• Title/Summary/Keyword: Post-oxidation

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A Effect of the Oxidation Process on the Lifetime Properties of Ag-CdO Contact Materials (산화 방식이 Ag-CdO계 전기접점재료의 수명 특성에 미치는 영향)

  • Kwon, Gi-Bong;Nam, Tae-Woon
    • Journal of Korea Foundry Society
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    • v.25 no.6
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    • pp.233-239
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    • 2005
  • Contact material is widely used in the field of electrical parts. Ag-CdO has a good wear resistance and stable contact resistance. We studied a lifetime of Ag-CdO material because of getting better properties of Ag-CdO using Post-oxidation. The experimental procedure were melting using high frequency induction, heat treatment, rolling and internal oxidation. And we experimented on difference process, Post-oxidaion. Then we tested a lifetime and analysed. We obtained the optimizing oxidation temperature was $750^{\circ}C$. Using Pre-oxidation, coarse oxide and depleted oxidation layer existed but finer oxides were existed and depleted oxidation layer was not using Post-oxidation. In Post-oxidation, The density was 10 $g/cm^{3}$, the hardness was Hv 80 and the adhesive strength was 9000N. The specimen of Post-oxidation had better lifetime properties than that of Pre-oxidation. We predicted that the lifetime of Post-oxidation specimen is more longer twice than that of Pre-oxidation one.

The Microstructures and Properties of Duplex Layer on the Tool Steel Formed by Post-oxidation and Sulfnitriding (금형공구강의 후산화와 침류질화에 의해 형성된 복합층의 조직과 특성에 관한 연구)

  • Lee, J.S.;Klm, H.G.;You, Y.Z.
    • Journal of the Korean Society for Heat Treatment
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    • v.14 no.2
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    • pp.81-88
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    • 2001
  • The effects of post-oxidation and sulfnitriding treatments on the phase transformation in the nitrided case of tool steels have been studied. Dense and compact $Fe_3O_4$ layer was formed at the outer surface of nitride compound layer by post-oxidation treatment and multi layer of iron sulfide(FeS) was formed in the compound layer by sulfnitriding treatment. The surface hardness decreased because of formation of the soft oxide or sulfide at the nitride surface. Diffusion layer of nitride case was not affected by post-oxidation treatment or sulfnitriding treatment of nitrided alloy tool steels.

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The Effect of The Heat Treatment Condition and the Oxidation Process on the Microstructure of Ag-CdO Contact Materials (Ag-CdO계 전기접점재료의 미세조직에 미치는 열처리 조건과 산화 공정의 영향)

  • Kwon, Gi-Bong;Nam, Tae-Woon
    • Journal of Korea Foundry Society
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    • v.25 no.6
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    • pp.226-232
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    • 2005
  • Contact material is widely used in the field of electrical parts. Ag-CdO material has a good wear resistance and stable contact resistance. In order to establish optimizing heat treatment condition, rolling temperature and oxidation process, we studied the microstructure of Ag-CdO material with various conditions. The experimental procedure were melting using high frequency induction, heat treatment, rolling and internal oxidation. And we experimented on difference process, Post-oxidaion. In this study, we obtained the optimizing heat treatment condition was $700^{\circ}C$ for 15 min. and the optimizing rolling temperature was $730^{\circ}C$. In investigation of the microstructure of oxidized material, coarse oxide and depleted oxidation layer existed. The hardness was average Hv 70. When we used Post-oxidation, oxides were finer than prior process and depleted oxidation layer did not exist. The hardness of Post-oxidation material was average Hv 80. And the optimizing rolling temperature was $800^{\circ}C$.

The Application of Plasma Nitrocarburizing and Plasma Post Oxidation Technology to the Automobile Engine Parts Shafts (자동차 엔진부품용 Shaft에 플라즈마 산질화기술 적용)

  • Jeon, Eun-Kab;Park, Ik-Min;Lee, In-Sup
    • Korean Journal of Materials Research
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    • v.16 no.11
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    • pp.681-686
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    • 2006
  • Plasma nitrocarburising and plasma post oxidation were performed to improve the wear and corrosion resistance of S45C and SCM440 steel by a plasma ion nitriding system. Plasma nitrocarburizing was conducted for 3h at $570^{\circ}C$ in the nitrogen, hydrogen and methane atmosphere to produce the ${\varepsilon}-Fe_{2-3}$(N, C) phase. Plasma post oxidation was performed on the nitrocarburized samples with various oxygen/hydrogen ratio at constant temperature of $500^{\circ}C$ for 1 hour. The very thin magnetite ($Fe_3O_4$) layer $1-2{\mu}m$ in thickness on top of the $15{\sim}25{\mu}m$ ${\varepsilon}-Fe_{2-3}$(N, C) compound layer was obtained by plasma post oxidation. A salt spray test and electrochemical testing revealed that in the tested 5% NaCl solution, the corrosion characteristics of the nitrocarburized compound layer could be further improved by the application of the superficial magnetite layer. Throttle valve shafts were treated under optimum plasma processing conditions. Accelerated life time test results, using throttle body assembled with shaft treated by plasma nitrocarburising and post oxidation, showed that plasma nitrocarburizing and plasma post oxidation processes could be a viable technology in the very near future which can replace $Cr^{6+}$ plating.

A Study on the Corrosion Resistance of Free Cutting Steels after Oxy-Nitriding (진공산질화기술에 의한 쾌삭강의 내부식성 향상기술)

  • Moon, Kyoung Il;Kim, Sang Gweon;Kim, Sung Wan
    • Journal of the Korean Society for Heat Treatment
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    • v.19 no.2
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    • pp.90-95
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    • 2006
  • Nitriding or carburizing of carbon steels results in good mechanical properties such as high surface hardness and wear resistance but it has no affection on the corrosion resistance. Corrosion properties of nitriding and carburizing steels could be deteriorated. So, recently, there have been great demand for oxi-nitriding to enhance both mechanical properties and corrosion resistance. In this study, the corrosion resistance of carbon steel, S35C, and free cutting steel, SUM222, are prepared by vacuum nitriding and vacuum post-oxidation were compared with those treated by nitriding. After vacuum post-oxidation, $5{\mu}m$ oxide layer was formed on the nitride layer with $20{\sim}30{\mu}m$ depth. Potentio-dynamic polarization curve in corrosion test showed that the corrosion potential after post oxidation was increased from 200 mV to 800 mV in S35C and from 600 mV to 1200 mV in SUM222. SEM analyses showed that pores was increased and surface roughness became rougher with post oxidation. However, the formation of $Fe_3O_4$ resulted in the enhanced corrosion resistance of steels.

Effects of Heat Treatment on Corrosion Resistance Properties of Gas Nitrided Stainless Steels (스테인레스강의 가스질화 후 내식특성에 미치는 열처리조건의 영향)

  • Kim, H.G.;Kim, Y.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.22 no.5
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    • pp.298-306
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    • 2009
  • Gas nitriding and post oxidation were performed on stainless steels and SACM 645 steel. With increasing gas nitriding time, the increasing rate of nitrided layer was most rapid on SACM 645 steel and the nitriding depth of nitrided layer was most narrow on STS 304 steel among three steels. Corrosion resistance was increased with post oxidation on stainless steels and with increasing time the effect of corrosion resistance was decreased to compare with relatively short gas nitriding time. An improvement effect of corrosion resistance was consisted of predominantly on austenitic stainless steel by post oxidation after gas nitriding among three steels and it was relatively less influenced on martensitic stainless steel.

MOSFET Characteristics and Hot-Carrier Reliability with Sidewall Spacer and Post Gate Oxidation (Sidewall Spacer와 Post Gate Oxidation에 따른 MOSFET 특성 및 Hot Carrier 신뢰성 연구)

  • 이상희;장성근;이선길;김선순;최준기;김용해;한대희;김형덕
    • Proceedings of the IEEK Conference
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    • 1999.06a
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    • pp.243-246
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    • 1999
  • We studied the MOSFET characteristics and the hot-carrier reliability with the sidewall spacer composition and the post gate oxidation thickness in 0.20${\mu}{\textrm}{m}$ gate length transistor. The MOSFET with NO(Nitride+Oxide) sidewall spacer exhibits the large degradation of hot-carrier lifetime because there is no buffering oxide against nitride stress. When the post gate oxidation is skipped, the hot-carrier lifetime is improved, but GIDL (Gate Induced Drain Leakage) current is also increased.

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Chromaticity removal by chlorine and ozone oxidation in water treatment (상수처리에서 염소 및 오존산화를 이용한 색도제거)

  • Lee, Jeonghoon;Kim, Jinkeun
    • Journal of Korean Society of Water and Wastewater
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    • v.31 no.4
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    • pp.273-279
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    • 2017
  • Optimal processes to remove chromaticity at E water treatment plant(WTP) mainly caused by algae of E lake in Jeju island were investigated based on lab-tests of chlorine and ozone oxidation. 42.9% of chromaticity of filtered water was removed by chlorine oxidation under pH 7.0~8.0, dose of 1.0 mg/L with contact time of 30~60 min. On the other hand, chromaticity removal was 71.4% when post-ozone dose of 0.9~1.9 mg/L and pH 9.0, while it was increased to 86.7% under post-ozone dose of 3.1~7.3 mg/L and pH 9.0. However, there was no significant chromaticity removal efficiency increase when ozone doses were higher than 5.0 mg/L regardless of feeding point(i.e., pre-ozonation and post-ozonation) and pHs(i.e., 7.0 and 9.0.) under the experimental conditions. Based on the results, chlorine oxidation using existing chlorination facilities at the WTP is recommended for lower chromaticity while ozone oxidation is recommended for higher chromaticity by installing new ozone feeding facilities.

The Effect of Post Oxidation on Corrosion Characteristics of Gas Nitrocarburised Carbon Steels (Nitrocarburising 처리된 탄소강의 내식특성에 미치는 Post Oxidation 효과)

  • Kim, Y.H.;Jung, K.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.12 no.1
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    • pp.9-20
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    • 1999
  • The effect of post oxidation, water-quenched after holding in air for 5~420 seconds or cooling or furnace cooling, on corrosion resistance and phase formation characteristics of the surface layer of SM20C and SM45C carbon steels after gas nirtrocarbursing in the $NH_3-5%CO_2-N_2$ gas atmosphere at $580^{\circ}C$ for 3hours is studied. The compound layers of two steels consist of ${\varepsilon}-Fe_{2-3}N$, ${\gamma}^{\prime}-Fe_4N$ and $Fe_3O_4$, phases, however, the quantity of ${\gamma}^{\prime}-Fe_4N$ phase increases for the furnace cooled specimen compared to that of air cooling specimen. With increasing $NH_3$ content in the gas mixture and also increasing the keeping time in the air after gas nitrocarburising, the ${\varepsilon}-Fe_{2-3}N$ phase of compound layer increases, while the decreased current density recognizing the improvement of corrosion resistance are shown. the passive current density of SM45C steel is lower than that of SM20C steel at the same nitrocarburising conditions.

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Evaluation on Enhanced Biodegradability in Landfill Leachate by Fenton Oxidation (Fenton 산화법에 의한 매립장 침출수의 생물 분해성 증진에 관한 평가)

  • Lee, Byung-Dae
    • Journal of the Korean Applied Science and Technology
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    • v.22 no.3
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    • pp.250-256
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    • 2005
  • This study was aimed to investigate treatment feasibility of leachate from D landfill that is located in gyr대ungbuk. From the analytical results of leachate, organic and nonbiodegradable matters were contained in high concentration. Thus chemical treatment was introduced to degrade nonbiodegradable matters in pre or post biological process. Two types of Fenton oxidation were adapted in this study. The first one is pre treatment process before biological treatment. The second one is post treatment process after biological treatment. The optimal conditions of both treatment methods were investigated as follows. In case of pre treatment process, the optimal conditions appeared in $Fe^{+2}/H_2O_2$(mmol/mmol): 0.1, $H_2O_2/CODcr$(mg/mg): 27.0, pH: 3 and reaction time: 2hrs. On the other hand, in case of post treatment process, the optimal conditions appeared in $Fe^{2+}$(mmol/mmol): 0.14, $H_2O_2/COD_{cr}$(mg/mg): 57.4, pH: 3 and reaction time: 1.25hrs. In the above optimal conditions, high COD removal was obtained in pre and post treatment process. Also it can expect that Fenton oxidation converted nonbiodegradable matters into biodegradable matters.