• Membrane Journal
• /
• v.32 no.6
• /
• pp.486-495
• /
• 2022

This study presents the improved recovery efficiency of rare metal ions through the modified separation membrane wettability and hydrogen ion permeation in the anion exchange membrane (AEM) under the recovery process of combined electrodialysis and solvent extraction. Specifically, the wettability of the separator was enhanced by hydrophilic modification on one separator surface through polydopamine (PDA) and lipophilic modification on the other surface through SiO₂ or graphene oxide (GO). In addition, the modified surface of AEM with polyethyleneimine (PEI), PDA, poly(vinylidene fluoride) (PVDF), etc. reduces the water uptake and modify the pore structure for proton ions generation. The suppressed transport resulted in the reduced hydrogen ion permeation. In the characterization, the surface morphology, chemical properties and composition of membrane or AEM were analyzed with Scanning Electron Microscopy (SEM) and Fourier Transform-Infrared Spectroscopy (FT-IR). Based on the analyses, improved extraction and stripping and hydrogen ion transport inhibition were demonstrated for the copper ion recovery system.

• Journal of the Korean Solar Energy Society
• /
• v.32 no.spc3
• /
• pp.289-294
• /
• 2012

In recent years, understanding the dynamics of DC distribution system has become critically important due mainly to the increasing needs for the interconnection of DC distributed generators and the (DC-based) electric vehicle (EV) charging systems. In this paper, the characteristics of the DC grid system connected to the compact proton exchange membrane fuel cell (PEMFC) has been studied. In particular, the voltage and current transient phenomena were measured by varying the load of the DC grid system. Also, the voltage and current ripple were measured at the different load conditions. Our experimental results clearly manifested that the study contributes to the establishment of fundamental method to characterize the small DC grid system including distributed generation.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.31 no.12
• /
• pp.1173-1179
• /
• 2007

In recent years, research to machine large-surface micro-features has become important because of the light guide panel of a large-scale liquid crystal display and the bipolar plate of a high-capacity proton exchange membrane fuel cell. In this study, in order to realize the systematic design technology and performance improvements of an ultra-precision machine for machining the large-surface micro-features, a structural characteristic analysis was performed using its virtual prototype. The prototype consisted of gantry-type frame, hydrostatic feed mechanisms, linear motors, brushless DC servo motor, counterbalance mechanism, and so on. The loop stiffness was estimated from the relative displacement between the tool post and C-axis table, which was caused by a cutting force. Especially, the causes of structural stiffness deterioration were identified through the structural deformation analysis of sub-models.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.31 no.12
• /
• pp.1188-1193
• /
• 2007

This study focuses on the corrosion problems of STS316(stainless steel 316) tube for the cooling system of PEMFC (Proton Exchange Membrane Fuel Cell) operation. Deionized water which is highly corrosive is used especially for cooling agent of PEMFC to eliminate electrical conductivity, The tensile stress analysis was performed to check the change of mechanical strength of cooling line and pH of the water was monitored for the observation of extent of corrosion at simulated PEMFC operating condition. When STS316 tube was exposed to deionized water for 500 hours, substantial cracks were found on the surface and the pH of water was decreased from 6.8 to 5.8. For prevention of corrosion problems, the STS316 was coated by three kinds of fluororesin such as PTFE, FEP and ETFE. Among the coating materials, PTFE was the most protective in corrosive environment and was maintained the mechanical strength. To lower the cost, the same experimental analyses were carried out for iron tubes and the result will be discussed in detail.

• Transactions of the Korean hydrogen and new energy society
• /
• v.20 no.3
• /
• pp.216-223
• /
• 2009

The relation between temperature and hydrogen desorption on variation in output was investigated for the metal hydride canister. For this study, an AB$_5$ type alloy were chosen as a hydrogen storage material in the metal hydride canister. And application to the single proton exchange membrane fuel cell was evaluated. As the results, the hydrogen desorption was linearly increased as the temperature was risen. In addition, metal hydride canister heating was able to correspond the variation of load as power request in the PEMFC system.

• Proceedings of the Korean Society of Precision Engineering Conference
• /
• 2005.06a
• /
• pp.235-239
• /
• 2005

We analyzed the thermal and mechanical behaviors of micro reformer for the purpose of design verifications and modification of micro channels. The reformer designed for hydrogen generation from methanol is essential to PEM(Proton Exchange Membrane) type fuel cell. For the mobile applications, the size and the simplicity would be the most critical issues. We utilized silicon process for micro reformer to obtain the thickness thinner than 2 mm thick. We have used commercial simulation software, IDEAS, to analyze the thermal and mechanical characteristics of micro reformer structure. The heat generation rates of heaters, heat transfer rates, and fluid temperatures are derived from thermal equilibrium relation and these values were used for thermal boundary conditions. We also analyzed the thermal stresses, thermal deformations to examine the possibility of failure.

• 한국신재생에너지학회:학술대회논문집
• /
• 2005.11a
• /
• pp.541-544
• /
• 2005

This study presents the integrated modeling approach to simulate the proton exchange membrane (PEM) fuel cell system for vehicle application. The fuel cell system consisting of stack and balance of plant (BOP) was simulated with MATLAB/Simulink environment to estimate the maximum system power and investigate the effect of BOP component sizing on system performance and efficiency. The PEM fuel cell stack model was established by using a semi-empirical modeling. To maximize the net efficiency of fuel cel1 system, multi-variable optimization code was adopted. Using this method the optimized operating values were obtained according to various system net power levels. The fuel cell model established was co-linked to AVL CRUISE, a vehicle simulation package. Through the vehicle simulation software, the fuel economy of fuel cell powered electric vehicle for two types of driving cycles was presented and compared. It is expected that this study tan be effectively employed in the basic BOP component sizing and in establishing system operation map with respect to net power level of fuel cell system.

• Corrosion Science and Technology
• /
• v.9 no.3
• /
• pp.129-136
• /
• 2010

The corrosion behaviors of 316L stainless steel were investigated in simulated anodic and cathodic environments for proton exchange membrane fuel cell (PEMFC) by using electrochemical measurement techniques. Interfacial contact resistance(ICR) between the stainless steel and gas diffusion layer(GDL) was also measured. The possibility of 316L was evaluated as a substitute material for the graphite bipolar plate of PEMFC. The value of ICR decreased with an increase in compaction stress(20 N/$cm^2$~220 N/$cm^2$) showing the higher values than the required value in PEMFC condition. Although 316L was spontaneously passivated in simulated cathodic environment, its passive state was unstable in simulated anodic environment. Potentiostatic and electrochemical impedance spectroscopy (EIS) measurement results showed that the corrosion resistance in cathodic condition was higher and more stable than that in anodic condition. Field emission scanning electron microscopy (FE-SEM), and inductively coupled plasma(ICP) were used to analyze the surface morphology and the metal ion concentration in electrolytes.

• 한국신재생에너지학회:학술대회논문집
• /
• 2006.11a
• /
• pp.105-108
• /
• 2006

The fuel cell is one of the promising environment-friendly energy sources for the next generation. The fuel cell provides good energy efficiency above 40% without pollution or noise. Different fuel cell types are usually distinguished by the kind of electrolyte. Among these, the proton exchange membrane fuel cell (PEMFC) has advantages of high power density. low operating temperature, relatively quick start-up, and rapid response to varying loads. The bipolar plate is a major component of the PEM fuel cell stack, and it takes a large portion of stack volume, weight and cost. In this study, as alternative materials for bipolar plate of PEM fuel cells, graphite composites were fabricated by compression molding and by machining. Graphite particles mixed with epoxy resin were used as the main substance to provide electric conductivity. Flow channels were fabricated by compression molding with design of experiments (DOE) to evaluate moldability. The cost for compression molding of graphite-composite bipolar plate was compared with machining cost to make the same bipolar plate.

• The Transactions of The Korean Institute of Electrical Engineers
• /
• v.58 no.3
• /
• pp.531-538
• /
• 2009

The paper deals with an operation scheme to improve the forecasting of output range and to regulate the active power output of the hybrid system consisting of a doubly fed induction generator (DFIG) and a fuel-cell. The power output of the wind turbine fluctuates as the wind speed varies and the slip power between the rotor circuit and power converter varies as the rotor speed change. The power fluctuation of a DFIG makes its operation difficult when a DFIG is connected to grid. A fuel cell system can be individually operated and adjusted output power, hence the wind turbine and fuel cell hybrid system can overcome power fluctuation by using a fuel-cell power control. In this paper, a fuel-cell is performed to regulate the active power output in comparison with the regulated active power output of a DFIG. And it also improves the forecasting of output range. Based on PSCAD/EMTDC tools, a DFIG and a proton exchange membrane fuel cell(PEMFC) is simulated and the dynamics of the output power in hybrid system are investigated.