• 제목/요약/키워드: Power-to-gas(P2G)

검색결과 30건 처리시간 0.023초

Ni 촉매 상에서 Power to Gas (P2G) 기술의 CO2 메탄화 반응에 관한 연구 (A Study on the CO2 Methanation in Power to Gas (P2G) over Ni-Catalysts)

  • 염규인;서명원;백영순
    • 한국수소및신에너지학회논문집
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    • 제30권1호
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    • pp.14-20
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    • 2019
  • The power to gas (P2G) is one of the energy storage technologies that can increase the storage period and storage capacity compared to the existing battery type. One of P2G technologies produces hydrogen by decomposing water from renewable energy (electricity) and the other produces $CH_4$ by reacting hydrogen with $CO_2$. The objective of this study is the reaction of $CO_2$ methanation which synthesized methane by reacting carbon dioxide and hydrogen. The effect of $CO_2$ conversion and $CH_4$ selectivity on reaction temperature, pressure, and methane contents over 40% Ni catalyst was mainly investigated throughout this study. As a result, the activity of this catalyst appeared to be the highest in $CH_4$ yield at around $400^{\circ}C$ and the selectivity of $CH_4$ increased with increasing reaction pressure. The methane content was not significantly influenced below 3% of all componets. As the space velocity increases from 10,000 to 30,000/hr, the $CO_2$ conversion rate tends to decrease.

PEM 수전해를 이용한 P2G에 대한 경제적 타당성 분석 (Economic Feasibility Analysis for P2G Using PEM Water Electrolysis)

  • 정선주;최낙헌;문창환;문상봉;임한권
    • 한국수소및신에너지학회논문집
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    • 제28권3호
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    • pp.231-237
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    • 2017
  • With worldwide efforts to increase the portion of renewable energy for $CO_2$ reductions, a lot of attention has been paid to P2G (power-to-gas) in Europe and Japan to efficiently utilize the surplus electricity. In this paper, economic feasibility analysis has been carried out for P2G using PEM water electrolysis by reflecting current economic status in Korea. In addition, efficiency and electricity price required to be competent in Korean market were provided. Based on cash flow diagrams, unit production costs for $H_2$ and $CH_4$ were estimated and profitability of P2G using PEM water electrolysis was analyzed.

0.4 MW급 가스분사식 배연탈황 흡수탑의 운전 특성 (Operating Characteristics of 0.4 MW-Scale Gas Dispersion Type FGD Absorber)

  • 안희수;김기형;박승수;박광규;김영호
    • 한국대기환경학회지
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    • 제24권4호
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    • pp.415-422
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    • 2008
  • This study was carried out to investigate the effect of operating and design conditions of gas dispersion type of absorber on $SO_2$ removal efficiency. pH difference between upper and lower part of gas dispersing plate of absorber was 0.2, which was relatively low. This was supposed that recirculation capacity of absorbing liquid between froth zone and reaction zone of absorber be increased by oxidation air injection through liquid riser which acted as liquid pump. Test results showed that $SO_2$ removal efficiency was more sensitive than absorber ${\Delta}P$. High $SO_2$ removal even at lower pH resulted from very low concentration of $HSO_3^-$ ion in absorbing liquid because of direct supply of dissolved oxygen into froth zone. 96% of $SO_2$ removal efficiency was obtained under the condition of absorber pH 5.2, flue gas flow rate of $1,530\;Nm^3/hr$, inlet $SO_2$ concentration of 800 ppm, absorber ${\Delta}P$ of 250mmAq. The following equation by a multiple linear regression was obtained to describe the relationship between $SO_2$ removal and operating variables. $$f=1-{\exp}(-1.3939+1.060pH+0.0139{\Delta}P-0.00267G-0.000064SO_2Conc.),\;R^2=0.9719$$

축산공해의 해결방안과 에너지 생산에 관한 연구 (Studies on Livestock Pollution Treatment and Energy Production)

  • 김창한;윤여창;최재용
    • 한국미생물·생명공학회지
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    • 제9권4호
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    • pp.219-223
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    • 1981
  • 축산공해를 방지하고 대체에너지를 개발하기 위하여 가축분뇨로부터의 메탄가스 발효실험을 실시하여 다음의 결과를 얻었다. (1) 각 가축의 분뇨에 약 30%의 슬러지를 첨가하여 37$^{\circ}C$에서 20일간 발효시킨 결과 우분, 돈분 및 계분의 유기물 1 kg당 메탄가스 생성량은 각각 181, 248 및 235 $\ell$였으며 발효기간중 pH 변화는 발효 초기에 약간 저하하다가 점차 상승하는 경향을 보였다. (2) 우분(300g)과 물(200g)의 혼합물에 슬러지를 각각 20, 30, 40 (w/w) %씩 첨가하여 발효시킨 결과 가스생성량은 약 6.1, 14. 5, 13.4 $\ell$ 였다. (3) 우분에 톱밥과 왕겨를 각각 등량씩 혼합하여 발효시킨 결과 톱밥 첨가시가 왕겨 첨가시보다 메탄생성량이 많았다. (4) 메탄발효처리물의 N, K, P의 함량에 있어서 N, K의 함량은 계분>돈분>우분의 순서였고 P는 우분>계분>돈분의 순서였다. (5) 수중펌프발효조를 이용하여 우분으로부터 메탄가스 생산발효를 20일간 실시한 결과 유기물 1kg 당 188 $\ell$의 메탄가스가 생성되었고, 이 때 생성된 총 메탄가스의 가격과 소모된 전력요금과는 거의 비슷하였다.

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ASSESSMENT OF GAS COOLED FAST REACTOR WITH INDIRECT SUPERCRITICAL $CO_2$ CYCLE

  • Hejzlar, P.;Dostal, V.;Driscoll, M.J.;Dumaz, P.;Poullennec, G.;Alpy, N.
    • Nuclear Engineering and Technology
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    • 제38권2호
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    • pp.109-118
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    • 2006
  • Various indirect power cycle options for a helium cooled gas cooled fast reactor (GFR) with particular focus on a supercritical $CO_2(SCO_2)$ indirect cycle are investigated as an alternative to a helium cooled direct cycle GFR. The balance of plant (BOP) options include helium-nitrogen Brayton cycle, supercritical water Rankine cycle, and $SCO_2$ recompression Brayton power cycle in three versions: (1) basic design with turbine inlet temperature of $550^{\circ}C$, (2) advanced design with turbine inlet temperature of $650^{\circ}C$ and (3) advanced design with the same turbine inlet temperature and reduced compressor inlet temperature. The indirect $SCO_2$ recompression cycle is found attractive since in addition to easier BOP maintenance it allows significant reduction of core outlet temperature, making design of the primary system easier while achieving very attractive efficiencies comparable to or slightly lower than, the efficiency of the reference GFR direct cycle design. In addition, the indirect cycle arrangement allows significant reduction of the GFR &proximate-containment& and the BOP for the $SCO_2$ cycle is very compact. Both these factors will lead to reduced capital cost.

경제성분석 프로그램을 이용한 도심형 마이크로그리드 최적 설계 (Optimal Design of Urban MICROGRID using Economical Analysis Program)

  • 유승덕;임성우;임유석;황성욱;이학주
    • KEPCO Journal on Electric Power and Energy
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    • 제8권2호
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    • pp.69-72
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    • 2022
  • This paper actually investigates the load on major large-scale buildings in the downtown area, examines the economic feasibility of installing PV and ESS in a microgrid target building, and evaluates whether an electric vehicle capable of V2G through two buildings is effective as an economical analysis program (HOMER) was analyzed using. It is economical to install a mixture of ESS rather than using the whole PV, and it is shown that if there is an electric vehicle using the V2G function of EV, there is an economic effect to replace the PV. So that Incentives and policies are needed to replace a large area of PV and utilize the existing parking lot to lead EV as a resource of the microgrid. Currently, P2X technology that stores power as ESS or converts it to other energy to control when surplus renewable energy occurs in large-capacity solar power plants and wind farms, etc. This is being applied, and efforts are being made to maintain the stability of the system through the management of surplus power, such as replacing thermal energy through a heat pump. Due to the increase in electric vehicles, which were recognized only as a means of transportation, technologies for using electric vehicles are developing. Accordingly, existing gas stations do not only supply traditional chemical fuels, but electricity, and super stations that also produce electricity have appeared. Super Station is a new concept power plant that can produce and store electricity using solar power, ESS, V2G, and P2G. To take advantage of this, research on an urban microgrid that forms an independent system by tying a large building and several buildings together and supplies power through a super station around the microgrid is in full swing.

40 wt% Ni 촉매에서 바이오가스 중 CO2로부터 메탄제조에 관한 연구: Commercial Catalyst와의 특성 비교분석 (A Study on the Synthesis of CH4 from CO2 of Biogas Using 40 wt% Ni-Mg Catalyst: Characteristic Comparison of Commercial Catalyst and 40 wt% Ni Catalyt)

  • 한단비;백영순
    • 한국수소및신에너지학회논문집
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    • 제32권5호
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    • pp.388-400
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    • 2021
  • Power to gas (P2G) is one of the energy storage technologies that can increase the storage period and storage capacity compared to the existing battery type. One of P2G technology produces hydrogen by decomposing water from renewable energy (electricity) and the other produces CH4 by reacting hydrogen with CO2. This study is an experimental study to produce CH4 by reacting CO2 of biogas with hydrogen using a 40 wt% Ni-Mg-Al catalyst and a commercial catalyst. Catalyst characteristics were analyzed through H2-TPR, XRD, and XPS instruments of 40% Ni catalyst and commercial catalyst. The effect on the CO2 conversion rate and CH4 selectivity was analyzed, and the activities of a 40% Ni catalyst and a commercial catalyst were compared. As a result of experiment, In the case of a 40 wt% catalyst, the maximum CO2 conversion rate showed 77% at the reaction temperature of 400℃. Meanwhile, the commercial catalyst showed a maximum CO2 conversion rate of 60% at 450℃. When 50% of CO was added to the CO2 methanation reaction, the CO2 conversion rate was increased by about 5%. This is considered to be due to the atmosphere in which the CO reaction can occur without the process of converting to CH4 after forming carbon and CO as intermediates in terms of the CO2 mechanism on the catalyst surface.

DED 방식을 적용한 플래너 밀러의 손상된 스핀들 키 보수 작업에 관한 연구 (A Study on the Repair Work for Spindle Key with Damaged Part in Planner Miller by Directed Energy Deposition)

  • 이재호;송진영;진철규;김채환
    • 한국산업융합학회 논문집
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    • 제25권4_2호
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    • pp.699-706
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    • 2022
  • In this study, Directed energy deposition (DED) among additive manufacturing is applied to repair damaged spindle key parts of planner miller. The material of the spindle key is SCM415, and the P21 Powder is used. In order to find the optimal deposition conditions for DED equipment, a single-line deposition experiment is conducted to analysis five parameters. The laser power affects the width, and the height is a parameter affected by coaxial gas and powder gas. In addition, laser power, powder feed rate, coaxial gas, and powder gas are parameters that affect dilution. Otimal deposition is that 400 W of laser power, 4.0 g/min of powder feed rate, 6.5 L/min of coaxial gas, 3.0 L/min of powder gas and 4.5 L/min of shield gas. By setting the optimum conditions, a uniform deposition cross section in the form of an ellipse can be obtained. Damage recovery process of spindle key consists of 3D shape design of the base and deposition parts, deposition path creation and deposition process, and post-processing. The hardness of deposited area with P21 powder on the SCM415 spindle key is 336 HV for the surface of the deposition, 260 HV for the boundary area, and 165 HV for the base material.

Screening of Spray-Dried K2CO3-Based Solid Sorbents using Various Support Materials for CO2 Capture

  • Eom, Tae Hyoung;Lee, Joong Beom;Baek, Jeom In;Ryub, Chong Kul;Rhee, Young Woo
    • KEPCO Journal on Electric Power and Energy
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    • 제1권1호
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    • pp.115-120
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    • 2015
  • $K_2CO_3$-based dry regenerable sorbents were prepared by spray-drying techniques to improve mass produced $K_2CO_3-Al_2O_3$ sorbents (KEP-CO2P, hereafter), and then tested for their $CO_2$ sorption capacity by a $2,000Nm^3/h$ (0.5 MWe) $CO_2$ capture pilot plant built for Unit 3 of the Hadong thermal power station in 2010. Each of the sample sorbents contained 35 wt.% $K_2CO_3$ as the active materials with various support materials such as $TiO_2$, MgO, Zeolite 13X, $Al_2O_3$, $SiO_2$ and hydrotalcite (HTC). Their physical properties and reactivity were tested to evaluate their applicability to a fluidized-bed or fast transport-bed $CO_2$ capture process. The $CO_2$ sorption capacity and percentage utilization of $K_2CO_3$-MgO based sorbent, Sorb-KM2, was $8.6g-CO_2/100g$-sorbents and 90%, respectively, along with good mechanical strength for fluidized-bed application. Sorbs-KM2 and KT were almost completely regenerated at $140^{\circ}C$. No degradation of Sorb-KM by $SO_2$ added as a pollutant in flue gas was observed during a cycle test.

MULTISCALE MODELLING FOR THE FISSION GAS BEHAVIOUR IN THE TRANSURANUS CODE

  • Van Uffelen, P.;Pastore, G.;Di Marcello, V.;Luzzi, L.
    • Nuclear Engineering and Technology
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    • 제43권6호
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    • pp.477-488
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    • 2011
  • A formulation is proposed for modelling the process of intra-granular diffusion of fission gas during irradiation of $UO_2$ under both normal operating conditions and power transients. The concept represents a simple extension of the formulation of Speight, including an estimation of the contribution of bubble motion to fission gas diffusion. The resulting equation is formally identical to the diffusion equation adopted in most models that are based on the formulation of Speight, therefore retaining the advantages in terms of simplicity of the mathematical-numerical treatment and allowing application in integral fuel performance codes. The development of the new model proposed here relies on results obtained by means of molecular dynamics simulations as well as finite element computations. The formulation is proposed for incorporation in the TRANSURANUS fuel performance code.