• Journal of Applied Biological Chemistry
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• v.61 no.4
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• pp.383-389
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• 2018

Degradation of the insecticide O,O-diethyl O-3,5,6-trichloro-2-pyridyl phosphorothioate (chlorpyrifos) in aqueous solution was investigated using iron salts and potassium persulfate during ZVI treatment through a series of batch experiments. The degradation rate of chlorpyrifos increased with increases in the concentrations of iron salts and potassium persulfate in the aqueous system. Ferric chloride was found to be the most effective iron salt for the ZVI-mediated degradation of chlorpyrifos in aqueous solution. Further, the iron salts tested could be arranged in the following order in terms of their effectiveness: $FeCl_3$> $Fe_2(SO_4)_3$> $Fe(NO_3)_3$. The persulfate-ZVI system could significantly degrade chlorpyrifos present in the aqueous medium. This revealed that chlorpyrifos degradation by treatment with $Fe^0$ was promoted on adding ferric chloride and potassium persulfate. The kinetics of the degradation of chlorpyrifos by persulfate-amended $Fe^0$ was higher than that for iron-salt-amended $Fe^0$. This suggests that using a sequential $Fe^0$ reduction-ferric chloride or $Fe^0$ reduction-persulfate process may be an effective strategy to enhance the removal of chlorpyrifos in contaminated water.

• Journal of Sericultural and Entomological Science
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• v.33 no.2
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• pp.82-86
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• 1991

The treatments of methacrylamide on silk fibers were studied in aqueous solution using potassium persulfate as an initiator, and suitable conditions of reaction were determined for weighing of silk fibers. The results obtained were summarized as follows ; The weight of MAA-treated silk fibers increased with monomer concentration. The adequate concentration of potassium persulfate was found to be 1.7%. Maximum weight increase was shown at initial pH 3.8 of reaction liquor controlled by buffer solution.

• Elastomers and Composites
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• v.52 no.3
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• pp.211-215
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• 2017

Thermally expandable microspheres were used as post-treatment initiators of potassium persulfate, sodium bisulfite, and sodium sulfide in order to improve the foaming ability and whiteness when foaming a mixture of thermally expandable microsphers and poly(vinyl chloride). Potassium persulfate showed no significant influence on the foaming behavior, foam expansion, whiteness, and yellowing, whereas in the case of using sodium bisulfite. In particular, sodium bisulfite demonstrated the best efficiency with 2 wt% treatment. The thermally expandable microspheres prepared herein can provide excellent foamability and whiteness, and are expected to be applicable in various fields such as general coating and wallpaper.

• Journal of Radiation Industry
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• v.5 no.4
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• pp.359-364
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• 2011

This study was aimed to investigate the effect of oxidants on biodegradability and decomposition of acetaminophen (ACT) by gamma ray. Three kinds of chemical, potassium persulfate, hydrogen peroxide and ferrous sulfate were selected as an oxidant. The absorbed dose was ranged from 0.2 to 10 kGy and the concentration of oxidants was from 0.1 to 10 mM and the initial concentration of acetaminophen was $30mg\;l^{-1}$ in this study. The concentration of ACT was gradually decreased corresponding to the increase of the absorbed dose. However, mineralization of ACT was not occurred by the increased of the absorbed dose. When the 10 mM of oxidants applied to the ACT aqueous solution, the concentration of ACT was rapidly decreased according to absorbed dose and the mineralization was observed in potassium persulfate. Biodegradability of ACT with potassium persulfate was higher than that of ACT without potassium persulfate in lower absorbed dose and decreased according to higher absorbed dose.

• 월간산업보건
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• s.291
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• pp.12-16
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• 2012

과황산암모늄 (ammonium persulfate), 과황산칼륨(potassium persulfate), 과황산나트륨(sodium persulfate)에 대한 작업 노출기준은 perfulfate ($S_2O_8$) 형태로서 0.1 $mg/m^3$(TLV-TWA)으로 권고하였다. 이 기준치는 피부 자극 및 피부염을 포함한 피부 또는 기관지계 관련 질환 발생을 최소화하기 위해 설정되었다. 몇몇 연구 자료에 의하면 이 물질들에 노출되면 폐 자극 증세도 나타난다고 보고되고 있다. 또한 이 TLV는 전신독성 측면보다는 자극 영향 측면에 근거를 두어 제안하였다. "감작제(SEN)", 발암성, TLV-STEL에 대한 설정은 유용한 자료의 부족으로 아직 권고하지 않고 있다.

• Macromolecular Research
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• v.12 no.1
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• pp.107-111
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• 2004

We have studied the polymerization kinetics of acrylamide in aqueous solution with potassium persulfate as an initiator by using quantitative real-time in situ IR spectroscopy and monitoring the profiles of peaks in the range 1900-850 cm$\^$-1/. The conversion of acrylamide was calculated from the disappearance of the peak at 988 cm$\^$-1/, which is the out-of-plane bending mode of the=C-H unit, normalized to the C=O stretching peak at 1675 cm$\^$-1/, as an internal standard. For reaction temperatures in the range 40-65$^{\circ}C$ and initiator and monomer concentrations of 0.9-2.6 mmol/L and 0.5-1.1 mol/L, respectively, we deduced that the rate of monomer consumption follows the relation R$\_$p/=k［K$_2$S$_2$O$\_$8/］$\^$0.5/ [Μ］$\^$1.35${\pm}$0.10/. In addition, we obtained activation parameters from an evaluation of the kinetic data.

• Journal of the Korean Applied Science and Technology
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• v.27 no.2
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• pp.216-221
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• 2010

Polyvinyl acetate (PVAc) prepared by emulsion polymerization has broad applications for additive such as paint binder, adhesive for wood and paper due to its low glass transition temperature which help to plasticize substrate resins. Since emulsion polymerization has a disadvantage that surfactant and ionic initiator degrade properties of the product polymer, poly (vinyl acetate-eo-ethyl acrylate) (VAc-EA) was synthesized using potassium persulfate as catalyst and polyvinylalcohol (PVA) as protective colloid to prevent the degradation. The copolymer latex product was internally plasticized and has enhanced adhesion, water resistance during VAc-EA emulsion polymerization. No coagulation and complete conversion occur with the reactant mixture of 10 mmol/L potassium persulfate, 10 mmol/L poly ( vinyl alcohol) (PVA 17). As the concentrations of PVA increase, the viscosity becomes increase.

• Journal of the Korea Institute of Building Construction
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• v.14 no.4
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• pp.322-328
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• 2014

In this study, revelation performance of concrete at early age according to types of cement, water reducing ratio of high performance superplasticizer and mixing of accelerator for early hydration was examined aiming for reduction of construction period of framework through securing strength at early age of concrete. It was observed that strength at early age, 5MPa in 12hours, 14MPa in 18hours, is secured by early strength improvement type cement and using promotion admixture for early hydration which are Sodium persulfate, Potassium hydroxide. Therefore cost reduction is expected to be possible in construction site by reducing construction period of frame work.

• Resources Recycling
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• v.31 no.4
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• pp.40-48
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• 2022

In waste lithium iron phosphate (LFP) batteries, the cathode material contains approximately 4% lithium. Recycling the constituent elements of batteries is important for resource circulation and for mitigating the environmental pollution. Li contained in the waste LFP cathode powder was selectively leached using persulfate-based oxidizing agents, such as sodium persulfate, potassium persulfate, and ammonium persulfate. Leaching efficiency and waste LFP powder properties were compared and analyzed. Pulp density was used as a variable during leaching, which was performed for 3 h under each condition. The leaching efficiency was calculated using the inductively coupled plasma (ICP) analysis of the leachate. All types of persulfate-based oxidizing agents used in this study showed a Li leaching efficiency over 92%. In particular, when leaching was performed using (NH₄)₂S₂O₈, the highest Li leaching percentage of 93.3% was observed, under the conditions of 50 g/L pulp density and an oxidizing agent concentration of 1.1 molar ratio.

• Journal of Sericultural and Entomological Science
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• v.34 no.2
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• pp.32-40
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• 1992

Many studies have been carried out on the graft finishing in order to improve the quality of silk fiber. Various vinyl monomers, for instance, styrene, methylmethacrylate, 2-hydroxyeth-ylmethacrylate and methacrylamide, have been used practically up to date. Among these monomers, methacrylamide has been applied as the most favourable monomer onto silk fibers in recent years. The polymerization mechanism about styrene- and methylmethacrylate-grafted silk fiber has been studied by many researchers. They proposed that free radicals were formed and vinyl monomers were polymerized in silk fibroin by graft polymerization mechanism, while active sites were varied by the types of monomer and initiator as well as by the reaction condition. In general. there is another Opinion that monomers are polymerized and impregnated in the internal side of the fiber by homopolymerization, which has not been proved experimentally yet More than 10 years have been passed since methacrylamide was applied on the silk fiber, and at the present time most finishings are being achieved by methacrylamide. However, no attention has been paid to the polymerization mechanism of the methacrylamide-treated silk fiber yeL In this paper, the treatments of methacrylamide on silk fibers were studied in aqueous solution using potassium persulfate as an initiator. The polymerization mechanism of the methacrylamide-treated silk fibers was investigated and analyzed on the basis of the results of infrared spectroscopy, amino acid analysis and scanning electron microscopy. From the results of these instrumental analyses, it can be suggested that polymerization mechanism about the methacrylamide-treated silk fibers is not performed by graft polymerization which has been accepted generally in styrene and methylmethacrylate-grafted silk fibers. The different mechanism is supposed to be due to the difference in monomer types, initiator types and treatment conditions.