeneous sample class after deleting outliers. Then three homogeneous Patterns were obtained as follows: the first class had been separated and objects in the class were considered to be sampled under semi-open condition. This class had high concentration of Ca, Fe, Mg, K, Al, and Na which are related with a soil and a chalk compounds. The second class was obtained in which objects were sampled while working air-conditioners and was identified low concentration of PM 10 and elements. Objects in the last class were assigned during rainy day. A chalk, soil element and various types of anthropogenic sources including combustions and industrial influenced the third class. This methodology was thought to be helpful enough to classify indoor air quality patterns and indoor environmental categories when controlling an indoor air quality.

Biochemical Studies on Korean Fermented Foods. (IX) Variation of Vitamin $B_{12}$ during the Kimchi Fermentation Period (한국 발효식품에 대한 생물화학적 연구 (제9보) 침채류의 발효에 따르는 $VitaminB_{12}$의 변화에 대하여)

  • Lee, In-Jae;Haw, Kum;Kim, Sung-Ikk
    • YAKHAK HOEJI
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    • v.4 no.1
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    • pp.53-55
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    • 1959
  • In order to confirm on production of vitamin $B_{12}$ during the kimchi fermentation period, the variation of its content is studied in this paper As a sample of kimchi for this fermentation study due to the seasonal condition, nabakkimchi which is aseasonal one in early spring, is prepared by author. The content of vitamin $B_{12}$ is estimated by the microbiological assay method using lactobacillus leichmannii A Tee 7830. Details for assay are indicated in the original part. And the pseudo-vitamin $B_{12}$ substances as thymidine which is active to the growth of lactobacillus leichmannii, are eliminated by the alkali treatment method of sample solution, According to the results shown in table 2 and 3 and figures 1 to 4, the following conclusions are summerized; 1. Vitamin $B_{12}$ produced during the fermentation period of kimchi. And the content of this vitamin during its optimum fermentation period, is much higher content compared with the theoretically calculated amount from its materials, This has been confirmed at the repeated experiment. The trend of variation during its period is indicated at the figures. 2. The sterilized kimchi inhibited the fermentation by sterilization at the preparation, did not increased its content showing only its theoretically calculated amount.

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Performance evaluation of organic matter adsorption from actual graywater using GAC: OrbitrapTM MS and optimization

  • Ligaray, Mayzonee;Kim, Minjeong;Shim, Jaegyu;Park, Jongkwan;Cho, Kyung Hwa
    • Membrane and Water Treatment
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    • v.10 no.6
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    • pp.471-484
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    • 2019
  • The complex combination of organic contaminants in the wastewater made water treatment challenging; hence, organic matter in water bodies is usually measured in terms of organic carbon. Since it is important to identify the types of compounds when deciding suitable treatment methods, this study implemented a quantitative and qualitative analysis of the organic matter content in an actual graywater sample from Ulsan, Republic of Korea using mass spectroscopy (MS). The graywater was treated using adsorption to remove the organic contaminants. Using orbitrap MS, the organic matter content between an untreated graywater and the treated effluent were compared which yielded a significant formula count difference for the samples. It was revealed that CHON formula has the highest removal count. Isotherm studies found that the Freundlich equation was the best fit with a coefficient of determination ($R^2$) of 0.9705 indicating a heterogenous GAC surface with a multilayer characteristic. Kinetics experiments fit the pseudo-second order equation with an $R^2$ of 0.9998 implying that chemisorption is the rate-determining step between the organic compounds and GAC at rate constant of $52.53g/mg{\cdot}h$. At low temperatures, the reaction between GAC and organic compounds were found to be spontaneous and exothermic. The conditions for optimization were set to achieve a maximum DOC and TN removal which yielded removal percentages of 94.59% and 80.75% for the DOC and TN, respectively. The optimum parameter values are the following: pH 6.3, 2.46 g of GAC for every 30 mL of graywater sample, 23.39 hrs contact time and $38.6^{\circ}C$.

UC Model with ARIMA Trend and Forecasting U.S. GDP (ARIMA 추세의 비관측요인 모형과 미국 GDP에 대한 예측력)

  • Lee, Young Soo
    • International Area Studies Review
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    • v.21 no.4
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    • pp.159-172
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    • 2017
  • In a typical trend-cycle decomposition of GDP, the trend component is usually assumed to follow a random walk process. This paper considers an ARIMA trend and assesses the validity of the ARIMA trend model. I construct univariate and bivariate unobserved-components(UC) models, allowing the ARIMA trend. Estimation results using U.S. data are favorable to the ARIMA trend models. I, also, compare the forecasting performance of the UC models. Dynamic pseudo-out-of-sample forecasting exercises are implemented with recursive estimations. I find that the bivariate model outperforms the univariate model, the smoothed estimates of trend and cycle components deliver smaller forecasting errors compared to the filtered estimates, and, most importantly, allowing for the ARIMA trend can lead to statistically significant gains in forecast accuracy, providing support for the ARIMA trend model. It is worthy of notice that trend shocks play the main source of the output fluctuation if the ARIMA trend is allowed in the UC model.

Functionalized magnetite / silica nanocomposite for oily wastewater treatment

  • Hakimabadi, Seyfollah Gilak;Ahmadpour, Ali;Mosavian, Mohammad T. Hamed;Bastami, Tahereh Rohani
    • Advances in environmental research
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    • v.4 no.2
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    • pp.69-81
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    • 2015
  • A new magnetite-silica core/shell nanocomposite ($Fe_3O4@nSiO_2@mSiO_2$) was synthesized and functionalized with trimethylchlorosilane (TMCS). The prepared nanocomposite was used for the removal of diesel oil from aqueous media. The characterization of magnetite-silica nanocomposite was studied by X-ray diffraction (XRD), Fourier transform infrared (FTIR), transmission electron microscopy (TEM), surface area measurement, and vibrating sample magnetization (VSM). Results have shown that the desired structure was obtained and surface modification was successfully carried out. FTIR analysis has confirmed the presence of TMCS on the surface of magnetite silica nanocomposites. The low- angle XRD pattern of nanocomposites indicated the mesoscopic structure of silica shell. Furthermore, TEM results have shown the core/shell structure with porous silica shell. Adsorption kinetic studies indicated that the nanocomposite was able to remove 80% of the oil contaminant during 2 h and fit well with the pseudo-second order model. Equilibrium studies at room temperature showed that the experimental data fitted well with Freundlich isotherm. The magnetic property of nanocomposite facilitated the separation of solid phase from aqueous solution.

Reaction Mechanism and Kinetics of Degradation for Refractory Organic Pollutants in Water by Ultrasonic Irradiation

  • Sohn, Jong-Ryeul;Moon, Kyung-Hwan
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2003.06a
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    • pp.123-127
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    • 2003
  • This experiment was performed to investigate the characteristics of sonolytic reaction as the basic data for development of the ultrasonic AOP(Advanced Oxidation Process) process from which the refractory organic compounds in aqueous solution which are not readily removed by the existing conventional wastewater treatment processes can be destructed and removed. Trichloroethylene (TCE), benzene, and 2,4-dichlorophenol(DCP) were used as the samples, and their destruction efficiency were measured in terms of experimental parameters of the initial solution concentration, initial solution pH, reaction temperature, acoustic frequencies and intensities. Results showed that the destruction efficiencies of all of the sample materials were above 80% within 120 minutes of sonolytic reaction in all reaction condition. The reaction order of these three compounds was verified as Pseudo first order. From the fore-mentioned results, it can be concluded that the refractory organic compounds could be removed by the ultrasonic irradiation with radicals, such as H$.$and OH$.$causing the high increase of pressure and temperature. Finally, it appears that the new AOP technology using ultrasonic irradiation can be applied to the treatment of refractory substances which are difficult to be decomposed by the conventional methods.

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