• 한국수소및신에너지학회논문집
• /
• 제28권4호
• /
• pp.392-400
• /
• 2017

An experimental study was conducted to investigate behavior of steel surface oxidation with characteristics of the combustion. The excess entalphy combustion in porous media system was applied to implement the direct radiation heating system. The surface oxidation thickness (SOT) of fuel-lean was thicker than the SOT of fuel-rich. Also, the SOT was increased by increasing residence time. Detailed explanations were given by SEM and EDS analysis.

• 한국수소및신에너지학회논문집
• /
• 제29권4호
• /
• pp.378-385
• /
• 2018

An experimental study was conducted to investigate behavior of surface oxidation with steel type. The excess entalphy combustion in porous media system was applied to implement the direct radiation heating system. The surface oxidation thickness (SOT) in fuel-lean condition was thicker than the SOT in fuel-rich. Also, the SOT was increased by increasing residence time. Detailed explanations were given by SEM and EDS analysis.

• Transactions on Electrical and Electronic Materials
• /
• 제11권5호
• /
• pp.230-233
• /
• 2010

The authors investigated the anodization mechanism of aluminum in an oxalic acid solution, and the electrochemical reaction is very unique for pore formation via the dissolution process, which is very dependent on the surface geometry in nanoporous alumina templates. The cross-sectional nanochannels showed that the geometrical curvature of the initial surface can cause the branching of nanochannels to be adjusted in volume occupancy to be direct to the electric field normal to the surface. The nanoporous alumina with the crystalline $\gamma-Al_2O_3$ phase showed hexagonal ordering at a voltage of 40 V, with a nanohole distance of 102 nm from the charge density oscillation of the oxalic acid solution.

• 대한기계학회:학술대회논문집
• /
• 대한기계학회 2003년도 춘계학술대회
• /
• pp.1590-1596
• /
• 2003

The experiments of boiling heat transfer were performed to investigate the boiling enhancement in saturated water by using multi-stage electroplated surface. In order to optimize the boiling performance, current flux and duration in multi-stage electroplating were varied. Current flux, 2 $A/12cm^2$ and 0.33 $A/cm^2$, and duration ranging from 15 second to 50 second are considered. The results showed that multi-stage electro plated surfaces generate enhancement of boiling parameters such as boiling incipient superheat, boiling heat transfer coefficient, and critical heat flux compared to plain surface. The SEM images of the coated surfaces were captured to examine the structure of porous surface, which provides the enhancement of boiling heat transfer.

• 한국결정성장학회지
• /
• 제16권3호
• /
• pp.106-111
• /
• 2006

The objective of this paper is to compare the surface features of two kinds of nano-porous activated carbon fiber (NPACF) treated with potassium and the variation of their properties by phosphoric acid pre-treatment. X-ray diffraction (XRD) patterns indicate that NPACF containing potassium species show better performance for potassium and potassium salts by pre-treatment with phosphoric acid. In order to present the causes of the differences in surface properties and specific surface area after the samples were treated with phosphoric acid, pore structure and surface morphology are investigated by adsorption analysis and SEM. For the chemical composition microanalysis for potassium loading of the NPACF pre-treated with phosphoric acid, samples were analyzed by EDX. Finally, the type and quality of oxygen groups are determined from the method proposed by Boehm.

• Carbon letters
• /
• 제2권2호
• /
• pp.91-98
• /
• 2001

Porous carbons have been prepared from different parts of banana stems using two different routes, viz., by pyrolysing the mass at different temperatures as well as by treating the dried mass with chemicals followed by pyrolysis. The pyrolysis behaviour of all these materials has been studied up to $1000^{\circ}C$. Samples treated with acids exhibit more increase in surface area as compared to those treated with alkalies or salts. Analysis of BET surface area shows that the carbon prepared at low temperature shows mixed porosity, i.e., micro and mesopores. Samples heated to high temperature above $700^{\circ}C$ show decrease in macroporosity and increase in microporosity. Liquid adsorption studies have been made using methylene blue and heavy oil. The activated carbons so prepared exhibit higher oil adsorption mainly in the macro and mesopores.

• 한국표면공학회지
• /
• 제37권5호
• /
• pp.289-295
• /
• 2004

A dense palladium-nikel (Pd-Ni) alloy composite membrane has been fabricated on microporous nickel support mixed with submicron/micron nickel powder instead of mesoporous stainless steel support. Plasma treatment process is introduced as pre-treatment process instead of HCI activation. Pd-Ni alloy composite membrane prepared by electro plating was fairly a uniform and dense surface morphology. The membrane was characterized by permeation experiments with hydrogen and nitrogen gases at temperature 773 K and pressure 2.2 psi. The results showed that hydrogen ($H_2$) permeance was 27 ml/$\textrm{cm}^2$ㆍatmㆍmin and hydrogen/ nitrogen ($_H2$$N_2$) selectivity was 8 at 773 K.

• Bulletin of the Korean Chemical Society
• /
• 제10권3호
• /
• pp.292-297
• /
• 1989

In this work we have experimentally observed the physisorption isotherms for nitrogen, TMS, cyclohexane, benzene, and n-hexane adsorbed on flat aluminum foil surface and have analyzed them theoretically on the basis of the theory proposed by Chang et al. The results show that the theory by Chang et al. can provide a useful means to describe the physisorption of gases on uniform flat solid surface which is essentially important for analysis of the pore volume distribution in porous solid surface. We have also discussed the application of the results obtained in this work to the analysis of pore volume distribution in porous alumina we reported previously.

• 한국재료학회지
• /
• 제16권3호
• /
• pp.178-182
• /
• 2006

A single electro-discharge-sintering (EDS) pulse (1.0 kJ/0.7 g), from a $300{\mu}F$ capacitor, was applied to atomized spherical Ti-6Al-4V powder in a low vacuum to produce porous-surfaced implant compacts. A solid core surrounded by a porous layer was formed by a discharge in the middle of the compact. XPS (X-ray photoelectron spectroscopy) was used to study the surface characteristics of the implant material. C, O, and Ti were the main constituents, with smaller amounts of Al, V, and N. The implant surface was lightly oxidized and was primarily in the form of $TiO_2$ with a small amount of metallic Ti. A lightly etched EDS implant sample showed the surface form of metallic Ti, indicating that EDS breaks down the oxide film of the as-received Ti-6Al-4V powder during the discharge process. The EDS Ti-6Al-4V implant surface also contained small amounts of aluminum oxide in addition to $TiO_2$. However, V detected in the EDS Ti-6Al-4V implant surface, did not contribute to the formation of the oxide film..

• 한국세라믹학회지
• /
• 제55권2호
• /
• pp.153-159
• /
• 2018

Porous ceramic plates were prepared from Onggi clay and bamboo charcoal powder at 1100 and $1200^{\circ}C$ and their porous properties and water absorption, and the cooling effect of porous plates, were investigated to produce eco-friendly porous ceramics for a self-cooling system that relies on the evaporation of absorbed water. Porous properties were dependent on the particle size of charcoal powder pore forming additive and the firing temperature; properties were also found to be dependent on the total pore volume, average pore size and porosity, which had values of $0.103-0.243cm^3/g$, 0.81 - 2.56 mm and 20.9 - 38.2%, respectively, at $1100^{\circ}C$ and $0.04-0.18cm^3/g$, 0.33 - 2.03 mm and 10.8 - 30.9%, respectively, at $1200^{\circ}C$. Cooling temperature difference of flowing air parallel to surface of porous ceramic plates fired with two kinds of charcoal powder at $1100^{\circ}C$ was $3.5-3.6^{\circ}C$ at $26^{\circ}C$ and 60% of relative humidity in a closed box. Cooling temperature difference was dependent on the number of porous plates and the distance between porous plates. A simple and eco-friendly cooling system using porous ceramic plates fired from Onggi clay and charcoal powder was proposed.