• 제목/요약/키워드: Porous Substrate

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수학적 귀납법을 이용한 정삼투 및 압력지연삼투 공정의 투과율 불균형 해석 (Intrinsic Flux Inequality in Forward Osmosis (FO) and Pressure-Retarded Osmosis (PRO) Processes)

  • ;이승원
    • 멤브레인
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    • 제25권4호
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    • pp.367-372
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    • 2015
  • 정삼투와 압력지연삼투 공정에서 용매의 투과율은 용매와 막이 접촉하는 방식에 의존한다. 각각의 공정에서 막의 활성층이 고농도 용매와 접촉하는 경우를 압력지연삼투 방식이라 하고, 고농도 용매가 막의 다공성 지지하층과 직면해 있는 경우를 정삼투 방식이라고 한다. 압력지연삼투 방식과 정삼투 방식은 각각 희석형 그리고 농축형의 내부농도 분극 현상을 유발하는데, 동일한 조작 조건에서 정삼투 방식보다 압력지연삼투 방식이 높은 투과율을 나타내는 현상이 실험적으로 관측되었다. 본고에서는 정삼투방식과 압력지연삼투 방식에서 발생하는 본질적인 투과율 불균형을 수학적 귀류법을 이용하여 증명하고, 물리적인 원인을 규명한다.

Hot Wire CVD를 이용한 다결정 Si 박막의 고속 저온 증착 (Fast and Low Temperature Deposition of Polycrystalline Silicon Films by Hot Wire CVD)

  • 이정철;강기환;김석기;윤경훈;송진수;박이준
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2001년도 하계학술대회 논문집 C
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    • pp.1427-1429
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    • 2001
  • Polycrystalline silicon(poly-Si) films are deposited on low temperature glass substrate by Hot-Wire CVD(HWCVD). The structural properties of the poly-Si films are strongly dependent on the wire temperature($T_w$). The films deposited at high $T_w$ of 2000$^{\circ}C$ have superior crystalline properties; average lateral grain sizes are larger than $1{\mu}m$ and there at·e no vertical grain boundaries. The surface of the high $T_w$ samples are naturally textured like pyramid shape. These large grain size and textured surface are believed to give high current density when applied to solar cells. However, the poly-si films are structurally porous and contains high defect density, by which high concentration of C and O resulted within the films by air-penetration after removed from chamber.

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접촉 표면의 강성 변화에 따른 박테리아의 군집 패턴 (Bacterial Pattern Formation in Response to the Stiffness of Substrates)

  • 김중경;박은정;김성래;조명옥;한화택
    • 한국가시화정보학회:학술대회논문집
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    • 한국가시화정보학회 2007년도 추계학술대회
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    • pp.88-91
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    • 2007
  • Animal cells show different behaviors in response to the mechanical properties of the substrates. We hypothesize that the rigidity of the substrates also affects the bacterial motility and controls the colony dynamics. It is found that the colony size of Escherichia colis and Bacillus subtilis grown on the agar plates is correlated with agarose gel concentrations and thus with the substrate rigidity. High- resolution microscopic imaging reveals that bacteria in single colonies form different aggregation patterns on the agar plates with varying gel concentration. We measured the apparent diffusion coefficients in the agarose gel plates made with different gel concentrations. Mathematical modeling and quantitative imaging of dye dispersion in the agar plates suggest that there is a close connection between the diffusion rate and the colony size. Nanoscale pore structures and kinetic constraints in the porous media may have an effect on bacterial colony dynamics.

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열화학기상증착법에 의해 실리콘 기판위에 수직방향으로 정렬된 탄소나노튜브의 성장 (Growth of vertically aligned carbon nanotubes on silicon substrates by the thermal CVD)

  • 이철진;김대운;이태재;박정훈;손권희;류승철;최영철;박영수;최원석
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 1999년도 하계종합학술대회 논문집
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    • pp.275-278
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    • 1999
  • We have grown vertically aligned carbon nanotubes in a large area of Co-Ni codeposited Si substrates by the thermal CVD using $C_2$H$_2$gas. Since the discovery of carbon nanotubes, Synthesis of carbon nanotubes for mass production has been achieved by several methods such as laser vaporization, arc discharge, and pyrolysis. In particular, growth of vertically aligned nanotubes is of technological importance for applications to FED. Recently, vertically aligned carbon nanotubes have been grown on glass by PECVD. Aligned carbon nanotubes can be also grown on mesoporous silica and Fe patterned porous silicon using CVD. Despite such breakthroughs in the growth, the growth mechanism of the alignment are still far from being clearly understood. Furthermore, FED has not been clearly demonstrated yet at a practical level. Here, we demonstrate that carbon nanotubes can be vertically aligned on catalyzed Si substrate when the domain density reaches a certain value. We suggest that steric hindrance between nanotubes at an initial stage of the growth forces nanotubes to align vertically and then nanotubes are further grown by the cap growth mechanism.

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A Comparison of Efficiency of Decolorizing Rhodamine B using Lab-Scale Photocatalytic Reactors : Slurry Reactor, IWCR and PFBR

  • Na, Young-Soo;Lee, Tae-Kyung;Lee, Song-Woo;Lee, Chang-Han;Kim, Do-Han;Park, Young-Seek;Song, Seung-Koo
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • 제10권S_4호
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    • pp.157-164
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    • 2001
  • The performance of fluidized-bed reactor with Photomedia, immobilized TiO$_2$ onto the porous ceramic ball using a sol-gel method has been studied in this work. A simple model substrate, dilute Rhodamine B (RhB), was decolorized at room temperature. For the purpose of comparison, the slurry reactor and the Inner Wall Coated Reactor (IWCR) were used. The aim of this work was to develop the photocatalytic fluidized bed reactor (PFBR) through contrasting the photodegradability of various reactors such as the TiO$_2$slurry reactor, the inner-wall coated reactor (IWCR). In this study, the RhB was decolorized in three types of reactor. Even though the reaction rate constant of PFBR was lower than that of slurry reactor, PFBR had the advantages of preventing the wash-out of photocatalyst, so it can be operated continuously.

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표면 마이크로머시닝을 이용한 산화된 다공질 실리콘 기판 위에 제조된 에어브리지를 가진 Coplanar Waveguides (Coplanar Waveguides with Air-Bridge Fabricated on Oxidzed Porous Silicon (OPS) Substrate using Surface Micromachining)

  • 심준환;박동국;강인호;권재우;이종현;예병덕
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2002년도 하계학술대회 논문집 C
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    • pp.2026-2028
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    • 2002
  • 본 논문에서는 실리콘 기판상의 전송선로 특성을 개선하기 위하여 표면 마이크로머시닝 기술을 이용하여 $10{\mu}m$ 두께의 다공질 실리콘 산화막으로 제조된 기판 위에 에어브리지를 가진 CPW 전송선로와 phase shifter를 제작하였다. 간격이 $30{\mu}m$, 신호선이 $80{\mu}m$인 CPW 에어브리지 전송선의 삽입손실은 4 GHz에서 -0.25 dB이며, 반사손실은 -28.9 dB를 나타내었다. CPW phase shifter의 크기는 S-W-$S_g$ = 100-30-400 ${\mu}m$로 설계되었다. "ㄷ" 모양을 가진 에어브리지의 폭은 $100{\mu}m$. 길이는 400-460-400 ${\mu}m$이다. 낮은 손실을 얻기 위한 Step된 에어브리지를 가진 phase shifter 구조가 step이 없는 에어브리지를 가진 구조보다 삽입손실이 보다 더 향상되었다. 제작된 CPW phase shifter의 위상특성은 28 GHz의 넓은 주파수 범위에서 $180^{\circ}E 의 천이를 타나내었다. 이상과 같은 결과로부터 두꺼운 다공질 실리콘은 고 저항 실리콘 집적회로 공정에서 고성능 저가의 마이크로파 및 밀리미터파 회로 응용에 충분히 활용 될 수 있으리라 기대된다.

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코발트 산화물 전극의 수퍼커페시터 성질에 미치는 니켈 폼 집전체 효과 (Effect of Nickel Foam Current Collector on the Supercapacitive Properties of Cobalt Oxide Electrode)

  • 윤여일;김광만;고장면
    • 한국세라믹학회지
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    • 제45권6호
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    • pp.368-373
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    • 2008
  • An electrode for supercapacitor using 3-dimensional porous nickel foam as a current collector and cobalt oxide as an active material was prepared and characterized in terms of morphology observation, crystalline property analysis, and the investigation of electrochemical property. The electrode surface showed that the cobalt oxide was homogeneously coated as the crystalline phase of $Co_3O_4$. Cyclic voltammetry for the $Co_3O_4$/nickel foam electrode exhibited higher specific capacitance values (445 F/g at 10 mV/s and 350 F/g at 200 mV/s) and excellent capacitance retention ratio (99% after $10^4$ cycles). It was proved that the nickel foam substrate played the roles in reducing the interfacial resistance with cobalt oxide and in improving the electrode density by embedding greater amount of cobalt oxide within it.

Co-Ni 합금위에서 수직방향으로 정렬된 탄소나노튜브의 성장 (Growth of Vertically Aligned Carbon Nanotubes on Co-Ni Alloy Metal)

  • 류재은;이철진;이태재;손경희;신동혁
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제49권8호
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    • pp.451-454
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    • 2000
  • We have grown vertically aligned carbon nanotubes in a large area of Co-Ni codeposited Si substrates by the thermal CVD usign $C_2H_2$ gas. Since the discovery of carbon nanotubes, growth of carbon nanotubes has been achieved by several methods such as laser vaporization, arc discharge, and pyrolysis. In particular, growth of vertically aligned nanotubes is important to flat panel display applications. Recently, vertically aligned carbon nanotubes have been grown on glass by PECVD. Aligned carbon nanotubes can be also grown on mesoporous silica and Fe patterned porous silicon using CVD. In this paper, we demonstrate that carbon nanotubes can be vertically aligned on catalyzed Si substrate when the domain density of catalytic particles reaches a certain value. We suggest that steric hindrance between nanotubes at an initial stage of the growth forces nanotubes to align vertically and each nonotubes are grown in bundle.

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금속기질에 앓은 마이크로 다공질 스케폴드 코팅에 관한 연구 (Thin Micro-Porous Scaffold Layer on Metallic Substrate)

  • 신동춘;자이젱 미아오;김원철
    • 동력기계공학회지
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    • 제14권5호
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    • pp.41-47
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    • 2010
  • 티타늄과 티타늄 합금은 재료적 특이성 때문에 심장 혈관 임플란트에서 일반적으로 사용되어 왔다. 일찍이 적용된 예로는 인공심장판막, 심박조율기의 보호케이스, 혈액 순환 장치 등이 있다. 하지만 물질유도혈전증(Material-induced thrombosis)은 혈전폐색에 의해 기인한 기능 손실로 심장혈관 임플란트 장치의 주된 합병증으로 존재하고 있으며, 심장혈관 임플란트의 혈전유전자는 심장혈관장치의 발달에 주된 난관 중 하나로 남아있다. 그리고 텍스처 혈액 접합 물질(Textured blood-contacting material)은 1960년대 초반 이후부터 혈액순환 보조 장치의 임상실험에 사용되고 있다. 접합 물질에 내장된 텍스처 섬유조직 표면은 형성, 성장, 안정적 부착, 생물학적 내벽(neointimal layer) 등 유도 혈액(entrapping blood) 성분에 의해 형성된다. 공동(cavity) 형상의 용해 가능한 미립자를 사용하는 SCPL법(Solvent casting/particulate leaching method)은 티타늄 기질 이전에 형성된 폴리우레탄 위에 텍스처(texture)를 생성하기 위해 사용되었다. 또한 콜라겐의 부동화(不動化)에 의한 공동(cavity)은 혈액 접합면에 잔존하기 위한 내피세포를 고정할 수 있는 효과가 있다. cpTi로 층화된 PU 기소공성(microporous)은 구조적 특성과 혈전증 감소를 위한 생물학적 내벽 사용의 잠재성을 평가하기 위한 세포 공동체 실험을 통해서 평가되었다.

폴리머 기판위에 형성된 나노구조제어 알루미나의 캐패시터 특성 (Capacitance Properties of Nano-Structure Controlled Alumina on Polymer Substrate)

  • 정승원;민형섭;한정환;이전국
    • 한국재료학회지
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    • 제17권2호
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    • pp.81-85
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    • 2007
  • Embedded capacitor technology can improve electrical perfomance and reduce assembly cost compared with traditional discrete capacitor technology. To improve the capacitance density of the $Al_2O_3$ based embedded capacitor on Cu cladded fiber reinforced plastics (FR-4), the specific surface area of the $Al_2O_3$ thin films was enlarged and their surface morphologies were controlled by anodization process parameters. From I-V characteristics, it was found that breakdown voltage and leakage current were 23 V and $1{\times}10^{-6}A/cm^2$ at 3.3 V, respectively. We have also measured C-V characteristics of $Pt/Al_2O_3/Al/Ti$ structure on CU/FR4. The capacitance density was $300nF/cm^2$ and the dielectric loss was 0.04. This nano-porous $Al_2O_3$ is a good material candidate for the embedded capacitor application for electronic products.