• Title/Summary/Keyword: Potential acid

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Corrosion Characteristics of Amorphous Alloy Ribbon ($Fe_{70}Cr_5Si_{10}B_{15}$ and $Co_{70}Cr_5Si_{10}B_{15}$) in Hydrochloric Acid Aqueous Solution

  • Choi, Chil-Nam;Hyo, Kyung-Yang;Yang, Myung-Sun
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2001.05a
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    • pp.236-237
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    • 2001
  • In this study, experiments were carried out to measure the variations in the corrosion potential and current density of polarization curves with amorphous $Fe_{70}Cr_5Si_{10}B_{15}$ and $Co_{70}Cr_5Si_{10}B_{15}$ alloy ribbon. The results were particularly examined to identify the influences of corrosion potential including various conditions such as hydrochloric acid, temperature, salt, pH, and oxygen. The optimum conditions were established with variations including temperature, salt, pH, oxygen, corrosion rate, and resistance of corrosion potential. The mass tranfer coefficient(${\alpha}$) value was determined with the Tafel's slope for the anodic dissolution based on the polarization effect with optimum conditions. The second anodic current density peak and maximum passive current density were designated as the critical corrosion sensitivity($I_{r}/I_{f}$).

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Improved Surface Plasmon Resonance Sensing Sensitivity due to an Electrochemically Potential-Induced Gold Reconstruction

  • Choi, Baeck B.;Kim, Bethy;Chen, Yiqi;Jiang, Peng
    • Journal of Electrochemical Science and Technology
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    • v.12 no.2
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    • pp.167-172
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    • 2021
  • he progressively improved sensing sensitivity (∆λSPR/∆n, nm/RIU) to detect the refractive index is observed on the SPR platform of an Au-covered epoxy gratings in an increase in potential cycling in a typical three-electrode cell. Here, a DVD-R optical disc was used as a structure template to prepare an Au-covered epoxy gratings, and the newly formed reverse track pitch structure on the epoxy substrate was used as a working electrode directly in aqueous sulfuric acid solution. It is expected that Au reconstruction by potential cycling in sulfuric acid electrolyte increases the packing density of Au atoms in the grain boundary and improves the propagation of electromagnetic waves.

Noticeable localized corrosion of solid boric acid on 304 stainless steel

  • Xinzhu Li;Wen Sun;Guiling Ning
    • Nuclear Engineering and Technology
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    • v.56 no.9
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    • pp.3616-3625
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    • 2024
  • With the aim to determine the potential corrosion effects of solid boric acid (BA) on light water reactors or other BA-involved equipment, the corrosion behaviors of solid BA on 304 stainless steel (SS) at different temperatures were investigated. Upon comparing the corrosion behaviors of solid BA at different temperatures, significant localized corrosion was observed on 304 SS surfaces at 150 ℃ following 90-day. This localized corrosion exhibited a characteristic pattern of scattered corrosion craters including B-containing Cr-rich oxides. These oxides were found to originate within micro-cracks, gradually evolving into scar-like protrusions within the craters. The proposed corrosion mechanisms entail the interactions between solid BA and chromium oxides/hydroxides, leading to the formation of B-containing Cr-rich oxides. Our findings offer insights into potential corrosion incidents and protective strategies for industries dealing with solid BA.

Identification of Fouling Phenomena and Establishment for Optimized Removal Process of Alginic Acid Sodium Salt Through Capacitive Deionization (CDI 공정에서 Alginic Acid Sodium Salt의 파울링 현상 확인 및 제거 조건 확립)

  • Lee, Jin Yeon;Rhim, Ji Won
    • Membrane Journal
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    • v.30 no.5
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    • pp.342-349
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    • 2020
  • In this study, we suggest conditions to reduce fouling in capacitive deionization (CDI) caused by alginic acid sodium salt, one of the most common fouling-causing substances in natural water and wastewater management. First, NaCl is used as feed material, which is selected as the control of the experiment. As expected, fouling phenomena is not observed from NaCl. On the other hand, when alginic acid sodium salt is added to the inlet, the fouling phenomena can be observed. In order to minimize the fouling phenomena, the feed concentration of alginic acid sodium salt, applied potential during desorption process, and duration of applied potential to our CDI cell are controlled. With 7 mg/L of feed stream concentration, CDI performed using 1.2 V for 1 min during adsorption followed by desorption with -2 V for 1 min exhibited the highest alginic acid salt removal efficiency reaching 50.07%.

Synthesis and Evaluation of Coumaroyl Dipeptide Amide as Potential Whitening Agents

  • Lee, Hye-Suk;Shin, Kyong-Hoon;Ryu, Geun-Seog;Cho, In-Shik;Kim, Jae-Il;Lee, Jae-Ho;Kim, Han-Young
    • Bulletin of the Korean Chemical Society
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    • v.34 no.10
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    • pp.3017-3021
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    • 2013
  • Coumaroyl dipeptide amide, Coumaric acid-LG-$NH_2$, was prepared successfully using the solid-phase method, and its efficacy as a skin whitening agent was studied. Coumaric acid-LG-$NH_2$ was prepared with Rink-amide resin, and 96.354% of purity was obtained. Using MTT assay and LDH release assay, we found that it exhibited very low cytotoxicity. And, we found that Coumaric acid-LG-$NH_2$ inhibited tyrosinase activity dose-dependently and showed superior tyrosinase inhibitory activity to well-known whitening agent, arbutin. $IC_{50}$ value of Coumaric acid-LG-$NH_2$ was 182.4 ${\mu}M$, and $IC_{50}$ value of arbutin was 384.6 ${\mu}M$. Also, in measurement of melanin contents using B16F1 melanoma cell lines, Coumaric acid-LG-$NH_2$ reduced melanin production induced by ${\alpha}$-MSH statistically significant, and showed superior melanin inhibitory activity to p-coumaric acid or arbutin. In addition, Coumaric acid-LG-$NH_2$ reduced MC1R mRNA expression level. Thus, we concluded that MC1R pathway is the significant pathway of Coumaric acid-LG-$NH_2$, and Coumaric acid-LG-$NH_2$ has great potential to be used as novel whitening agents.

Chromosomal Aberrations in Chinese Hamster Ovary Cells Induced by Kojic Acid (Kojic Acid에 의해 유기된 Chinese Hamster 난소세포의 염색체 변이)

  • Lee, Yang-Soon;Wei, Cheng-I
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.21 no.4
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    • pp.454-459
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    • 1992
  • Kojic acid, a fungal metabolite produced by some species of Aspergillus and Penicillium, was found to induce chromosomal aberrations in Chinese hamster ovary cells in the presence or absence of the rat liver homogenate (59 mix). All categories of chromosomal aberrations increased with increased doses of kojic acid. Based on the this result, kojic acid was assumed to be a kind of mutagens. On the potential toxicity of this compound it becomes evident that kojic acid would not be used as a food additive at this time.

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Hydrogen Adsorption of Acid-treated Multi-walled Carbon Nanotubes at Low Temperature

  • Lee, Seul-Yi;Park, Soo-Jin
    • Bulletin of the Korean Chemical Society
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    • v.31 no.6
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    • pp.1596-1600
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    • 2010
  • Surface functionalization of multi-walled carbon nanotubes (MWNTs) was carried out by means of acid treatment. The presence of oxygen functional groups on the surface of acid-treated MWNTs was confirmed with the aid of Fourier transform infrared spectroscopy and X-ray spectroscopy. In addition, carboxylic groups generally formed on the surface of acid-treated MWNTs, and the dispersion was increased by the duration of the acid treatment. The zeta-potential indicated the surface charge transfer and the dispersion of MWMTs. Morphological characteristics of acid-treated MWNTs were also observed using a transmission electron microscopy, X-ray diffraction, and Raman analysis, which was revealed the significantly unchanged morphologies of MWNTs by acid treatment. The hydrogen adsorption capacity of the MWNTs was evaluated by means of adsorption isotherms at 77 K/1 atm. The hydrogen storage capacity was dependent upon the acid treatment conditions and the formation of oxygen functional groups on the MWNT surfaces. The latter have an important effect on the hydrogen storage capacity.

An Investigation of the Solubilization of Primary Sewage Sludge using Lactic Acid Bacteria Cultured in a Glucose and Yeast Extract Medium (Glucose와 Yeast Extract를 이용하여 배양된 유산균을 이용한 하수 일차 슬러지의 가용화)

  • Lee, Sang Min;Choi, Han Na;Shin, Jung Hun;Lee, Eun Young
    • Microbiology and Biotechnology Letters
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    • v.40 no.4
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    • pp.424-429
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    • 2012
  • The intention of this research was to investigate the solubilization of primary sewage sludge using lactic acid bacteria cultured in a glucose and yeast extract medium. Glucose as the carbon source and yeast extract as the source of nitrogen were chosen as an economic medium with the potential for the mass production of lactic acid bacteria. The optimal concentrations of the medium were 3% (w/v) glucose and 2% (w/v) yeast extract. In this study, in order to improve field applications for the solubilization of sludge at sewage treatment plants, a powdered form of lactic acid bacteria was produced. The optimal inoculum of the powder for the maximum efficiency of solubilization was 1% (w/v). In that condition, the SCOD value increased from 8600 (mg/L) at the beginning of experiment to 10290 (mg/L) at 96 h, with the highest solubilization rate (20.6% DDCOD) and 11.2% (SCOD). Also, the TVFAs of the lactic acid bacteria inoculation group were produced more than that of the control group. In particular, acetic acid was produced 5 times more in the experimental group than in the control group. In this research, the potential of lactic acid bacteria in the pretreatment of primary sewage sludge as a solubilizer, and as an energy source producer for microbial fuel cells was revealed.

Contemporary Issues Surrounding Folic Acid Fortification Initiatives

  • Choi, Jeong-Hwa;Yates, Zoe;Veysey, Martin;Heo, Young-Ran;Lucock, Mark
    • Preventive Nutrition and Food Science
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    • v.19 no.4
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    • pp.247-260
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    • 2014
  • The impact of folate on health and disease, particularly pregnancy complications and congenital malformations, has been extensively studied. Mandatory folic acid fortification therefore has been implemented in multiple countries, resulting in a reduction in the occurrence of neural tube defects. However, emerging evidence suggests increased folate intake may also be associated with unexpected adverse effects. This literature review focuses on contemporary issues of concern, and possible underlying mechanisms as well as giving consideration the future direction of mandatory folic acid fortification. Folate fortification has been associated with the presence of unmetabolized folic acid (PteGlu) in blood, masking of vitamin $B_{12}$ deficiency, increased dosage for anti-cancer medication, photo-catalysis of PteGlu leading to potential genotoxicity, and a role in the pathoaetiology of colorectal cancer. Increased folate intake has also been associated with twin birth and insulin resistance in offspring, and altered epigenetic mechanisms of inheritance. Although limited data exists to elucidate potential mechanisms underlying these issues, elevated blood folate level due to the excess use of PteGlu without consideration of an individual's specific phenotypic traits (e.g. genetic background and undiagnosed disease) may be relevant. Additionally, the accumulation of unmetabolized PteGlu may lead to inhibition of dihydrofolate reductase and other enzymes. Concerns notwithstanding, folic acid fortification has achieved enormous advances in public health. It therefore seems prudent to target and carefully monitor high risk groups, and to conduct well focused further research to better understand and to minimize any risk of mandatory folic acid fortification.

Enzymatic Activity and Amino Acids Production of Predominant Fungi from Traditional Meju during Soybean Fermentation

  • Dong Hyun Kim;Byung Hee Chun;Jae-Jung Lee;Oh Cheol Kim;Jiye Hyun;Dong Min Han;Che Ok Jeon;Sang Hun Lee;Sang-Han Lee;Yong-Ho Choi;Seung-Beom Hong
    • Journal of Microbiology and Biotechnology
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    • v.34 no.3
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    • pp.654-662
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    • 2024
  • To investigate the effect of the predominant fungal species from Korean traditional meju and doenjang on soybean fermentation, the enzymatic activity and amino acid production of twenty-two fungal strains were assessed through solid- and liquid-state soybean fermentation. Enzymatic activity analyses of solid-state fermented soybeans revealed different enzyme activities involving protease, leucine aminopeptidase (LAP), carboxypeptidase (CaP), glutaminase, γ-glutamyl transferase (GGT), and amylase, depending on the fungal species. These enzymatic activities significantly affected the amino acid profile throughout liquid-state fermentation. Strains belonging to Mucoromycota, including Lichtheimia, Mucor, Rhizomucor, and Rhizopus, produced smaller amounts of total amino acids and umami-producing amino acids, such as glutamic acid and aspartic acid, than strains belonging to Aspergillus subgenus circumdati. The genera Penicillium and Scopulariopsis produced large amounts of total amino acids and glutamic acid, suggesting that these genera play an essential role in producing umami and kokumi tastes in fermented soybean products. Strains belonging to Aspergillus subgenus circumdati, including A. oryzae, showed the highest amino acid content, including glutamic acid, suggesting the potential benefits of A. oryzae as a starter for soybean fermentation. This study showed the potential of traditional meju strains as starters for soybean fermentation. However, further analysis of processes such as the production of G-peptide for kokumi taste and volatile compounds for flavor and safety is needed.