• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2011년도 춘계학술대회 초록집
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• pp.179.1-179.1
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• 2011

Pretreatment of cellulosic biomass is necessary before enzymatic saccharification and fermentation. The objective of this study was to evaluate the effect of combined aqueous ammonia-dilute sulfuric acid treatment on cellulosic biomass. Miscanthus was pretreated using aqueous ammonia and dilute sulfuric acid solution under high temperature and pressure conditions to be converted into bioethanol. Aqueous ammonia treatment was performed with 15 %(w/w) ammonia solution at $150^{\circ}C$ of reaction temperature and 20 minutes of reaction time. And then, dilute sulfuric acid treatment was performed with 1.0 %(w/w) sulfuric acid solution at $150^{\circ}C$ of reaction temperature and 10 minutes of reaction time. The compositional variations of this combined aqueous ammonia-dilute sulfuric acid treatment resulted in 68.0 % of cellulose recovery and 95.7 % of hemicellulose, 81.3 % of lignin, 89.1 % of ash removal respectively. The enzymatic digestibility of 90.5 % was recorded in the combined pretreated Miscanthus sample and it was 14.7 times higher than the untreated sample. The ethanol yield in the Simultaneous Saccharification and Fermentation was 90.4 % of maximum theoretical yield based on cellulose content of the combined pretreated sample and it was about 98 % compared to the ${\alpha}$-cellulose ethanol yield.

• Membrane and Water Treatment
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• 제8권3호
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• pp.279-292
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• 2017

This study was aimed at ultrafiltration (UF) as a pretreatment before reverse osmosis (RO) within the scheme of hybrid reverse osmosis-multistage flush (RO-MSF) desalination. Seawater at elevated temperature (after MSF heat-exchangers) was used as a feed in this process. The pretreatment system was represented as a set of functionally-linked technological segments such as: UF filtration, backwashing, chemical- enhanced backwashing, cleaning, waste disposal, etc. The process represents the sequences of operating cycles. The cycle, in turn, consists of the following unit operations: filtration, backwashing and chemical-enhanced backwashing (CEB). Quantitative assessment was based on the following indicators: normalized permeability, transmembrane pressure, specific energy and water consumption, specific waste generation. UF pre-treatment is accompanied by the following waste streams: $W1=1.19{\times}10$ power of $-2m^3$ (disposed NaOCl with 0.0044% wt.)/$m^3$ (filtrate); $W2=5.95{\times}10$ power of $-3m^3$ (disposed $H_2SO_4$ with 0.052% wt.)/$m^3$(filtrate); $W3=7.26{\times}10$ power of $-2m^3$ (disposed sea water)/$m^3$ (filtrate). Specific energy consumption is $1.11{\times}10$ power of $-1kWh/m^3$ (filtrate). The indicators evaluated over the cycles with conventional (non-chemical) backwashing were compared with the cycles accompanied by CEB. A positive impact of CEB on performance indicators was demonstrated namely: normalized UF resistance remains unchanged within the regime accompanied by CEB, whereas the lack of CEB results in 30% of its growth. Those quantitative indicators can be incorporated into the target function for solving different optimization problems. They can be used in the software for optimisation of operating regimes or in the synthesis of optimal flow- diagram. The cycle characteristics, process parameters and water quality data are attached.

• 대한환경공학회지
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• 제35권3호
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• pp.200-205
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• 2013

전처리 공정은 막의 오염 정도를 제어할 수 있는 유일한 방법이다. 막의 오염 현상은 피할 수 없는 중요한 문제이며 RO 공급수로 적합한 전처리 공정의 선택이 중요하다. 본 연구는 pH, 해수의 탁도, 수온, 응집제 주입량 그리고 SDI 측정 막재질과 같은 SDI 값에 영향을 미치는 인자들을 평가 하기위해 수행되었다. 그 결과 해수의 탁도는 여과수의 SDI 값에 약간의 영향을 미친것으로 조사되었다. 0.45 um 공극 크기를 가지는 SDI 측정 막은 소수성 막 보다 동일한 재질의 친수성 막을 이용하는 것이 분석 결과의 신뢰성과 재현성을 확보할 수 있었다. pH 7.0 이하의 조건에서 pH가 감소할수록 SDI 값은 증가한 것으로 나타났다. 그리고 수온은 SDI 값은 큰 영향을 미친것으로 조사되었다.

• 대한정형도수물리치료학회지
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• 제12권1호
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• pp.37-43
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• 2006

PURPOSE: Previous studies have documented the lack of ultrasound's non-thermal effects on nerve conduction using frequencies of 1 MHz and 870 kHz. The purpose of this study was to determine the biophysical effects of continuous ultrasound on median local forearm temperature and motor nerve conduction velocities using frequencies of 3.0 MHz. SUBJECTS: Twelve healthy subjects (6 males, 6 females, age $22.30{\pm}2.41$ yrs, weight $61.33{\pm}10.16$ kg, height $167.58{\pm}8.04$ cm) without a history of neurological or musculoskeletal injury to their dominant arm volunteered for this study. METHODS AND MATERIALS: Each subject received a total of five treatments, one each at .0, 0.5, 1.0, 1.5, 2.0 W/$cm^2$ of 3 MHz continuous ultrasound on the anterior surface of the middle area of dominant forearm for 10 minutes. Dependent measures for forearm local temperature and median motor nerve conduction velocity (MNCV) were taken pretreatment and immediately post-treatment. One-way ANOVA were used for each dependent measure. RESULTS: The posttreatment forearm local temperature were differed significantly (p<0.001) between intensities of ultrasound. The posttreatment forearm local temperature of the ultrasound treated with 1.0 w/$cm^2$, 1.5 w/$cm^2$ and 2.0 w/$cm^2$ were significantly higher than 0.5 w/$cm^2$ and 0.0 w/$cm^2$ of ultrasound (p<0.05). The posttreatment median MNCV were differed significantly from the respective pretreatment velocities (p<0.001). The MNCV of the ultrasound treated with 0.0 w/$cm^2$ and 0.5 w/$cm^2$ were significantly (p<0.05) slower than that observed pretreatment, while the three ultrasound intensities produced significantly increased posttreatment MNCV: 1.0 w/$cm^2$ and 1.5 w/$cm^2$ and 2.0 W/$cm^2$. The posttreatment MNCV at 2.0 w/$cm^2$ and 1.5 w/$cm^2$ was significantly faster than that at 0 w/$cm^2$, 0.5 w/$cm^2$ and 1.0 w/$cm^2$ (p<0.05), the MNCV at 1.0 w/$cm^2$ was significantly faster than that associated with 0 w/$cm^2$ and 0.5 w/$cm^2$ of ultrasound (p<0.05). CONCLUSIONS: The decreased median motor forearm local temperature and MNCV of the ultrasound treated with 0.0 w/$cm^2$ and 0.5 w/$cm^2$ were attributed to the cooling effect by ultrasound transmission gel. Local forearm temperature and nerve conduction velocity were directly related to the intensity of ultrasound. Alterations in MNCV from ultrasound on healthy nerves appeared to be related to temperature changes induced by thermal effects of ultrasound.

• KSBB Journal
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• 제24권6호
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• pp.527-532
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• 2009

본 연구에서는 바이오 에탄올 생산을 위한 보릿짚의 전처리에 ethanosolv 방법을 적용하여 그 타당성을 조사하였다. 리그닌제거율은 처리 온도와 시간에 따라 증가 하였으며 $180^{\circ}C$, $200^{\circ}C$에서 거의 38%정도의 비슷한 제거율을 보였는데 비용절감 등의 부분을 감안할 때 $180^{\circ}C$, 120 min가 적정조건이라는 결론을 얻었다. ethanosolv 전처리 효과를 증대시키기 위하여 2단계의 전처리 방법을 적용하였다. 볶은 후 ethanosolv 한 보릿짚의 경우 리그닌 제거율은 35%정도로 그렇지 않은 경우와 거의 유사하여 볶음이 리그닌제거율에 큰 영향을 미치지 않음을 확인 할 수 있었다. XRD분석을 통하여 전처리 시간과 온도가 증가할수록 결정성은 감소하였다. 볶은 후 ethanosolv 한 것과 ethanosolv 단독 처리한 보릿짚 사이의 결정성은 미소하지만 물리적 변형을 한 단계 더 겪은 볶은 보릿짚이 전체적으로 낮게 나타났다.

• 한국식품조리과학회지
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• 제15권5호
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• pp.490-499
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• 1999

한우암소의 양지머리(brisket)와 사골(shank)을 전처리 방법, 가열 온도 및 시간에 따른 곰국의 맛성분 변화를 연구하기 위하여 유리아미노산과 핵산관련물질을 분석하고 색도 측정과 관능평가를 병행한 결과를 다음과 같이 요약할 수 있었다. 1. Soaking, blanching 전처리 양지머리 곰국의 유리아미노산 용출량은 대체로 가열시간에 따라 증가하는 경향이었으며 용출량은 고온가결 보다 저온가열시에 많았으나 roasting 전처리 곰국은 고온 가열시의 용출량이 높았다. Glutamic acid 용출량은 대체로 soaking＞blanching> roasting의 순으로 많았으며 저온에서 6시간 가열시료 (BSL)의 용출량이 8.73 mg%로 가장 많았고 1시간 가열시의 17배 정도였다. 2. 사골(shank) 곰국 중의 유리아미노산 용출량은 전처리법에 따른 일정한 경향이 없었으며 용출량도 매우 적었다. Glutamic acid 용출량은 저온가열시에는 일정한 경향은 볼 수 없었으나 soaking, blanching 전처리하여 고온가열 3시간 시료에서, roasting처리하여 고온 가열 6시간 시료가 2.49 mg%로 최고치를 보였다. 3. 양지머리 곰국 중 핵산관련 물질의 용출량은 대체로 가열에 따라 증가하는 경향이었다. Soaking, blanching 전처리하여 저온가열 한 시료의 5'-IMP 용출량은 6시간 가열한 시료(BSL)가 37.06%, 5 시간 가열한 시료(BBL)이 38.37 mg%로 최고치를 보였으며 roasting 전처리하여 고온가열 6시간 시료(BRH)가 10.85 mg%로 최고치를 보였다. 4. 사골곰국의 5'-IMP 용출량은 soaking＞blanching>roasting 전처리 순으로 많이 용출 되었으며 대체로 고온 가열시 높은 용출량을 보였으며 soaking, blanching 전처리시료는 가열 온도와 관계 없이 3시간 가열 이후 부터는 감소하는 경향이었다. Roasting 처리하여 고온가열 6시간 시료의 5'-IMP 용출량은 1.55 mg%로 최고치를 보였다. 5. Roasting 전처리 고온가열 양지머리 곰국(BRH)의 색차계에 의한 L값은 가장 낮았으며 b값은 가장 높은 값을 보였으나 사골곰국의 L, a, b 값은 전처리 방법이나 가열 온도에 따른 차이는 크지 않았다. 6. 양지머리 곰국의 색ㆍ향에 대한 관능평가는 roasting 전처리 고온가열시료(BRH)의 선호도가 가장 높았으며 맛 전반적 기호에 대한 선호도는 soaking 전처리 고온가열시료(BSH)가 가장 높았으며, 사골곰국의 경우에는 soaking 전처리 고온가열시료(SSH)의 모든 관능적 특성의 선호도가 가장 높았다.

• Journal of the Korean Wood Science and Technology
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• 제44권5호
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• pp.677-684
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• 2016

본 연구에서는 배할과 자상-인사이징 처리가 두께 15 cm 크기 소나무 정각재의 고온건조 특성에 미치는 영향을 확인하기 위해 수행되었다. 건조 후 최종함수율은 5.6% ~ 7.5% 범위였으며, 전처리조건에 따른 함수율분포에 차이는 없는 것으로 조사되었다. 배할의 경우 재면할렬 발생을 감소시키는 것이 가능하였으며, 뒤틀림은 약간 감소되는 경향을 나타내었다. 배할과 자상-인사이징 처리는 내부할렬과 건조 수축률에 영향을 미치지 않는 것으로 나타났다.

• Korean Chemical Engineering Research
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• 제54권1호
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• pp.70-74
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• 2016

본 연구에서는 창자파래(Enteromorpha intestinalis)로부터 citrate buffer를 사용하여 전처리 조건(고액비, 반응온도, buffer의 pH와 농도)에 따른 전처리 반응과 효소가수분해를 통한 가수분해 수율을 조사하였다. 0.25 M, pH 3.5의 citrate buffer를 이용하여 $140^{\circ}C$에서 60분간 전처리를 수행한 결과, 5.40%의 가수분해 수율을 얻었다. 최종적으로 전처리 반응 후 24시간의 효소 가수분해를 통하여 18.68%의 가수분해 수율을 얻었다. 이 결과는 대조구에 비하여 약 1.81배 증가한 결과이다.

• KSBB Journal
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• 제27권3호
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• pp.137-144
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• 2012

Among various pretreatment processes for bioethanol production, extrusion pretreatment, one of cheap and simple process was investigated to efficiently produce fermentable sugars from micro alga, Chlorella sp. The biomass was pretreated in a single screw extruder at five different barrel temperatures of 45, 50, 55, 60 and $65^{\circ}C$, respectively with five screw rotation speed of 10, 50, 100, 150 and 200 rpm. The pretreated biomass was reacted with two different hydrolyzing enzymes of cellulase and amyloglucosidase since the biomass contained different types of carbohydrates, compared to cellulose of agricultural by-products such wheat and corn stovers, etc. In general, higher glucose conversion yield was obtained as 13.24 (%, w/w) at $55^{\circ}C$ of barrel temperature and 100 rpm of screw speed conditions. In treating 5 FPU/glucan of cellulase and 150 Unit/mL of amyloglucosidase, ca. 64% of cellulose and 40% of polysaccharides in the micro alga were converted into glucose, which was higher yields than those from other reported data without applying an extrusion process. 84% of the fermentable sugars obtained from the hyrolyzing processes were fermented into ethanol in considering 50% of theoretical maximum fermentation yield of the yeast. These results implied that high speed extrusion could be suitable as a pretreatment process for the production of bioethanol from Chlorella sp.

• Journal of Ecology and Environment
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• 제41권7호
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• pp.191-201
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• 2017

Background: Limited availability of corn stover due to the competing uses (organic manure, animal feed, bio-materials, and bioenergy) presents a major concern for its future in the bio-economy. Furthermore, biomass research has exhibited different results due to the differences in the supply of enzymes and dissimilar analytical methods. The effect of the two leading pretreatment techniques (dilute acid and alkaline) on glucose yield from three corn stover fractions (cob, stalk, and leaf) sourced from a single harvest in Uganda were studied at temperatures 100, 120, 140, and $160^{\circ}C$ over reaction times of 5, 10, 30, and 60 min. Results: From this study, the highest glucose concentrations obtained from the dilute acid (DA) pretreated cobs, stalks, and leaves were 18.4 g/L (66.8% glucose yield), 16.2 g/L (64.1% glucose yield), and 11.0 g/L (49.5% glucose yield), respectively. The optimal pretreatment settings needed to obtain these yields from the DA pretreated samples were at a temperature of $160^{\circ}C$ over an incubation time of 30 min. The highest glucose concentrations obtained from the alkaline (AL) pretreated cobs, stalks, and leaves were 24.7 g/L (81.73% glucose yield), 21.3 g/L (81.23% glucose yield), and 15.0 g/L (51.92% glucose yield), respectively. To be able to achieve these yields, the optimal pretreatment settings for the cobs and stalks were $140^{\circ}C$ and for a retention time of 30 min, while the leaves require optimal conditions of $140^{\circ}C$ and for a retention time of 60 min. Conclusions: The study recommends that the leaves could be left on the field during harvesting since the recovery of glucose from the pretreated cobs and stalks is higher.