Browse > Article
http://dx.doi.org/10.4191/KCERS.2002.39.12.1177

Formation of Solution-derived Hydroxyapatite Layer on the Surface of a Shell  

Kim, Hui-Lae (Division of Advanced Materials Engineering, Kyungnam University)
Song, Tae-Woong (Division of Advanced Materials Engineering, Kyungnam University)
Publication Information
Abstract
Highly surfaced and porous hydroxyapatite body was artificially formed on the surface of a shell through a reaction with phosphatic solutions. As a result of qualitative observation, hydroxyapatite seemed to be crystallized by solution-precipitation process accelerated by the nucleation surface of a shell. The process of formation of hydroxyapatite layer was as follows. 1. Dense nucleation and growth on the surface of solid phase 2. Formation of microporous layer by contact and entanglement between crystallines 3. diffusion of solution through the porous layer and thickness growth of layer towards inside
Keywords
Porous hydroxyapatite body; Shell; Solution-precipitation Process;
Citations & Related Records
연도 인용수 순위
  • Reference
1 R. Z. LeGeros, 'Biological and Synthetic Apatites,' pp. 3-28 in Hydroxyapatite and Related Materials, Ed. P. W. Brown. CRC Press, London & Tokyo (1994)
2 Y. Fang, D. K. Agrawal and D. W. Roy, 'Thermal Stability of Synthetic Hydroxyapatite,' pp. 269-82 in Hydroxyapatite and Related Materials, Ed. P. W. Brown. CRC Press, London & Tokyo (1994)
3 E. A. Monroe, W. Votya and D. B. Bass, 'New Calcium Phosphate Ceramic Material for Bone and Tooth Implants,'J. Dent Res., 50 860 (1971)   DOI   ScienceOn
4 O. Bermudez, M. G. Boltong, F. C. M. Dnessens and J. A. Planell, 'Compressive Strength and Diametral Tensile Strength of Some Calcium Orthophosphate Cements : A Pilot Study,' J. Mater. Scie.: Materiats in Medicine, 4 389-93 (1993)   DOI   ScienceOn
5 L. C. Chow, S. Takagi, P. D. Costantino and C. D. Friedman, 'Self-setting Calcium Phosphate Cements,' Mat. Res. Soc. Symp. Proc., 179 (1991)
6 M. Yoshmura, H. Suda, K. Okamoto and K. loku, 'Hydro thermal Synthesis bf Biocompatible Whisker,' J. Mater. Sci., 29 399-422 (1994)
7 Y. D. Son and T. W. Song, 'Hydrothermal Synthesis of Hydroxyapatite Whiskers for Reinforcement of Bioce ments,' J. Kor. Ceram. Soc., 38 [7] 648-53 (2001)
8 D. M. Roy and S. K. Linnehan, 'Hydroxyapatite Formed from Coral Skeletal Carbonate by Hydrothermal Exchange,' Nature, 247 220-22 (1974)   DOI
9 D. K. Smith, 'Calcium Phosphate Apatites in Nature,' pp. 29-44 in Hydroxyapatite and Related Materials, Ed. P. W. Brown. CRC Press, London & Tokyo (1994)
10 K. Ishikawa, S. Takagi, L. C. Chow and Y. Ishikawa, 'Properties and Mechanisms of Fastsetting Calcium Phosphate Cements,' J. Mater. Sci.:Mater. in Med., 6 528-33 (1995)   DOI   ScienceOn
11 G. H. Nancollas and J. Zhang, 'Formation and Disolution Mechanism of Calcium Phosphates in Aqueous Systems,' Hydroxyapatite and Related Materials, Ed. P. W. Brown, CRC Press, London & Tokyo, p73 (1994)
12 M. Yoshmura, H. Suda, K. Okamoto and K. loku, 'Hydro thermal Synthesis of Needle like Apatite Crystals,' Nippon Kaeaku Kaishi, 10 3101-06 (1991)
13 P. W. Brown, 'Phase Relationships in the Temary System CaO-P$_{2}O_{5}-H_{2}O at 25{\circ}C,' J. Am. Ceram. Soc., 75 1 (1992)
14 Y. D. Son and T. W. Song, 'Microstructure and Mechanical Strength of Hardened Paste of Hydroxyapatite Cement Containing Whisker Phase,' J. Kor. Ceram. Soc., 36 [12] 1342-49 (1999)