• Title/Summary/Keyword: Process Decomposition

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A Comparative Study on Litter Decomposition of Emergent Macrophytes in the Littoral Zone of Reservoir

  • Jo, Kang-Hyun;Gong, Hak-Yang
    • Animal cells and systems
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    • v.2 no.3
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    • pp.333-339
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    • 1998
  • Litter decomposition is a key process in energy flow and nutrient cycling in the freshwater littoral zone, and is regulated by physicochemical properties of litters. Using a litterbag method, we compared the decomposition rates of 16 different litter types from 10 plant species of the emergent macrophytes for one year in the littoral zone of the Paltangho Reservoir, Korea. The regression analysis fitted to the various decomposition models showed that mass loss of the litters with time best fitted an asymptotic function. The litters of the emergent macrophytes were composed of two compartments, labile and refractory. The macrophytic litters showed a great variety in decomposition dynamics depending on sources of litters. The labile compartment of the initial litter mass was in a wide range between 18% and 99%, and their decomposition rates varied from 0.0037 to 0.0131 day-1. The decomposition processes of the emergent macrophytes were determined by the relative amounts of the labile and refractory compartments and by the decomposition rate of the habile one in the littoral zone.

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Effect of $H_2O_2$ and Metals on The Sonochemical Decomposition of Humic Substances in Wastewater Effluent

  • Jung, Oh-Jun
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.10 no.S_3
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    • pp.127-137
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    • 2001
  • The sonochemical Process has been applied as a treatment method and was investigated its effect on the decomposition of humic substances(HS). The reaction kinetics and mechanisms in the Process of sonochemical treatment for humic substances(HS) in wastewater have also been discussed. It was observed that the metal ions such as Fe(II) and Mn(II) showed catalytic effects, while Al(III), Ca(II), and Mg(II) had inhibitory effects on the decomposition of humic substances in sonochemical reaction with hydrogen peroxide. Experimental results also showed factors such as hydrogen peroxide dose affected the formation of disinfection by-products. Two trihalomethanes, chloroform and dichlorobromomethane were formed as major disinfection by-products during chlorination. The mechanism of radical reaction is controlled by an oxidation process. The radicals are so reactive that most of them are consumed by HS radicals and hydroxyl radicals can be acted on organic solutes by hydroxyl addition, hydrogen abstraction, and electron transfer. The depolymerization and the radical reaction of HS radicals appear to occur simultaneously. The final steps of the reaction are the conversion of organic acids to carbon dioxide.

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Effects of word frequency and semantic transparency on decomposition processes of compound nouns (사용빈도와 의미투명도가 복합명사의 분리처리에 미치는 효과)

  • Lee, Tae-Yeon
    • Korean Journal of Cognitive Science
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    • v.18 no.4
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    • pp.371-398
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    • 2007
  • This study examined effects of word frequency and semantic transparency on decomposition processes of compound nouns by semantic priming task and repetition priming task. In Experiment 1, it was investigated that decomposition process depended on word frequency of compound noun. Semantic priming effects were found In the compound noun's associate rendition consistently, and repetition priming effects were found in the whole rendition as well as in the part condition irrespective of word frequency and SOA. These results implied that compound noun was processed through decomposition process path and direct access path. In Experiment 2, Effects of semantic transparency on decomposition processes of compound nouns were examined. Semantic priming effects were found when compound nouns' associates were presented as primes irrespective of semantic transparency and SOA, and results were the same as experiment 1b in repetition priming task. Results of experiment 1 and 2 implies that compound nouns are interpreted by interactive activation processes of attributes activated by decomposition path and direct access path.

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Studies on decomposition behavior of oxalic acid waste by UVC photo-Fenton advanced oxidation process

  • Kim, Jin-Hee;Lee, Hyun-Kyu;Park, Yoon-Ji;Lee, Sae-Binna;Choi, Sang-June;Oh, Wonzin;Kim, Hak-Soo;Kim, Cho-Rong;Kim, Ki-Chul;Seo, Bum-Chul
    • Nuclear Engineering and Technology
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    • v.51 no.8
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    • pp.1957-1963
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    • 2019
  • A UVC photo-Fenton advanced oxidation process (AOP) was studied to develop a process for the decomposition of oxalic acid waste generated in the chemical decontamination of nuclear power plants. The oxalate decomposition behavior was investigated by using a UVC photo-Fenton reactor system with a recirculation tank. The effects of the three operational variables-UVC irradiation, H2O2 and Fenton reagent-on the oxalate decomposition behavior were experimentally studied, and the behavior of the decomposition product, CO2, was observed. UVC irradiation of oxalate resulted in vigorous CO2 bubbling, and the irradiation dose was thought to be a rate-determining variable. Based on the above results, the oxalate decomposition kinetics were investigated from the viewpoint of radical formation, propagation, and termination reactions. The proposed UVC irradiation density model, expressed by the first-order reaction of oxalate with the same amount of H2O2 consumption, satisfactorily predicted the oxalate decomposition behavior, irrespective of the circulate rate in the reactor system within the experimental range.

Long -Term Settlement Behavior of Landfills with Consideration of Refuse Decomposition (분해가 고려된 쓰레기 매립지의 장기 침하 거동)

  • Park, Hyeon-Il;Lee, Seung-Rae;Go, Gwang-Hun
    • Geotechnical Engineering
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    • v.14 no.1
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    • pp.5-14
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    • 1998
  • In refuse landfill, long-term settlement is considerably dependent upon the biological decomposition of refuse which is distinguished from typical soil behavior. Two equations are combined in order to model long-term settlement behavior of refuse landfill caused by mechanical secondary compression and secondary compression caused by the decomposition of biolegradable refuse. It is suggested that mechanical secondary compression is linear with respcet to the logarithm of time. In order to estimate the settlement that occurs due. to the decomposition of biodegradable refuse, a mathematical model is used which theoretically conoiders the decomposition process related to the solubilization stage of biodegradable refuse solid. This model is based on hydrolysis process and expressed as first order kinetics. The proposed model is applied to Lysimeter compression data of an old refuse. This paper intends to propose the simplest mathematical model which effectively represents settlement caused by the solubilization stage of biodegradable refuse solid on decomposition process.

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Parallel Process System and its Application to Steam Generator Structural Analysis

  • Chang Yoon-Suk;Ko Han-Ok;Choi Jae-Boong;Kim Young-Jin
    • Journal of Mechanical Science and Technology
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    • v.19 no.11
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    • pp.2007-2015
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    • 2005
  • A large-scale analysis to evaluate complex material and structural behaviors is one of interesting topic in diverse engineering and scientific fields. Also, the utilization of massively parallel processors has been a recent trend of high performance computing. The objective of this paper is to introduce a parallel process system which consists of general purpose finite element analysis solver as well as parallelized PC cluster. The later was constructed using eight processing elements and the former was developed adopting both hierarchical domain decomposition method and balancing domain decomposition method. Then, to verify the efficiency of the established system, it was applied for structural analysis of steam generator in nuclear power plant. Since the prototypal evaluation results agreed well to the corresponding reference solutions it is believed that, after reinforcement of PC cluster by increasing number of processing elements, the promising parallel process system can be utilized as a useful tool for advanced structural integrity evaluation.

A Study on Thermal Characteristics on Polymeric Floorings (고분자물질 바닥재의 열적특성에 관한 연구)

  • Lee, Nae-Woo;Kim, Nam-Seok;Moon, Byoung-Soo
    • Journal of the Korean Society of Safety
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    • v.21 no.6 s.78
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    • pp.38-45
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    • 2006
  • Polymeric floorings mainly consisted of PVC are easily decomposed by many kinds of hot environmental factors, then generate hazardous asphyxiate gases and/or toxic gases etc. Therefore the mechanism of decomposition and quantitative toxic indices of products are very important for preventing safety and health disasters, especially in case of confined area. So we have investigated decomposition kinetics, numbers of process involved, toxicity indices of product and so on, using DSC, TGA, FT-IR and Pyrolyzer-GC/MS. The thermal decomposition process of polymeric floorings can be mainly divided by dehydrochlorinated reaction and polyene decomposition step, and activation energies of those are approximately $53.93{\sim}62.42kcal/mol$. Especially lethal concentration($LC_{50}$), fractional effective dose (FED) are calculated by measuring the amount of decomposition product. The values on $LC_{50}$ of sample G are ranged $2,003{\sim}2,019(mg/m^{3})$ in case of sample K and H are $1,877,\;1,998(g/m^{3})$ respectively. Even if the results are estimated by calculation method without animal test and/or clinical demonstration, these values could be very useful data for occupational health, hygiene and safety control.

Removal of High Strength Nitrogen in Dyeing Wastewater by Decomposition-Air Stripping Process (분해탈기법에 의한 염색폐수 중의 고농도 질소 제거에 관한 연구)

  • Cho, Byeung-Rak
    • Journal of the Korean Society of Industry Convergence
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    • v.5 no.3
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    • pp.213-218
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    • 2002
  • Total nitrogen is a major pollutant which mostly causes eutrophication and red tide. Wastewater effluent from printing of cotton-viscose rayon containing high concentrations of total nitrogen can not be effectively treated with a typical biological treatment process. This paper provides a new treatment process and experimental results for the removal of high strength nitrogen from dyeing wastewater. The optimum conditions of air stripping for the removal of total nitrogen include around pH 12, temperature $60^{\circ}C$ with 60 minutes of stripping time. In case of a filtration-air stripping process, an initial level ($500mg/{\ell}$) of total nitrogen was significantly reduced to below $60mg/{\ell}$. Deconite was synthesised for further decomposition of organic nitrogen. Thus, a filtration-decomposition-air stripping process was possibly achieved, by which a high level ($900mg/{\ell}$) of total nitrogen was effectively removed to below $60mg/{\ell}$ P. Finally, a continuous new process for the removal of total nitrogen is proposed and confirmed, based on batch experimental results, and its process validity is further discussed throughout.

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Effect of Ultrasonic Irradiation on Ozone Nanobubble Process for Phenol Degradation (페놀 분해를 위한 오존 나노기포 공정에서 초음파 조사의 영향)

  • Lee, Sangbin;Park, Jae-Woo
    • Journal of the Korean GEO-environmental Society
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    • v.23 no.3
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    • pp.23-29
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    • 2022
  • In this study, we investigated the ozone nanobubble process in which nanobubble and ultrasonic cavitation were applied simultaneously to improve the dissolution and self-decomposition of ozone. To confirm the organic decomposition efficiency of the process, a 200 mm × 200 mm × 300 mm scale reactor was designed and phenol decomposition experiments were conducted. The use of nanobubble was 2.07 times higher than the conventional ozone aeration in the 60 minutes reaction and effectively improved the dissolution efficiency of ozone. Ultrasonic irradiation increased phenol degradation by 36% with nanobubbles, and dissolved ozone concentration was lowered due to the promotion of ozone self-decomposition. The higher the ultrasonic power was, the higher the phenol degradation efficiency. The decomposition efficiency of phenol was the highest at 132 kHz. The ozone nanobubble process showed better decomposition efficiency at high pH like conventional ozone processes but achieved 100% decomposition of phenol after 60 minutes reaction even at neutral conditions. The effect by pH was less than that of the conventional ozone process because of self-decomposition promotion. To confirm the change in bubble properties by ultrasonic irradiation, a Zetasizer was used to measure the bubbles' size and zeta potential analysis. Ultrasonic irradiation reduced the average size of the bubbles by 11% and strengthened the negative charge of the bubble surface, positively affecting the gas transfer of the ozone nanobubble and the efficiency of the radical production.

Operability of Composting Facilities by Modeling (모델링에 의한 퇴비화 시설의 운전성에 관한 연구)

  • Yoo, Yeong Seok;Kim, I Tae;Gee, Chai Sung
    • Journal of the Korea Organic Resources Recycling Association
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    • v.3 no.2
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    • pp.59-68
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    • 1995
  • Composting facilities are operated with air and moisture control. Composting effects on two operating factors was analysed changing aeration rate with and without water addition to maintain the optimun moisture level. Though the composting facilties are provided with appropriate surroundings for compositing, operating temperature is set for decomposition rate. Accordingly control of decomposition phases was analysed by modeling the process of high and low decomposition phases with various operating temperature. A composting model of "The Library of Compost Engineering Software" developed by Roger T. Haug Inc. in U.S.A. was applied in modeling. As result of this study, operation with optimum moisture has more sensitive temperature to aeration fluctuation and lead to higher reaction rate with lower aeration than operation with poor moisture. Decomposition rate in composting facilities depend on slow decomposition phase because high rate decomposing substances already have been decomposed before entire process is not completed. In order to enhance decomposition rate of organics, effective decomposition in slow decomposition phase needs to be focused.

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