• Journal of the Korean Society of Manufacturing Process Engineers
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• 제17권6호
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• pp.68-74
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• 2018

Study on the Ti-6Al-4V have been carried out using cutting simulation, and researches for cutting force and chip shape prediction have been actively conducted under various conditions. However, a 3D printer application method using Ti-6Al-4V metal powder material as a high-power method has been studied for the purpose of prototyping, mold modification and product modification while lowering material removal rate. However, in the case of products / parts made of 3D printers using powder materials, problems may occur in the contact surface during tolerance management and assembly due to the degradation of the surface quality. As a result, even if a 3D printer is applied, post-processing through cutting is essential for surface quality improvement and tolerance management. In the cutting simulation, the cutting force and the chip shape were predicted based on the Johnson-Cook composition equation, but the shape of the shear type chip was not predictable. To solve this problem, we added a damaging term or strain softening term to the Johnson-Cook constitutive equation to predict chip shape. In this thesis, we applied the constant value of the S-K equations to the cutting simulation to predict the cutting force and compare with the experimental data to verify the validity of the cutting simulation and analyzed the machining characterization by considering conditions.

• Journal of Powder Materials
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• 제30권1호
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• pp.53-64
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• 2023

Atomic layer etching (ALE) is a promising technique with atomic-level thickness controllability and high selectivity based on self-limiting surface reactions. ALE is performed by sequential exposure of the film surface to reactants, which results in surface modification and release of volatile species. Among the various ALE methods, thermal ALE involves a thermally activated reaction by employing gas species to release the modified surface without using energetic species, such as accelerated ions and neutral beams. In this study, the basic principle and surface reaction mechanisms of thermal ALE?processes, including "fluorination-ligand exchange reaction", "conversion-etch reaction", "conversion-fluorination reaction", "oxidation-fluorination reaction", "oxidation-ligand exchange reaction", and "oxidation-conversion-fluorination reaction" are described. In addition, the reported thermal ALE processes for the removal of various oxides, metals, and nitrides are presented.

• Journal of Korean Society of Environmental Engineers
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• 제33권1호
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• pp.39-46
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• 2011

NO oxidation is an important prerequisite step to assist the selective catalytic reduction (SCR) at low temperatures ($<200^{\circ}C$). Therefore, we conducted the lab- and bench-scales experiments appling the sodium chlorite powder ($NaClO_2(s)$) for the oxidation of NO to $NO_2$ and the carbon-based catalyst for the reduction of $NO_x$ and $SO_2$; the lab- and bench-scales experiments were conducted in laboratory and iron-ore sintering plant, respectively. In the lab-scale experiment, known concentrations of $NO_x$ (200 ppm), $SO_2$ (75 ppm), $H_2O$ (10%) and $NH_3$ (400 ppm) in 2.6 L/min were introduced into a packed-bed reactor containing $NaClO_2(s)$, then gases produced by the reaction with $NaClO_2(s)$ were fed into the carbon-based catalyst (space velocity = $2,000hr^{-1}$) at $130^{\circ}C$. In the bench-scale experiment, flue gases of $50Nm^3/hr$ containing 120 ppm NO and 150 ppm $SO_2$ were taken out from the duct of iron-ore sintering plant, then introduced into the flow reactor; $NaClO_2(s)$ were injected into the flow reactor using a screw feeder. Gases produced by the reaction with $NaClO_2(s)$ were introduced into the carbon-based catalyst (space velocity = $1,000hr^{-1}$). Results have shown that, in both lab- and bench-scales experiments, NO was oxidized to $NO_2$ by $NaClO_2(s)$. In addition, above 90% of $NO_x$ and $SO_2$ removal were obtained at the carbon-based catalyst. These results lead us to suggest that the combination of $NaClO_2(s)$ with the carbon-based catalyst has the potential to achieve the simultaneous removal of $NO_x$ and $SO_2$ at low temperature ($<200^{\circ}C$).

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• 제11권2호
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• pp.85-93
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• 2013

This study has been carried out to elucidate the characteristics of the dissolution for Thermal Decomposed Solid Waste of uranium-bearing sludge (TDSW), the removal of impurities by an alkalization in a nitric acid dissolving solution of TDSW, and the selective removal (/recovery) of uranium by an acidification in an carbonate alkali solution, respectively. TDSW generated by thermal decomposition of U-bearing sludge which was produced in the uranium conversion plant operation, was stored in KAERI as a solid-powder type. It is found that the dissolution of TDSW is more effective in nitric acid dissolution than oxidative-dissolution with carbonate. At 1 M nitric acid solution, TDSW was undissolved about 30wt% as a solid residue, and uranium contained in TDSW was dissolved more than 99%. In order to the alkalization for the nitric acid dissolving solution of TDSW, carbonate alkalization is more effective with respect to remove the impurities. At the carbonate alkali solution controlled to about 9 of pH, Al, Ca, Fe and Zn co-dissolved with U in dissolution step was removed about $98{\pm}1%$. On the other hand, U could be recovered more than 99% by an acidification at pH about 3 in a carbonate alkali solution, which was nearly removed the impurities, adding 0.5M $H_2O_2$. It was found that uranium could be selectively recovered (/removed) from TDSW.

• Microbiology and Biotechnology Letters
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• 제38권3호
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• pp.308-314
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• 2010

This study was conducted to investigate the characteristics and concentrations of ammonia produced from the livestock swine nightsoil treated with or without the livestock - environment improving agents. Odor generating device made of acryl was made by volume of 96 L to sample the ammonia odor. When swine night soil was placed in the device, concentration of ammonia averaged out at about 23.4 ppmv and ranged from 16 ppmv to 40 ppmv. Removal efficiencies of them showed 50% to 90% as compared to initial level before spraying, when the spray type agents were used immediately after they purchased. The persistence of the efficiency was retained for first two days. Among the agents, the natural deodorant showed the best efficiency of 87 to 99%. To evaluate the effects of 5 kinds of dietary probiotic powders, the experiments were conducted and based dietary treatments without antibiotics on growing piglets. In experiments, 60 piglets ($6.3{\pm}0.2\;kg$) were subjected to a 35-day feeding trial in which the effects of the dietary probiotic powder on the ammonia emission were compared. The ammonia gas emission was measured for every week. Ammonia emission from the swine nightsoil obtained from piglets supplemented with the probiotics power was lower than that of the nightsoil obtained from pigs in the control treatment (without probiotics). In ammonia removal efficiencies of the experimental groups, some products showed from 71% to 99% removal efficiencies throughout the entire period as compared to the control group. On the other hand, initial reduction of ammonia in some product was effective temporarily. After then, it did not show any reduction efficiency of ammonia.

• Clean Technology
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• 제26권4호
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• pp.263-269
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• 2020

Zeolite was synthesized hydrothermally using the water-treatment sludge, and the effects of various synthesis parameters like reaction temperature, reaction time, and Na2O/SiO2 molar ratio on the crystallization of zeolite were investigated. Crystal structure, physical property, and thermal stability of zeolite crystals were characterized by X-ray powder diffraction, FTIR spectroscopy, BET nitrogen adsorption, and TGA measurements. The removal efficiencies of nitrogen in ammonia, heavy metal ions, and TOC were calculated to evaluate zeolite's adsorption capacity. The primary chemical composition of water-treatment sludge was 28.79% Al2O3 and 27.06% SiO2. The zeolites were synthesized by merely employing the water-treatment sludge as silica and alumina sources without additional chemicals. Zeolite crystals synthesized through the water-treatment sludge were confirmed as an A-type zeolite structure. Zeolite A had the highest crystallinity obtained from a gel with the molar composition 2.1Na2O-Al2O3-1.6SiO2-65H2O after 5 h at a temperature of 90 ℃. The specific surface area of zeolite obtained was 55 ㎡ g-1, which was higher than commercial zeolite A. The removal efficiency of nitrogen in ammonia was 68% after 3 h of reaction time, while the removal efficiencies of Pb2+ and Cd2+ ions were 99.1% and 99.3%, respectively. These results indicate active ion exchange between Pb2+ or Cd2+ ion and Na+ ion in the zeolite framework. The adsorption experiments on the different zeolite addition conditions were performed for 3 h with 300 ppm humic acid. Based on the results, TOC's highest efficiency was 83% when 5 g of zeolite was added.

• Clean Technology
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• 제28권4호
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• pp.285-292
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• 2022

Adsorption tower systems based on activated carbon adsorption towers have mainly been employed to reduce the emission of volatile organic compounds (VOCs), a major cause of air pollution. However, the activated carbon currently used in these systems has a short lifespan and thus requires frequent replacement. An approach to overcome this shortcoming could be to develop metal oxide photocatalysis-activated carbon composites capable of degrading VOCs by simultaneously utilizing photocatalytic activation and powerful adsorption by activated carbon. TiO₂ has primarily been used as a metal oxide photocatalyst, but it has low economic efficiency due to its high cost. In this study, ZnO particles were synthesized as a photocatalyst due to their relatively low cost. Silver nanoparticles (Ag NPs) were deposited on the ZnO surface to compensate for the photocatalytic deactivation that arises from the wide band gap of ZnO. A microfluidic process was used to synthesize ZnO particles and Ag NPs in separate reactors and the solutions were continuously supplied with a pack bed reactor loaded with activated carbon powder. This microfluidic-assisted pack bed reactor efficiently prepared a Ag-ZnO-activated carbon composite for VOC removal. Analysis confirmed that Ag-ZnO photocatalytic particles were successfully deposited on the surface of the activated carbon. Conducting a toluene gasbag test and adsorption breakpoint test demonstrated that the composite had a more efficient removal performance than pure activated carbon. The process proposed in this study efficiently produces photocatalysis-activated carbon composites and may offer the potential for scalable production of VOC removal composites.

• Journal of Institute of Convergence Technology
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• 제6권2호
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• pp.35-40
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• 2016

Ignitor tip is a component of burner to start the burning process in power plant. This is used to ignite the coal to a constant operating state by fuel mixed with air and kerosene. This component is composed of three components so that air and kerosene are mixed in the proper ratio and injected uniformly. Because the parts with the designed shape are manufactured in the machining process, they have to be made of three parts. These parts are designed to have various functions in each part. The mixing part mixes the supplied air and kerosene through the six holes and sends it to the injecting part at the proper ratio. The inject part injects mixed fuel, which is led to have a constant rotational direction in the connecting part, to the burner. And the connecting plate that the mixed fuel could rotate and spray is assembled so that the flame can be injected uniformly. But this part causes problems that are worn by vibration and rotation because it is mechanically assembled between the mixing part and the inject part. In this study, 3D printing method is used to integrate a connecting plate and an inject part to solve this wear problem. The 3D printing method could make this integrated part because the process is carried out layer by layer using a metal powder material. The part manufactured by 3D printing process should perform the post process such as support removal and surface treatment. However, while performing the 3D printing process, the material properties of the metal powders are changed by the laser sintering process. This change in material properties makes the post process difficult. In consideration of these variables, we have studied the optimization of manufacturing process using 3D printing method.

• The Korean Journal of Pesticide Science
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• 제16권2호
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• pp.145-150
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• 2012

This study was carried out to investigate the degradation of six residual pesticides (${\alpha}$- and ${\beta}$-Endosulfan, Cypermethrin, Fenitrothion, Hexaconazole, EPN) in red pepper powder after ultraviolet (UV) irradiation. The residual ratio of pesticides after 365 nm irradiation which distance is 20 cm and irradiation time is 5 minutes were 73.4, 69.6, 60.8, 92.7, 73.8 and 90.5% in ${\alpha}$-Endosulfan, ${\beta}$-Endosulfan, Cypermethrin, Fenitrothion, Hexaconazole and EPN, respectively. The residual ratio of pesticides after 254 nm irradiation which distance is 5 cm and irradiation time is 36 hours were 74.6, 64.5, 71.1, 79.1, 79.4 and 64.7% in ${\alpha}$-Endosulfan, ${\beta}$-Endosulfan, Cypermethrin, Fenitrothion, Hexaconazole and EPN, respectively.

• Clean Technology
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• 제18권1호
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• pp.63-68
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• 2012

In this study, aluminum hydroxide ($Al(OH)_3$) was synthesized by Bayer process and sodium contained in $Al(OH)_3$ was removed with the acid solution such as HCl and acetic acid for the synthesis of high purity alumina. The bauxite produced in Queensland of Australia was used for the production of alumina by Bayer, and was crushed to a particle size of below 10 um by attrition mill. The crushed bauxite was treated in sodium hydroxide solution of 5 N for the elution of aluminum component. The elution of aluminum from bauxite was carried out at $140^{\circ}C$ and 3.4 atm in autoclave. The sample solution was separated to the red mud and liquid solution by filter paper. The elution of aluminum from bauxite was confirmed with changing a structure and aluminum content in both bauxite and red mud analyzed by XRD and EDX. Aluminum contained in the separated solution was crystallized to $Al(OH)_3$ with the addition of aluminum hydroxide used as the seed material. $Al(OH)_3$ powder obtained during the crystallization process was purified by several times washing with distillated water. It was also confirmed that the sodium remained in $Al(OH)_3$ powder is removed with acid solution. The purity of $Al(OH)_3$ powder produced in this study was 99.3% and the content of sodium was reduced to approximately 0.009% after the acid treatment.