• 대한화학회지
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• 제59권6호
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• pp.508-519
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• 2015

본 연구에서는 개념 질문지를 사용하여 퍼텐셜 에너지 곡선에 대한 예비 화학 교사들의 이해 정도를 조사하였다. 조사 대상은 화학교육을 전공하는 사범대학 3학년 학생 24명, 4학년 학생 26명으로 총 50명이었다. 개념 질문지는 구슬 두 개의 거리에 따른 퍼텐셜 에너지 변화 곡선을 주고 상상실험을 하는 것으로 구성하였다. 질문지의 응답을 분석한 결과 예비 화학 교사들은 퍼텐셜 에너지나 전체 역학적 에너지가 음의 값을 가지는 것을 받아들이기 어려워하였다. 또한 역학적 에너지 보존은 대부분 알고 있었으나 이를 상상실험의 조건에 제대로 적용하지 못하는 것으로 나타났다. 그리고 구슬에 작용하는 힘의 방향은 대체로 알고 있었으나, 초기 위치에서 구슬이 이동하여 퍼텐셜 에너지가 가장 낮은 우물 바닥에서 정지할 것이라는 응답이 상당히 많았다. 또한 퍼텐셜 에너지 곡선과 관련지어 화학 결합, 기체의 액화, 분자의 진동 운동에 대한 이해도가 매우 낮은 것으로 드러났다.

• Advances in Energy Research
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• 제1권1호
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• pp.35-52
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• 2013

A model for DMFC anode performance is developed. The model takes into account potential--independent methanol adsorption on the catalyst surface, finite rate of proton transport through the anode catalyst layer (ACL), and a potential loss due to methanol transport in the anode backing layer. An approximate analytical half--cell polarization curve is derived and equations for the anode limiting current density are obtained. The polarization curve is fitted to the curves measured by Nordlund and Lindbergh and parameters resulted from the fitting are discussed.

• 신재생에너지
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• 제5권2호
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• pp.31-38
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• 2009

The performance test of a wind turbine in a wind farm is generally carried out by the owner to verify the power curve of the wind turbine given by the turbine manufacturer. The international electro-technical commission provides the IEC 61400-12-1 standard on "Power performance measurements of electricity producing wind turbines". By using this code, one can easily find the suitable met-mast (meteorological mast) location for the wind data whether a wind farm is potential or already built. In this paper, the valid sectors for wind turbines installed in the HanKyoung wind farm, south-west in Jeju island are analyzed on the basis of the code by considering the wind farm layout. Among these sectors, the optimal met-mast location is presented for the power curve verification of the wind farm.

• Bulletin of the Korean Chemical Society
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• 제32권3호
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• pp.863-866
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• 2011

The electrode reaction of $Eu^{3+}$ in a LiCl-KCl eutectic melt has been re-examined using cyclic voltammetry (CV). In this work, for the first time, the kinetic details of a $Eu^{3+}/Eu^{2+}$ redox system have been completely elucidated, along with the thermodynamic property, through a curve fitting applied to experimental CV data, which were obtained in a wide scan rate range of 0.5 to 10 V/s. The simulated results showed an excellent fit to all experimental CV data simultaneously, even though the curve fittings were performed within a large dynamic range of initial transfer coefficient values, formal potentials, and standard rate constants. As a result, a proper formal potential, transfer coefficient, and standard rate constant for the $Eu^{3+}/Eu^{2+}$ redox system were successfully extracted using the CV curve fitting.

• Bulletin of the Korean Chemical Society
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• 제28권12호
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• pp.2343-2353
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• 2007

We report the application of time-dependent density functional theory (TDDFT) to the calculation of potential energy profile relevant to the excited state intramolecular proton transfer (ESIPT) processes in title molecules. The TDDFT single point energy calculations along the reaction path have been performed using the CIS optimized structure in the excited state. In addition to the Stokes shifts, the transition energies including absorption, fluorescence, and 0-0 transition are estimated from the TDDFT potential energy profiles along the proton transfer coordinate. The excited state TDDFT potential energy profile of SA and 3ASA resulted in very flat function of the OH distance in the range ROH = 1.0-1.6 A, in contrast to the relatively deep single minimum function in the ground state. Furthermore, we obtained very shallow double minima in the excited state potential energy profile of SA and 3ASA in contrast to the single minimum observed in the previous work. The change of potential energy profile along the reaction path induced by the substitution of electron donating groups (-NH2 and -OCH3) at different sites has been investigated. Substitution at para position with respect to the phenolic OH group showed strong suppression of excited state proton dislocation compared with unsubstitued SA, while substitution at ortho position hardly affected the shape of the ESIPT curve. The TDDFT results are discussed in comparison with those of CASPT2 method.

• Bulletin of the Korean Chemical Society
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• 제31권2호
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• pp.365-371
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• 2010

The multiconfiguration molecular mechanics (MCMM) algorithm was used to generate potential and vibrationally adiabatic energy surfaces for excited-state tautomerization in the 1:1 7-azaindole:$H_2O$ complex. Electronic structures and energies for reactant, product, transition state were computed at the CIS/6-31G(d,p) level of theory. The potential and vibrationally adiabatic energies along the reaction coordinate were generated step by step by using 16 high-level Shepard points, which were computed at the CIS/6-31G(d,p) level. This study shows that the MCMM method was applied successfully to make quite reasonable potential and adiabatic energy curves for the excited-state double proton transfer reaction. No stable intermediates are present in the potential energy curve along the reaction coordinate of the excited-state double proton transfer in the 1:1 7-azaindole:$H_2O$ complex, indicating that these two protons are transferred concertedly. The change in the bond distances along the reaction coordinate shows that two protons move very asynchronously to make an $H_3O^+$-like moiety at the transition state.

• Bulletin of the Korean Chemical Society
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• 제29권9호
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• pp.1678-1684
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• 2008

• Nuclear Engineering and Technology
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• 제54권3호
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• pp.917-925
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• 2022

Steam generator (SG) tubes in a nuclear power plant can undergo rapid changes in pressure and temperature during an accident; thus, an accurate model to predict short-term creep damage is essential. The theta (𝜃) projection method has been widely used for modeling creep-strain behavior under constant stress. However, many creep test data are obtained under constant load, so creep rupture behavior under a constant load cannot be accurately simulated due to the different stress conditions. This paper proposes a novel methodology to obtain the creep curve under constant stress using a modified 𝜃 projection method that considers the increase in true stress during creep deformation in a constant-load creep test. The methodology is validated using finite element analysis, and the limitations of the methodology are also discussed. The paper also proposes a creep-strain model for alloy 690 as an SG material and a novel creep hardening rule we call the damage-fraction hardening rule. The creep hardening rule is applied to evaluate the creep rupture behavior of SG tubes. The results of this study show its great potential to evaluate the rupture behavior of an SG tube governed by creep deformation.

• Nuclear Engineering and Technology
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• 제55권10호
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• pp.3659-3664
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• 2023

The electrochemical behavior of dissolved hydrogen (H₂) was investigated at a Pt electrode in a high temperature LiOH-H₃BO₃ solution. The diffusion current of the H₂ oxidation was proportional to the concentration of the dissolved H₂ as well as the reciprocal of the temperature. In the polarization curve, a potential region in which the oxidation current decreases despite an increase in the applied potential between the H₂ oxidation and the water oxidation regions was observed. This potential region was interpreted as being caused by the formation of a Pt oxide layer. Using the properties of the Cl^- ion that reduces the growth rate of the Pt oxide layer, it was confirmed that there is a correlation between the Cl^- ion concentration and the transient current of the H₂ oxidation.

• 한국수자원학회:학술대회논문집
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• 한국수자원학회 2023년도 학술발표회
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• pp.32-32
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• 2023

Incidences of urban flood and extreme heat waves (due to the urban heat island effect) are expected to increase in New Zealand under future climate change (IPCC 2022; MfE 2020). Increasingly, the mitigation of such events will depend on the resilience of a range Nature-Based Solutions (NBS) used in Sustainable Urban Drainage Schemes (SUDS), or Water Sensitive Urban Design (WSUD) (Jamei and Tapper 2019; Johnson et al 2021). Understanding the impact of changing precipitation and temperature regimes due climate change is therefore critical to the long-term resilience of such urban infrastructure and design. Cuthbert et al (2022) have assessed the trade-offs between the water retention and cooling benefits of different urban greening methods (such as WSUD) relative to global location and climate. Using the Budyko water-energy balance framework (Budyko 1974), they demonstrated that the potential for water infiltration and storage (thus flood mitigation) was greater where potential evaporation is high relative to precipitation. Similarly, they found that the potential for mitigation of drought conditions was greater in cooler environments. Subsequently, Jaramillo et al. (2022) have illustrated the locations worldwide that will deviate from their current Budyko curve characteristic under climate change scenarios, as the relationship between actual evapotranspiration (AET) and potential evapotranspiration (PET) changes relative to precipitation. Using the above approach we assess the impact of future climate change on the urban water-energy balance in three contrasting New Zealand cities (Auckland, Wellington, Christchurch and Invercargill). The variation in Budyko curve characteristics is then used to describe expected changes in water storage and cooling potential in each urban area as a result of climate change. The implications of the results are then considered with respect to existing WSUD guidelines according to both the current and future climate in each location. It was concluded that calculation of Budyko curve deviation due to climate change could be calculated for any location and land-use type combination in New Zealand and could therefore be used to advance the general understanding of climate change impacts. Moreover, the approach could be used to better define the concept of urban infrastructure resilience and contribute to a better understanding of Budyko curve dynamics under climate change (questions raised by Berghuijs et al 2020)). Whilst this knowledge will assist in implementation of national climate change adaptation (MfE, 2022; UNEP, 2022) and improve climate resilience in urban areas in New Zealand, the approach could be repeated for any global location for which present and future mean precipitation and temperature conditions are known.