• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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• pp.111-112
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• 2006

Injection molding of corrosive super engineering plastics and engineering plastics with various fillers is conducted under severe conditions and causes corrosion and wear problems. We have developed $Mo_2NiB_2$ boride base cermets, which have excellent corrosion-and wear-resistances, and tried to apply them into plastic molding machine parts. In this paper, the effects of V substitution for Cr on the mechanical properties, corrosion resistance and microstructure of Ni-5.0B-51.0Mo-(17.5-X)Cr-XV (mass%) model cermets were investigated. Both transverse rupture strength (TRS) and hardness increased monotonically with increasing V content and reached 2.94GPa and $87.2R_A$ at 10.0%V, respectively. The improvements of TRS and hardness were attributed to microstructural refinement.

• 한국분말재료학회지
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• 제31권3호
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• pp.243-254
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• 2024

High-entropy alloys (HEAs) have been reported to have better properties than conventional materials; however, they are more expensive due to the high cost of their main components. Therefore, research is needed to reduce manufacturing costs. In this study, CoCrFeMnNi HEAs were prepared using metal injection molding (MIM), which is a powder metallurgy process that involves less material waste than machining process. Although the MIM-processed samples were in the face-centered cubic (FCC) phase, porosity remained after sintering at 1200℃, 1250℃, and 1275℃. In this study, the hot isostatic pressing (HIP) process, which considers both temperature (1150℃) and pressure (150 MPa), was adopted to improve the quality of the MIM samples. Although the hardness of the HIP-treated samples decreased slightly and the Mn composition was significantly reduced, the process effectively eliminated many pores that remained after the 1275℃ MIM process. The HIP process can improve the quality of the alloy.

• 대한치과보철학회지
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• 제43권4호
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• pp.478-486
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• 2005

Statement of problem : Fracture and dimensional change of an acrylic resin denture are a rather common occurrence. Purpose : The purpose of this study was to compare differences in dimensional changes and flexural strength of separate maxillary complete dentures after immediate deflasking by injection molding and conventional compression processing. Material and method: To evaluate dimensional stability, the maxillary dentures were fabricated by using different materials and methods. Lucitone 199(Dentsply Trubyte. york, pennsylvania, USA) and Vertex(Dentimex, zeist, Netherlands) were used as materials. Compression and injection packing methods were used as processing methods. The impression surface of the dentures was measured by 3D Scann-ing System(PERCEPTRON USA) and overlapped original impression surface of the master cast. To evaluate flexural strength, resin specimens were made according to the different materials, powder/liquid ratio and processing methods. Flexural strength of the complete resin specimens (64mm$\times$10mm$\times$3.3mm) were measured by INSTRON 4467. (INSTRON, England) The data was analyzed by ANOVA, t-test and Tukey test. (p<.05 level of significance) Result: The results were as follows 1. There was no significant differences between master model and denture base for each group in overall dimensional changes. 2. Palatal area was more stable than flange or alveolar area in dimensional stability. but. there was no significant differences among each area. 3. Materials and power/liquid ratio had an effect on flexural strength. (P<.05) Especially materials was most effective. (P<.05) 4. Lucitone 199(powder/liquid ratio followed by manufacturer's direction) showed higher flexural strength than Vertex. Conclusion : Dimensional stability or flexural strength are affected by materials rather than packing techniques.

• 한국분말재료학회지
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• 제10권1호
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• pp.6-14
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• 2003

The purpose of the present study is to investigate the method decreasing debinding time as well as lowering operation condition than pure supercritical $CO_2$ debinding by using cosolvent or binary mixture of propane + $CO_2$. First method is to add cosolvent, such as n-hexane, DCM, methanol, 1-butanol, in supercritical $CO_2$. In case of adding cosolvent, we were found the addition of non-polar cosolvent (n-hexane) improves dramatically the binder removal rate (more than 2 times) compared with pure supercritical $CO_2$ debinding, second method is to use mixture of supercritical propane + $CO_2$, as solvent. In case of using mixture of supercritical propane + $CO_2$, the rate of debinding speeded up with increasing of pressure and concentration of propane at 348.15 K. It was found that addition of cosolvent (e.g., n-hexane, DCM) and binary mixture propane + $CO_2$ for supercritical solvent remarkably improved binder removal rate for the paraffin wax-based binder system, in comparison with using pure supercritical $CO_2$.

• 한국분말재료학회지
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• 제19권2호
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• pp.117-121
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• 2012

Tool steels serve a large range of applications including hot and cold workings of metals and injection mouldings of plastics or light alloys. The high speed steels (HSS) are specifically used as cutting tools and wear parts because it has high strength, wear resistance and hardness along with appreciable toughness and fatigue resistance. From the view of HSS microstructure, it can be described as metallic matrix composites formed by a ferrous with a dispersion of hard and wear resistant carbides. The experimental specimens were manufactured using the PIM with T42 powders (50~80 vol.%) and polymer (20~50 vol.%). The green parts were debinded in n-hexane solution at $60^{\circ}C$ for 8 hours and thermal debinded at an $N_2-H_2$ mixed gas atmosphere for 8 hours. Specimens were sintered in high vacuum ($10^{-5}$ Torr) and various temperatures.

• 한국분말재료학회지
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• 제18권3호
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• pp.262-268
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• 2011

In order to investigate the microstructure and mechanical properties of WC-10 wt% Co insert tool alloy fabricated by PIM (Powder Injection Molding) process, the feedstock of WC-10 wt% and wax used as a kind of binder were mixed together by two blade mixer. After injection molding, the debinding process was carried out by two-steps. First, solvent extraction, in which the binder was eliminated by putting the specimen into normal hexane for 24 hrs at $60^{\circ}C$, and subsequently thermal debinding which was conducted at $260^{\circ}C$ and $480^{\circ}C$ for 6 hrs in the mixed gas of $H_2/N_2$, respectively. Meantime, in order to compensate the decarburization due to hydrogen, 1.2~1.8% of carbon was added to ensure the integrity of the phase. Finally, the specimens were sintered in vacuum under different temperatures, and the relative density of 99.8% and hardness of 2100 Hv can be achieved when sintered at $1380^{\circ}C$, even the TRS is lower than the conventional sintering process.

• 한국재료학회지
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• 제14권11호
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• pp.795-801
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• 2004

The injection molded Fe sintered bodies were fabricated using two kinds of Fe powders haying 50 nm and $3\sim5{\mu}m$ in diameter. In the using of Fe powder having 50 nm in diameter, the comparatively dense bodies ($94\sim97\%$) were obtained even at low sintering temperature ($600\sim700^{\circ}C$), while in the sintered bodies ($1000^{\circ}C$) using $3\sim5{\mu}m$ Fe powder, their relative densities showed low values about $93\%$, although they were strongly depend on the sintering temperature and volume ratio of Fe powder and binder. In the sintered bodies using of 50 nm Fe powders, the volume shrinkage and grain size increased as the sintering temperature increased, but the values of hardness decreased. In the sample sintered at $650^{\circ}C$, the values of relative density, volume shrinkage and grain size were $96\%,\;37\%\;and\;0.97{\mu}n$, respectively and the minimum value of wear depth was obtained due to combination of fine grain and comparatively high density.

• 한국분말재료학회지
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• 제17권4호
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• pp.312-318
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• 2010

High speed steels (HSS) were used as cutting tools and wear parts, because of high strength, wear resistance, and hardness together with an appreciable toughness and fatigue resistance. Conventional manufacturing process for production of components with HSS was used by casting. The powder metallurgy techniques were currently developed due to second phase segregation of conventional process. The powder injection molding method (PIM) was received attention owing to shape without additional processes. The experimental specimens were manufactured with T42 HSS powders (59 vol%) and polymer (41 vol%). The metal powders were prealloyed water-atomised T42 HSS. The green parts were solvent debinded in normal n-Hexane at $60^{\circ}C$ for 24 hours and thermal debinded at $N_2-H_2$ mixed gas atmosphere for 14 hours. Specimens were sintered in $N_2$, $H_2$ gas atmosphere and vacuum condition between 1200 and $1320^{\circ}C$. In result, polymer degradation temperatures about optimum conditions were found at $250^{\circ}C$ and $480^{\circ}C$. After sintering at $N_2$ gas atmosphere, maximum hardness of 310Hv was observed at $1280^{\circ}C$. Fine and well dispersed carbide were observed at this condition. But relative density was under 90%. When sintering at $H_2$ gas atmosphere, relative density was observed to 94.5% at $1200^{\circ}C$. However, the low hardness was obtained due to decarbonization by hydrogen. In case of sintering at the vacuum of $10^{-5}$ torr at temperature of $1240^{\circ}C$, full density and 550Hv hardness were obtained without precipitation of MC and $M_6C$ in grain boundary.

• Design & Manufacturing
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• 제13권2호
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• pp.17-21
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• 2019

In this study, selective laser sintered 3D printing mold core and metal core were used to investigate the difference of the thickness shrinkage from the gate of the injection molded part at a constant interval. SLS 3D printing mold core was made of nylon-based PA2200 powder and the metal core was manufactured by conventional machining method. As the PA2200 powder material has low strength, thermal conductivity and high specific heat characteristics compared with metal, molding conditions were set with the consideration of molten temperature and injection pressure. Crystalline resin(PP) and amorphous resin(PS) with low melting temperature and viscosity were selected for the injection molding experiment. Cooling time for processing condition was selected by checking the temperature change of the cores with a cavity temperature sensor. The cooling time of the 3D printing core was required a longer time than that of the metal core. The thickness shrinkage of the molded part compared to the core depth was measured from the gate by a constant interval. It was shown that the thickness shrinkage of the 3D printing core was 2.02 ~ 4.34% larger than that of metal core. In additions, in the case of metal core, thickness shrinkage was increased with distance from the gate, on the contrary, in the case of polymer core showed reversed aspect.

• Archives of Metallurgy and Materials
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• 제65권3호
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• pp.997-1000
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• 2020

With the recent advancement in technology for titanium metal powder injection molding and additive manufacturing, high yield and good flowability powder production is needed. In this study, titanium powder was produced through vacuum induction melting gas atomization with a cold crucible, which can yield various alloy compositions without the need for material pretreatment. The gas behavior in the injection section was simulated according to the orifice protrusion length for effective powder production, and powder was prepared based on the simulation results. The gas distribution changes with the orifice protrusion length, which changes the location of the recirculation zone and production yield of the powder. The produced powders had a spherical morphology, and the content of impurities (N, O) changed with the injected-gas purity.