• 제목/요약/키워드: Porous Layer

검색결과 754건 처리시간 0.022초

Al장극산화법에 의한 반휴분이용 다공성 격영의 제조에 관한 연구 (A Study on the Manufacturing of Porous Membrane for Separation of Gas Mixture by Al Anodizing Method)

  • 윤은열;라경용
    • 한국표면공학회지
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    • 제15권2호
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    • pp.69-76
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    • 1982
  • With a view to manufacturing membranes for separation of gas mixtures, Al foils were anodized in a 2% oxalic-acid electrolyte at 40V and 80V. When anodizing was completed and Barrier layer existed at the extreme back site of the foil, the anodized foil was made to react with only electrolyte, with switching off the electric power. When the size and density of pores were changed through voltage change, the membr-anes did not show large difference in the permeability. Reacting with electrolyte, the existing Barrier layer turns into porous layer. During this process, several small pores grow from one relatively large pore, getting to the back site. The number and size of the small pores getting to the back surface increase as time passing. This change of Barrier layer into porous layer is thought to be directly related to the permeability change of the membranes. The selectivity of an anodized Al membrane was not related to the voltage change, and was high, being similar to the theoretical selctivity of metallic membranes, according to my observation.

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용액 반응에 의한 패각 표면의 수산화아파타이트 층 생성 거동 (Formation of Solution-derived Hydroxyapatite Layer on the Surface of a Shell)

  • 김희래;송태웅
    • 한국세라믹학회지
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    • 제39권12호
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    • pp.1177-1182
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    • 2002
  • 인산염 용액과의 반응으로 패각의 표면에 고 비표면적의 다공성 수산화아파타이트 층이 생성되는 거동을 정성적으로 관찰하였다. 수산화아파타이트의 생성기구는 패각 표면을 핵으로하는 용해-석출 반응으로 보이며 층의 생성은 다음의 과정에 의하였다. 1. 고상 표면 상의 고밀도 핵생성 및 성장 2. 결정의 접촉과 엉킴에 의한 미세 다공성 층의 형성 3. 층을 통한 용액의 확산과 내측으로의 층 두께의 성장

다공성 실리콘을 이용한 LED의 발광 특성에 관한 연구 (A Study on Characteristics of Light Emitting Diode with Porous Silicon)

  • 이성훈;이치우
    • 전기화학회지
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    • 제3권1호
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    • pp.39-43
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    • 2000
  • n형 실리콘으로 제조한 다공성 실리콘을 이용하여 Light-emitting diode(LED)를 제작하고, LED를 구성하는데 있어서 전극 물질들을 변화시켰을 때 나타나는 LED의 전류 대 전압의 특성과 공급되어지는 전류의 세기에 따른 전계 발광 (Electroluminescence: EL) 세기의 변화를 관찰하고, 일정 전위에 대한 EL 세기의 시간 의존도를 여러 전위에 대해서 알아보았다. 또한 전극 물질과 다공성 실리콘층(Porous Silicon Layer: PSL)의 접촉 면적을 넓혀주기 위해서 In을 PSL 위에 전기 화학적으로 전착시켰을 때 나타나는 LED의 전기적 특성과 EL의 특성에 대해 알아보았다.

Enhanced Photoelectrochemical Behavior of Gold-coated Porous n-Si Electrochemically Modified with Polyaniline

  • Park, Soo-Jin;Chae, Won-Seok;Kim, Kang-Jin
    • 분석과학
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    • 제8권4호
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    • pp.637-642
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    • 1995
  • The presence of a porous Si layer(PSL) formed on the surface of crystalline silicon by electrochemical etclling in HF solution is found to enhance the stability of n-Si photoanodes, but porous n-Si thus formed is still liable to corrode upon exposure to excitation light. To improve the stability of the porous n-Si electrodes and to reduce the photo-induced corrosion, we have examined the PEC behavior of porous n-Si modified with polyaniline(PANI) and 3 nm thick layer of Au. Comparisons were made between Au/PSL and PANl/Au/PSL photoelectrodes.

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Activated Carbons as Electrode Materials in Electric Double-Layer Capacitors I. Electrochemical Properties of Activated Carbons in Relation to their Porous Structures and Surface Oxygen Functional Groups

  • Kim, Chang-Hee;Pyun, Su-Il
    • 한국세라믹학회지
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    • 제40권9호
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    • pp.819-826
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    • 2003
  • This article is concerned with the overview of activated carbons as electrode materials in electric double-layer capacitors. Firstly, this article introduced various types of activated carbons with their precursors and manufacturing conditions which can be divided into two main steps of the carbonization and activation processes. Secondly, the present article gave the detailed discussion about the porous structures and examined previous works on the electrochemical behaviors of activated carbons in relation to their porous structures, along with our recent works. Finally, this article characterized the surface oxygen functional groups and presented their influence on the electrochemical properties of activated carbons by reviewing our recent results.

Boussinesq 식을 사용하여 Cnoid 파의 투수방파제 월파 해석: Navier-Stokes 식 결과와 비교 (Numerical Simulation of Overtopping of Cnoidal Waves on a Porous Breakwater Using the Boussinesq Equations: Comparison with Solutions of the Navier-Stokes Equations)

  • 휜탄트;이창훈;안석진
    • 한국해안·해양공학회논문집
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    • 제31권2호
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    • pp.41-49
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    • 2019
  • 1개층 Boussinesq 방정식(Vu 등, 2018)과 2개층 Boussinesq 방정식(Huynh 등, 2017)을 사용하여 투수방파제를 지나는 cnoid 파의 월파고를 구하였다. 수치실험을 통해 천단고가 낮은 투수방파제를 지나는 cnoid 파의 월파고(Navier-Stokes 방정식으로 구함)가 천단고가 높은 투수방파제를 지나는 통과파고(1개층 Boussinesq 방정식으로 구함)보다 더 작고, 천단고가 해저에 있는 투수방파제를 지나는 통과파고(2개층 Boussinesq 방정식으로 구함)보다 더 크다는 것을 확인하였다. cnoid 파의 파고가 낮을수록 또는 투수방파제의 폭이 좁을수록 1개층 및 2개층 Boussinesq 방정식으로 구한 통과파고가 Navier-Stokes 방정식으로 구한 월파고에 근접한 것을 확인하였다.

다공질 실리콘의 유기가스 검지 특성 (Sensing Properties of Porous Silicon Layer for Organic Vapors)

  • 김성진;이상훈;최복길
    • 한국전기전자재료학회논문지
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    • 제15권11호
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    • pp.963-968
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    • 2002
  • In this work, porous silicon (PS) layer is investigated as a sensing material to detect organic vapors such as ethanol (called alcohol), methanol, and acetone in low concentrations. To do this, PS sensors were fabricated. They have a membrane structure and comb-type electrodes were used to detect the change of electrical resistance effectively. PS layer on Si substrates was formed by anodization in HF solution of 25%. From fabricated sensors, current-voltage (Ⅰ-Ⅴ) curves were measured for gases evaporated from 0.1 to 0.5% organic solution concentrations at 36$\^{C}$. As the result, all curves showed rectifying behavior due to a diode structure between Si and the PS layer. The conductance of most sensors increased largely at high voltage of 5V, but the built-in potential on the measured Ⅰ-Ⅴ curve was lowered inversely by the adsorption effect of the organic vapors with high dipole moment.

CONVECTION IN A HORIZONTAL POROUS LAYER UNDERLYING A FLUID LAYER IN THE PRESENCE OF NON LINEAR MAGNETIC FIELD ON BOTH LAYERS

  • Bukhari, Abdul-Fattah K.;Abdullah, Abdullah A.
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • 제11권1호
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    • pp.1-11
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    • 2007
  • A linear stability analysis applied to a system consist of a horizontal fluid layer overlying a layer of a porous medium affected by a vertical magnetic field on both layers. Flow in porous medium is assumed to be governed by Darcy's law. The Beavers-Joseph condition is applied at the interface between the two layers. Numerical solutions are obtained for stationary convection case using the method of expansion of Chebyshev polynomials. It is found that the spectral method has a strong ability to solve the multilayered problem and that the magnetic field has a strong effect in his model.

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Shear wave in a fiber-reinforced anisotropic layer overlying a pre-stressed porous half space with self-weight

  • Kakar, Rajneesh;Kakar, Shikha
    • Smart Structures and Systems
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    • 제18권5호
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    • pp.911-930
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    • 2016
  • The main purpose of this paper is to study the effects of initial stress, gravity, anisotropy and porosity on the propagation of shear wave (SH-waves) in a fiber-reinforced layer placed over a porous media. The frequency equations in a closed form have been derived for SH-waves by applying suitable boundary conditions. The frequency equations have been expanded and approximated up to $2^{nd}$ order of Whittaker's function. It has been observed that the SH-wave velocity decreases as width of fiber-reinforced layer increases. However, with the increase of initial stress, gravity parameter and porosity, the phase velocity increases. The results obtained are in perfect agreement with the standard results investigated by other relevant researchers.

나노 기공성 알루미나의 생성과 화학적 용해 거동 (Formation and Chemical Dissolution Behaviors of Nano Porous Alumina)

  • 오한준;정용수;지충수
    • 한국표면공학회지
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    • 제43권5호
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    • pp.217-223
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    • 2010
  • For an application as templates of high performance with proper pore size and shape, porous anodic alumina films were prepared by anodization in oxalic acid, and formation behaviors of anodic alumina layer as well as dissolution process in acid solution have been investigated. The surface characteristics on anodic alumina layer were shown to be dependent on the fabrication parameters for anodization. For the dissolution behaviors of anodic alumina, the thickness of the barrier-type alumina layer decreased linearly with the rate of 0.98 nm/min in $H_3PO_4$ solution at $30^{\circ}C$. The changes of the anodic alumina layers were analyzed by SEM and TEM.