• Journal of the Korean GEO-environmental Society
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• v.24 no.6
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• pp.5-11
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• 2023

The engineering industry heavily relies on fossil fuels such as coal and petroleum to generate energy through combustion. However, this process emits carbon dioxide into the atmosphere, leading to global warming. To mitigate this issue, researchers have explored various methods to reduce carbon dioxide emissions, one of which is carbon dioxide underground storage technology. This innovative technology involves capturing carbon dioxide from industrial plants and injecting it into the saturated ground layer beneath the earth's surface, storing it securely underground. Despite its potential benefits, carbon dioxide underground storage efficiency needs improvement to optimize storage in a limited space. To address this challenge, our research team has focused on improving storage efficiency by utilizing surfactants. Furthermore, we evaluated how different carbon dioxide states, including gaseous, liquid, and supercritical, impact storage efficiency based on their respective pressures and temperatures within the underground reservoir. Our findings indicate that using surfactants and optimizing the injection rate can effectively enhance storage efficiency across all carbon dioxide states. This research will pave the way for more efficient carbon dioxide underground storage, contributing to mitigating the environmental impact of fossil fuels on the planet.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.26 no.5B
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• pp.539-549
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• 2006

The performance of a pontoon-type floating breakwater (FB) is investigated numerically with the use of a second-order time domain model. The model has been developed based on potential theory, perturbation theory and boundary element method. This study is focused on the effects of weakly nonlinear wave on the hydrodynamic characteristics of the FB. Hydrodynamic forces, motion responses, surface elevation, and wave transmission coefficient around the floating breakwater are evaluated for various wave and geometric parameters. It is shown that the second-order wave component is of significant importance in calculating magnitudes of the hydrodynamic forces, mooring forces and the maximum response of a structure. The weak non-linearity of incident waves, however, can have little influence on the efficiency of the FB. From numerical simulations, the ratio of draft and depth, the relationship of wave number and width are presented for providing an effective means of reducing wave energy.

• Nuclear Engineering and Technology
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• v.55 no.12
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• pp.4671-4677
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• 2023

For the first time Pb, Ni, and Cu nanocomposites were synthesized by versatile solution combustion synthesis using Aloevera extract as a reducing agent, to study the potential applications in X-ray/gamma, neutron, and Bremsstrahlung shielding. The synthesized Lead-Nickel-Copper (LNC) nanocomposites were characterized by PXRD, SEM, UV-VIS, and FTIR for the confirmation of successful synthesis. PXRD analysis confirmed the formation of multiphase LNC NCs and the Scherrer equation and the W-H plot gave the average crystal sizes of 19 nm and 17 nm. Surface morphology using SEM and EDX confirmed the presence of LNC NCs. Strong absorption peaks were analyzed by UV visible spectroscopy and the direct energy gap is found to be 3.083 eV. Functional groups present in the LNC NCs were analyzed by FTIR spectroscopy. X-ray/gamma radiation shielding properties were measured using NaI(Tl) detector coupled with MCA. It is found to be very close to Pb. Neutron shielding parameters were compared with traditional shielding materials and found LNC NCs are better than lead and concrete. Secondary radiation shielding known as Bremsstrahlung shielding characteristics also studied and found that LNC NCs are best in secondary radiation shielding. Hence LNC NCs find shielding applications in ionizing radiation such as X-ray/gamma and neutron radiation.

• Elastomers and Composites
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• v.59 no.2
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• pp.51-63
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• 2024

Polypropylene (PP) is a commodity plastic that is widely used owing to its cost-effectiveness, lightweight nature, easy processability, and outstanding chemical and thermomechanical characteristics. However, the imperative to address energy and environmental crises has spurred global initiatives toward a circular economy, necessitating sustainable alternatives to traditional fossil-fuel-derived plastics. In this study, we conducted a series of comparative investigations of bio-based polypropylene (bio-PP) blends with current PP of the same and different grades. An extrusion-based processing methodology was employed for the bio-PP composites. Talc was used as an active filler for the preparation of the composites. A comparative analysis with the current petroleum-based PP indicated that the thermal properties and tensile characteristics of the bio-PP blends and composites remained largely unaltered, signifying the feasibility of bio-PP as a potential substitute for the current PP. To achieve a higher Young's modulus, elongation at break (EAB), and melt flow index (MFI), we prepared different composites of PP of different grades and bio-PP with varying talc contents. Interestingly, at higher biomass contents, the composites exhibited higher MFI and EAB values with comparable Young's moduli. Notably, the impact strengths of the composites with various biomass and talc contents remained unaltered. In-depth investigations through surface analysis confirmed the uniform dispersion of talc within the composite matrix. Furthermore, the moldability of the bio-PP composites was substantiated by comprehensive rheological property assessments encompassing shear rate and shear viscosity. Thus, from these outcomes, the fabricated bio-PP-based composites could be an alternative to petroleum-based PP composites for sustainable automobile applications.

• Archives of Metallurgy and Materials
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• v.63 no.3
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• pp.1433-1437
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• 2018

Neodymium-Iron-Boron (Nd-Fe-B) magnets are considered to have the highest energy density, and their applications include electric motors, generators, hard disc drives, and MRI. It is well known that a fiber structure with a high aspect ratio and the large specific surface area has the potential to overcome the limitations, such as inhomogeneous structures and the difficulty in alignment of easy axis, associated with such magnets obtained by conventional methods. In this work, a suitable heat-treatment procedure based on single-step and multistep treatments to synthesize sound electrospun Nd-Fe-B-O nanofibers of Φ572 nm was investigated. The single-step heat-treated (directly heat-treated at 800℃ for 2 h in air) samples disintegrated along with the residual organic compounds, whereas the multistep heat-treated (sequential three-step heat-treated including three steps;: dehydration (250℃ for 30 min in an inert atmosphere), debinding (650℃ for 30 min in air), and calcination (800℃ for 1 h in air)) fibers maintained sound fibrous morphology without any organic impurities. They could maintain such fibrous morphologies during the dehydration and debinding steps because of the relatively low internal pressures of water vapor and polymer, respectively. In addition, the NdFeO3 alloying phase was dominant in the multistep heat-treated fibers due to the removal of barriers to mass transfer in the interparticles.

• Archives of Metallurgy and Materials
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• v.67 no.4
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• pp.1469-1473
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• 2022

Tungsten diselenide (WSe₂) is one of the promising transition metal dichalcogenides (TMDs) for nanoelectronics and optoelectronics. To enhance and tune the electronic performance of TMDs, chemical functionalization via covalent and van der Waals approaches has been suggested. In the present report, the electric and structural transition of WSe₂ oxidized by exposure to O₃ is investigated using scanning tunneling microscopy. It is demonstrated that the exposure of WSe₂/high-ordered pyrolytic graphite sample to O₃ induces the formation of molecular adsorbates on the surface, which enables to increase in the density of states near the valence band edge, resulting from electric structural modification of domain boundaries via exposure of atomic O. According to the work function extracted by Kelvin probe force microscopy, monolayer WSe₂ with the O₃ exposure results in a gradual increase in work function as the exposure to O₃. Therefore, the present report demonstrates the potential pathway for the chemical functionalization of TMDs to enhance the electric performance of TMDs devices.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.26 no.6
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• pp.367-380
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• 2014

Tsunami take away life, wash houses away and bring devastation to social infrastructures such as breakwaters, bridges and ports. The targeted coastal structure object in this study can be damaged mainly by the tsunami force together with foundation ground failure due to scouring and liquefaction. The increase of excess pore water pressure composed of oscillatory and residual components may reduce effective stress and, consequently, the seabed may liquefy. If liquefaction occurs in the seabed, the structure may sink, overturn, and eventually increase the failure potential. In this study, the solitary wave was generated using 2D-NIT(Two-Dimensional Numerical Irregular wave Tank) model, and the dynamic wave pressure acting on the seabed and the estimated surface boundary of the vertical revetment. Simulation results were used as an input data in a finite element computer program(FLIP) for elasto-plastic seabed response. The time and spatial variations in excess pore water pressure, effective stress, seabed deformation, structure displacement and liquefaction potential in the seabed were estimated. From the results of the analysis, the stability of the vertical revetment was evaluated.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.27 no.1
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• pp.63-77
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• 2015

Tsunami take away life, wash houses away and bring devastation to social infrastructures such as breakwaters, bridges and ports. The coastal structure targeted object in this study can be damaged mainly by the wave pressure together with foundation ground failure due to scouring and liquefaction. The increase of excess pore water pressure composed of oscillatory and residual components may reduce effective stress and, consequently, the seabed may liquefy. If liquefaction occurs in the seabed, the structure may sink, overturn, and eventually increase the failure potential. In this study, the bore was generated using the water level difference, its propagation and interaction with a vertical revetment analyzed by applying 2D-NIT(Two-Dimensional Numerical Irregular wave Tank) model, and the dynamic wave pressure acting on the seabed and the surface boundary of the vertical revetment estimated by this model. Simulation results were used as input data in a finite element computer program(FLIP) for elasto-plastic seabed response. The time and spatial variations in excess pore water pressure ratio, effective stress path, seabed deformation, structure displacement and liquefaction potential in the seabed were estimated. From the results of the analysis, the stability of the vertical revetment was evaluated.

• Korean Chemical Engineering Research
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• v.58 no.4
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• pp.530-535
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• 2020

A ceramide-containing nanoemulsion was synthesized by using a High-Pressure Homogenizer (HPH) to observe its changes in properties and long-term stability. The droplet size, droplet distribution and zeta potential of nanoemulsion were examined by varying the pressure and the number of passes of the HPH. The increase in HPH pressure and number of passes decreased the average droplet size and made the nanoemulsion more uniform. However, beyond certain operating condition, the recombination between the droplets was confirmed due to droplet surface energy and emulsifier. This study also shows that the decrease in droplet size increased the nanoemulsion viscosity although only minimal changes occurred in the zeta potential. The formed nanoemulsion was then tested for its stability by storing it at 25 and 45 ℃ for 28 days. During the first week, the average droplet size increased due to recombination and then subsequently remained constant. We confirmed that ceramide nanoemulsion for industrial application could be synthesized by using HPH.

• Journal of the Korean Vacuum Society
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• v.9 no.2
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• pp.99-101
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• 2000

The fabrication of the submicron size hole has been interesting due to the potential application of the near field optical sensor or liquid metal ion source. The 2 micron size dot array was photolithographically patterned. After formation of the V-groove shape by anisotropic KOH etching, dry oxidation at $1000^{\circ}C$ for 600 minutes was followed. In this procedure, the orientation dependent oxide growth was performed to have an etch-mask for dry etching. The reactive ion etching by the inductively coupled plasma (ICP) system was performed in order to etch ~90 nm $SiO_2$ layer at the bottom of the V-groove and to etch the Si at the bottom. The negative ion energy would enhance the anisotropic etching by the $Cl_2$ gas. After etching, the remaining thickness of the oxide on the Si(111) surface was measured to be ~130 nm by scanning electron microscopy. The etched Si aperture can be used for NSOM sensor.