• Title/Summary/Keyword: Pressure-distribution

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Stability of the growth process at pulling large alkali halide single crystals

  • V.I. Goriletsky;S.K. Bondarenko;M.M. Smirnov;V.I. Sumin;K.V. Shakhova;V.S. Suzdal;V.A. Kuznetzov
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.13 no.1
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    • pp.5-14
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    • 2003
  • Principles of a novel pulse growing method are described. The method realized in the crystal growing on a seed from melts under raw melt feeding provided a more reliable control of the crystallization process when producing large alkali halide crystals. The slow natural convection of the melt in the crucible at a constant melt level is intensified by rotating the crucible, while the crystal rotation favors a more symmetrical distribution of thermal stresses over the crystal cross-section. Optimum rotation parameters for the crucible and crystal have been determined. The spatial position oi the solid/liquid phase interface relatively to the melt surface, heaters and the crucible elements are considered. Basing on that consideration, a novel criterion is stated, that is, the immersion extent of the crystallization front (CF) convex toward the melt. When the crystal grows at a <> CF immersion, the raised CF may tear off from the melt partially or completely due to its weight. This results in avoid formation in the crystal. Experimental data on the radial crystal growth speed are discussed. This speed defines the formation of a gas phase layer at the crystal surface. The layer thickness il a function of time a temperature at specific values of pressure in the furnace and the free melt surface dimensions in the gap between the crystal and crucible wall. Analytical expressions have been derived for the impurity component mass transfer at the steady-state growth stage describing two independent processes, the impurity mass transfer along the <> path and its transit along the <> one. The heater (and thus the melt) temperature variation is inherent in any control system. It has been shown that when random temperature changes occur causing its lowering at a rate exceeding $0.5^{\circ}C/min$, a kind of the CF decoration by foreign impurities or by gas bubbles takes place. Short-term temperature changes at one heater or both result in local (i.e., at the front) redistribution of the preset axial growth speed.

Preparation of Monodispersed Silica-Rubitherm®Microparticles Using Membrane Emulsification and Their Latent Heat Properties (막유화법을 이용한 단분산성 실리카-루비덤® 마이크로 입자의 제조 및 잠열 특성)

  • Kim, Soo-Yeon;Jung, Yeon-Seok;Lee, Sun-Ho;You, Jin-Oh;Youm, Kyung-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.2
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    • pp.215-225
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    • 2015
  • Recently, the importance of energy saving and alternative energy is significantly increasing due to energy depletion and the phase change material (PCM) research for saving energy is also actively investigating. In this research, the membrane emulsification using SPG membrane was used to make various microencapsulated phase change material (MPCM) particles which were comprised of $Rubitherms^{(R)}$ (RT-21 and RT-24) core and silica coating. We investigated the pressure of the dispersion phase, the concentration of surfactant, and the ratio of $Rubitherm^{(R)}$ and silica to prepare various MPCM particles. The DSC and TGA were used to examine the heat stability and latent heat properties. Also, PSA, SEM, and optical microscopy were used to confirm the size of $Rubitherm^{(R)}$ particles and the thickness of silica shell. The average of particle size was $7-8{\mu}m$. And, FT-IR was also used to enforce the qualitative analysis. Finally, the MPCM particles obtained from membrane emulsification showed monodispersed size distribution and the heat stability and latent heat were kept up to 80% compared to pure $Rubitherm^{(R)}$. So, it can be effectively used for wallpaper, buildings and interior products for energy saving as PCMs.

Analysis of Factors Related to Pain Relief on Modified Mammography (변형 유방촬영술시 통증완화에 따른 요인 분석)

  • Jang, Myung Mi;Kim, Hwa Sun
    • Journal of the Korean Society of Radiology
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    • v.11 no.5
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    • pp.413-421
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    • 2017
  • Mammography, the basic test for finding and treating increased breast cancer, gives the anxiety of cancer and radiation exposure to most women. In addition, it gave very severe compression pain, so we studied the degree of pain and tried to reduce the pain. The purpose of this study is to compare and analyze the modified imaging technique and the basic imaging technique based on clinical experience, respectively. The subjects of this study were 160 women from 30 to 60 years old who visited to Seoul Boramae Hospital operated by Seoul National University Hospital from February to March 2017 for breast screening. Modified 80 persons and 80 persons were divided into two groups, and each group was asked to fill out questionnaires sequentially without knowing the subjects. The first method is a modified method in which an automatic pedal is divided into four or more presses, a manual pressure is used together, and an attitude is described in detail. Secondly, we used only the automatic pedal compression method and press it within 1-3 times. In the mean of the pain distribution, the experimental group (modified method) was 2.49 and the control group (basic method) had an average of 4.86, which showed 48.8% less pain. In this modified method, the pain scores of the experimental group were lower than those of the control group, and the degree of the pain was statistically significant.

A Statistical Analysis of External Force on Electric Pole due to Meteorological Conditions (기상현상에 의한 전주 외력의 통계적 분석)

  • Park, Chul Young;Shin, Chang Sun;Cho, Yong Yun;Kim, Young Hyun;Park, Jang Woo
    • KIPS Transactions on Computer and Communication Systems
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    • v.6 no.11
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    • pp.437-444
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    • 2017
  • Electric Pole is a supporting beam used for power transmission/distribution which is sensitive to external force change of environmental factors. Therefore, power facilities have many difficulties in terms of maintenance/conservation from external environmental changes and natural disasters that cause a great economic impact. The aerial wire cause elasticity due to the influence of temperature, or factors such as wind speed and wind direction, that weakens the electric pole. The situation may lead to many safety risk in day-to-day life. But, the safety assessment of the pole is carried out at the design stage, and aftermath is not considered. For the safety and maintenance purposes, it is very important to analyze the influence of weather factors on external forces periodically. In this paper, we analyze the acceleration data of the sensor nodes installed in electric pole for maintenance/safety purpose and use Kalman filter as noise compensation method. Fast Fourier Transform (FFT) is performed to analyze the influence of each meteorological factor, along with the meteorological factors on frequency components. The result of the analysis shows that the temperature, humidity, solar radiation, hour of daylight, air pressure, wind direction and wind speed were influential factors. In this paper, the influences of meteorological factors on frequency components are different, and it is thought that it can be an important factor in achieving the purpose of safety and maintenance.

Production of Silver Impregnated Bamboo Activated Carbon and Reactivity with NO Gases (은첨착 대나무 활성탄의 제조와 NO 가스 반응 특성)

  • Bak, Young-Cheol;Choi, Joo-Hong;Lee, Geun-Lim
    • Korean Chemical Engineering Research
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    • v.52 no.6
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    • pp.807-813
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    • 2014
  • The Ag-impregnated activated carbon was produced from bamboo activated carbon by soaking method of silver nitrate solution. The carbonization and activation of raw material was conducted at $900^{\circ}C$. Soaking conditions are the variation of silver nitrate solution concentration (0.002~0.1 mol/L) and soaking time (maximum 24 h). The specific surface area and pore size distribution of the prepared activated carbons were measured. Also, NO and activated carbon reaction were conducted in a thermogravimetric analyzer in order to use for de-NOx agents of used activated carbon. Carbon-NO reactions were carried out with respect to reaction temperature ($20{\sim}850^{\circ}C$) and NO gas partial pressure (0.1~1.8 kPa). As results, Ag amounts are saturated within 2h, Ag amounts increased 1.95 mg Ag/g (0.2%)~ 88.70 mg Ag/g (8.87%) with the concentration of silver nitrate solution in the range of 0.002~0.1 mol/L. The specific volume and surface area of bamboo activated carbon of impregnated with 0.2% silver were maximum, but decreased with increasing Ag amounts of activated carbon due to pore blocking. In NO reaction, the reaction rate of impregnated bamboo activated carbon was retarded as compare with that of bamboo activated carbon. Measured reaction orders of NO concentration and activation energy were 0.63[BA], 0.69l[BA(Ag)] and 80.5 kJ/mol[BA], 66.4 kJ/mol[BA(Ag)], respectively.

Steam Reforming of Methanol for the Production of Hydrogen (수소제조를 위한 메탄올의 수증기 개질반응)

  • Kim, Sang-Chai;Jung, Chan-Hong;Yu, Eui-Yeon
    • Applied Chemistry for Engineering
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    • v.7 no.2
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    • pp.261-268
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    • 1996
  • Various $Cu/SiO_2$ catalysts with copper concentration ranging from 0 to 50wt% were prepared by kneading method for the steam reforming of methanol. These catalysts were calcined at temperatures in the range of $400^{\circ}C{\sim}900^{\circ}C$ and then reduced in a $H_2$ atmosphere in the range of $150^{\circ}C{\sim}350^{\circ}C$. Steam reforming of methanol was carried out at atmospheric pressure over a temperature range of $200^{\circ}C{\sim}400^{\circ}C$, steam/methanol molar ratio of 0.4~1.6 and W/F of 3~25 g.-cat.hr./mol. Characterization of the catalysts was studied using IR, BET and XRD. Using copper nitrate as a precursor for catalysts, pH in the preparation of catalysts had a great effect on the catalytic activity, but pH in the preparation of catalysts, calcination temperature, and reducing temperature in $H_2$ atmosphere had no effect on the product distribution. Optimum copper concentration, calcination temperature and reducing temperature were 40wt%, $700^{\circ}C$ and $300^{\circ}C$, respective)y. Reaction temperature for maximum $H_2$ production was $275^{\circ}C$, and the formation of methane which lowered quantity and quality of $H_2$ would be inhibited below $275^{\circ}C$. $Cu^{\circ}-Cu_2O$ might be active species in $Cu/SiO_2$ catalyst.

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Thermodynamic Study of Poly(dimethylsiloxane)-Solvents Systems Using Inverse Gas Chromatography (Inverse Gas Chromatography를 이용한 Poly(dimethylsiloxane)-Solvent계의 열역학적 연구)

  • Cho, Joung-Mo;Kang, Choon-Hyoung
    • Applied Chemistry for Engineering
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    • v.10 no.5
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    • pp.718-725
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    • 1999
  • In order to investigate the interaction characteristics of poly(dimethylsiloxane) (PDMS) with various solvents such as water, ethanol, and iso-propanol, Inverse Gas Chromatography(IGC) at finite concentration, which is a very fast, accurate, and thus promising technique in thermodynamic study of polymer systems, is employed. By measuring the specific retention volumes of the probes, the interaction parameters are calculated by means of the Flory-Huggins equation. From the results, the interaction parameters of the probes are, as expected due to the hydrophobicity of the polymer, found to be of large positive values (2$2.0{\times}10^{-3}mol/g$. For the linear PDMS, interpretation of the space distribution of molecules is performed by the Kirkwood-Buff-Zimm(KBZ) integrals, which give intuitive information about physical properties. From the KBZ integrals, water does not show the tendency of preferential solvation with the PDMS but formed self-cluster. The larger solvent molecules show a stronger tendency to distribute more randomly in the mixture.

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Hydrogeological Stability Study on the Underground Oil Storage Caverns by Numerical Modeling (수치모델링을 이용한 지하원유비축시설의 수리지질학적 안정성 연구)

  • 김경수;정지곤
    • The Journal of Engineering Geology
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    • v.12 no.1
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    • pp.35-51
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    • 2002
  • This study aims to establish the methodology for design of an optimum water curtain system of the unlined underground oil storage cavern satisfying the requirements of hydrodynamic performance in a volcanic terrain of the south coastal area. For the optimum water curtain system in the storage facility, the general characteristics of groundwater flow system in the site are quantitatively described, i.e. distribution of hydraulic gradients, groundwater inflow rate into the storage caverns, and hydrogeologic influence area of the cavern. In this study, numerical models such as MODFLOW, FracMan/MAFIC and CONNECTFLOW are used for calculating the hydrogeological stability parameters. The design of a horizontal water curtain system requires considering the distance between water curtain and storage cavern, spacing of the water curtain boreholes, and injection pressure. From the numerical simulations at different scales, the optimum water curtain systems satisfying the containment criteria are obtained. The inflow rates into storage caverns estimated by a continuum model ranged from about 120 m$^3$/day during the operation stage to 130~140m$^3$/day during the construction stage, whereas the inflow rates by a fracture network model are 80~175m$^3$/day. The excavation works in the site will generate the excessive decline of groundwater level in a main fracture zone adjacent to the cavern. Therefore, the vertical water curtain system is necessary for sustaining the safe groundwater level in the fracture zone.

A Study on Body Mass Index ( BMI ) , Nutrients Intake and Serum Lipid Components of Industrial Male Workers (일부 지역 산업체 남성 근로자들의 체적지수 , 영양소 섭취상태 및 혈청지질 성상에 관한 연구)

  • Lee, Seong-Hui;No, Suk-Ryeong
    • Journal of the Korean Dietetic Association
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    • v.5 no.1
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    • pp.10-20
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    • 1999
  • This study aimed at investigating correlation of nutrients intake and serum lipids of industrial workers. 226 for adult aged 20yr~59yr (average age 35.9yr) were selected as subjects during 6 months, from June to December, 1997. Nutrients intake was investigated by questionnaire, 24-hour recall method. Antropometric assessments, serum lipids and blood pressure of the subjects were investigated. The results as follows ; In total subjects, calories, calcium, vitamin A, vitamin $B_1$, and vitamin $B_2$ were below Korean RDA(recommended dietary allowances) and protein, iron, vitamin C, niacin and phosphorus were above Korean RDA. Distribution of BMI groups were underweight groups(7.9%), normalweight groups(63.3%) and overweight groups(28.8%). In BMI groups, intakes of calories, carbohydrates, protein, fats, iron, niacin and potassium of overweight groups were higher than those of other groups, significantly(P<0.001). Intakes of calcium of underweight groups were lower than those of other groups, significantly(P<0.05). BMI increased with age. Total cholesterol, triglyceride, apo(b) and atherogenic index of overweight groups were higher than those of other groups, significantly(P<0.001). Calories, carbohydrates, protein, fats, iron, vitamin $B_1$, vitamin $B_2$, niacin, natrium and potassium were positively correlated with BMI, significantly(P<0.001). Calcium and vitamin C were positively correlated with BMI, significantly(P<0.01). vitamin A and phosphorus were positively correlated with BMI, significantly(P<0.05). Total lipid, total-chol., triglyceride, apo(b) and atherogenic index were positively correlated with BMI, significantly(P<0.001). HDL-chol. were negatively correlated with BMI, significantly(P<0.001). Above results, the more BMI and age increased, the worse patterns of serum lipid, so that increased atherogenic index that increased risk of atherosclerosis and degenerative chronic disease connected with serum lipid. After classified by BMI, age and lipid pattern, it will be managed individually for health management of industrial workers. Development and application of efficient program will be urgent for harmonious nutrition counseling and guidance.

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Nocturnal temperature distribution on orange orchards in Cheju Island (II) (제주도 감귤 과수원의 야간 기온 분포(II))

  • ;;Lee, Seung-Ho;Lee, Hyong-Young
    • Journal of the Korean Geographical Society
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    • v.30 no.3
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    • pp.230-241
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    • 1995
  • The Characteristics of nocturnal temperature fields were analyzed to understand the factors of freezing-and-cold damages on orange orchards in Cheju Island. Temperatures were measured from January 7th through 27, 1995 at 25 sites in an area of 1x1.25$ extrm{km}^2$, Wasan-ri, Chochon-up, Pukcheju-kun located on the northeastern slope of Mt.Hanla. Several other weather elements such as wind and cloud were observed as supplementary data. Surface weather maps were also analyzed to clarify the influence of prevailing pressure patterns on the temperature fields. The vertical temperature profiles were obtained at the height from the ground up to 360 cm in 30 cm intervals at site 3, a frost hollow, and site 10 on the upper slope. The results show that freezing damages occured in the hollows, terrain depressions, rather than at the upper slope due to nocturnal radiation cooling as well as accumulation of cold airflow from Mt.Hanla. Windbreaks of densely planted Japanese ceders with stone-walls also roled as obstacles to the cold airflow in nights with Clear skies and light winds. The maximum intensity of temperature inversion in hollows, quasi-cold air lake, was 3.1$^{\circ}C$. Cold air from Mt.Hanla was trapped in the depressions up to a height of 90cm forming frost pocket. Man-made facilities such as shelterbelt or stone-wall which are built to prevent the penetration of cold north-westeries in winter aggravated the cold damage. The differance of daily minimum temperatures between before and behind shelterbelts was 2.$0^{\circ}C$. The man-made convection by smudgin which raised the temperatures up to 3.8$^{\circ}C$ can reduce the cold damage in the hellows.

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