• Title/Summary/Keyword: Porous Layer

Search Result 754, Processing Time 0.027 seconds

The Effects of Anodizing Process Parameters and Oxidation Temperature under Atmospheric Environment on Morphology of the Pure Titanium by Alternating Current Arc-anodizing (순티타늄의 교류 불꽃 양극산화층 미세조직에 미치는 양극산화공정변수 및 대기산화온도의 영향)

  • Yang, Hack-Hui;Park, Chong-Sung
    • Journal of the Korean institute of surface engineering
    • /
    • v.41 no.1
    • /
    • pp.16-22
    • /
    • 2008
  • Anodizing to form oxide layers on the pure titanium was performed in the electrolyte containing 1.5M $H_2SO_4$, 0.2M $H_3PO_4$, and 2.5wt.% $CuSO_4$ using the ac-biased arc anodizing technique. Titanium oxide layers anodized with different applied voltages, voltage-elevating rates, and anodizing times were investigated. In addition, thermal oxidation test under an atmospheric environment for the arc-anodized specimens was carried out. The thickness of oxide layers were not affected by the voltage-elevating rates, but increased slightly with the increase of anodizing times. The thickness of oxide layers were increased with the increase of voltages, and increased remarkably in the condition of 200V. The size and number of the pore observed in the center of the porous cell were decreased with increase of applied voltage. From the result of thermal oxidation test, it revealed that oxide layer formed by arc anodizing more effective to prevent oxidation of pure titanium.

The Permeability Characteristics of the Reactive Soil - Bentonite Landfill Liner (혼합반응 차수재의 투수특성 연구)

  • 이강원;황의석;안기봉;정하익;김학문
    • Proceedings of the Korean Geotechical Society Conference
    • /
    • 2002.10a
    • /
    • pp.545-552
    • /
    • 2002
  • The purpose of this paper is to investigate permeability characteristic of soil-bentonite landfill liner and development of desirable liner system. In this study, permeability tests for soil-bentonite, reactive soil-bentonite and apply bentomat and reactive mat are carried out under the low and high water pressure. According to test result, additional amount of bentonite decreases the coefficient of permeability up to the bentonite mixture ratio of 15%. Therefore, the permeability test for landfill liner's indicated that the use of general water would be in more safe side because the liner system show low permeability duet decrease effect of porous by suspended soild(SS). The permeability of leachate for Zeolite mixture ratio 0, 5, 10% with bentonite mixture ratio 15% showed negligible variation in the permeability with general water. Therefore, Zeolite could be used as a successful that is available purification material for the treatment of leachate, without changing the of landfill liners. Also odious smell could be removed by adding smell amount of Zeolite to the leachate. It was revealed that the bentomat and reactive mat installed in soil-bentonite layer effectively improved the permeability as well as purification of the leachate.

  • PDF

A TWO-DIMENSIONAL FINITE VOLUME METHOD FOR TRANSIENT SIMULATION OF TIME- AND SCALE-DEPENDENT TRANSPORT IN HETEROGENEOUS AQUIFER SYSTEMS

  • Liu, F.;Turner, I.;Ahn, V.;Su, N.
    • Journal of applied mathematics & informatics
    • /
    • v.11 no.1_2
    • /
    • pp.215-241
    • /
    • 2003
  • In this paper, solute transport in heterogeneous aquifers using a modified Fokker-Planck equation (MFPE) is investigated. This newly developed mathematical model is characterised with a time-, scale-dependent dispersivity. A two-dimensional finite volume quadrilateral mesh method (FVQMM) based on a quadrilateral background interpolation mesh is developed for analysing the model. The FVQMM transforms the coupled non-linear partial differential equations into a system of differential equations, which is solved using backward differentiation formulae of order one through five in order to advance the solution in time. Three examples are presented to demonstrate the model verification and utility. Henry's classic benchmark problem is used to show that the MFPE captures significant features of transport phenomena in heterogeneous porous media including enhanced transport of salt in the upper layer due to its parameters that represent the dependence of transport processes on scale and time. The time and scale effects are investigated. Numerical results are compared with published results on the some problems.

Numerical Study of Land/Channel Flow-field Optimization in Polymer Electrolyte Fuel Cells (PEFCs) (I) -The Effects of Land/Channel Flow-field on Current Density and HFR Distributions- (고분자전해질형연료전지의 가스 채널 최적화를 위한수치적연구(I) -가스 채널 치수가 전류밀도와 HFR 분포에 미치는영향성-)

  • Ju, Hyun-Chul
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.32 no.9
    • /
    • pp.683-694
    • /
    • 2008
  • The performance and durability of Polymer Electrolyte Fuel Cells (PEFCs) are strongly influenced by the uniformity of current density, temperature, species distributions inside a cell In order to obtain uniform distributions in them, the optimal design of flowfield must be a key factor. In this paper, the numerical study of land/channel flowfield optimizations is performed, using a multi-dimensional, multi-phase, non-isothermal PEFC model. Numerical simulations reveal more uniform current density and HFR(High Frequency Resistance) distributions and thus better PEFC performance with narrower land/channel width where the less severe oxygen depletion effect near the land region and more uniform contact resistance variation along the in-plane direction are achieved. The present study elucidates detailed effects of land/channel width and assist in identifying optimal flow-field design strategies for the operation of PEFCs.

Morphology and swelling property of chitosan microapsules and microbeads prepared by W/O emulsion (W/O 에멀젼에 의한 chitosan microcapsule 및 microbead의 morphology와 팽윤성)

  • 하병조;이옥섭
    • Journal of the Society of Cosmetic Scientists of Korea
    • /
    • v.21 no.2
    • /
    • pp.49-56
    • /
    • 1995
  • Chitosan microcapsules and microbeads were prepared by W/O emulsion method, and their morphologies were observed through SEM. The microcapsules have skin layer of 8 Um and 250 Um of mean diameter, The swelling test showed higher s welling ability in protic solvents than in aphotic solvents. After containing moth-yl violet in the microcapsules, the release patterns were investigated. The results sho wed that the addition of Iysozyme in pH 5.1 acetate buffer accelerated the re-lease rate. In case of the microbeads, the mean diameter was about 70 Um. The surface of the microbeads showed porous structures. The swelling ability of the beads revealed two times higher than the one of the microcapsules.

  • PDF

Pervaporation of TFEA/MA/Water Mixtures through PVA Composite Membranes

  • Ahn, Sang-Man;Kim, Jeong-Hoon;Lee, Yong-Taek;Lee, Soo-Bok
    • Proceedings of the Membrane Society of Korea Conference
    • /
    • 2005.11a
    • /
    • pp.133-147
    • /
    • 2005
  • In order to investigate applicability for 2,2,2-trifluoroethyl methacrylate (TFEMA) produced by esterification of 2,2,2-trifluoroethanol(TFEA) and methacrylic acid(MA) using pervaporation membrane, poly(vinyl alcohol) (PVA) composite membranes were prepared with glutaraldehyde(GA) onto porous polyethersulfone(PES) support. The degree of crosslinking and thickness of PVA coating layer were analyzed by swelling test and SEM(scanning electron microscopy), respectively. Pervaporation test was done with two feed mixures; TFEA/water, MA/water. The pervaporation data were obtained as a function of content of crosslinking agent, feed composition, and operating temperature, respectively. In case of TFEA-water(90/10 wt%) feed mixture at $80^{\circ}C$, the optimized membrane showed the high permeation flux of 1.5 $kg/m^2hr$ and separation factor of 320. In case of MA-water(90/10 wt%) feed mixture, the membranealso showed high permeation flux of 2.3 $kg/m^2hr$ and separation factor of 740 in same conditions.

  • PDF

Fabrication of Anodic Aluminum Oxide on Si and Sapphire Substrate (실리콘 및 사파이어 기판을 이용한 알루미늄의 양극산화 공정에 관한 연구)

  • Kim Munja;Lee Jin-Seung;Yoo Ji-Beom
    • Korean Journal of Materials Research
    • /
    • v.14 no.2
    • /
    • pp.133-140
    • /
    • 2004
  • We carried out anodic aluminum oxide (AAO) on a Si and a sapphire substrate. For anodic oxidation of Al two types of specimens prepared were Al(0.5 $\mu\textrm{m}$)!Si and Al(0.5 $\mu\textrm{m}$)/Ti(0.1 $\mu\textrm{m}$)$SiO_2$(0.1 $\mu\textrm{m}$)/GaN(2 $\mu\textrm{m}$)/Sapphire. Surface morphology of Al film was analyzed depending on the deposition methods such as sputtering, thermal evaporation, and electron beam evaporation. Without conventional electron lithography, we obtained ordered nano-pattern of porous alumina by in- situ process. Electropolishing of Al layer was carried out to improve the surface morphology and evaluated. Two step anodizing was adopted for ordered regular array of AAO formation. The applied electric voltage was 40 V and oxalic acid was used as an electrolyte. The reference electrode was graphite. Through the optimization of process parameters such as electrolyte concentration, temperature, and process time, a regular array of AAO was formed on Si and sapphire substrate. In case of Si substrate the diameter of pore and distance between pores was 50 and 100 nm, respectively. In case of sapphire substrate, the diameter of pore and distance between pores was 40 and 80 nm, respectively

Plasma-Sprayed $Al_{2}O_{3}-SiO_{2}$ Multi-Oxide Films on Stainless Steel Substrate

  • Korobova, N.;Soh, Deawha
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2000.11a
    • /
    • pp.116-119
    • /
    • 2000
  • The advantage of plasma-sprayed coating is their good resistance against thermal shock due to the porous state of the coated layer with a consequently low Youngs modules. However, the existence of many pores with a bimodal distribution and a laminar structure in the coating reduces coating strength and oxidation protection of the base metals. In order to counteract these problems, there have been many efforts to obtain dense coatings by spraying under low pressure or vacuum and by controlling particle size and morphology of the spraying materials. The aim of the present study is to survey the effects of the HIP treatment between 1100 and 130$0^{\circ}C$ on plasma-sprayed oxide coating of A1$_2$O$_3$, A1$_2$O$_3$-SiO$_2$ on the metal substrate (type C18N10T stainless steel). These effects were characterized by phase identification, Vickers hardness measurement, and tensile test before and after HIPing, These results show that high-pressure treatment has an advantage for improving adhesive strength and Vickers hardness of plasma- sprayed coatings.

  • PDF

A Infiltration Analysis in Unsaturated Porous Layer with Permeable Sidewalk Block (투수성 보도블록에서의 불포화 투수층 침투 해석)

  • Lee, Jae-Joon;Lee, Ye-Hee;Kwak, Chang-Jae
    • Proceedings of the Korea Water Resources Association Conference
    • /
    • 2012.05a
    • /
    • pp.905-905
    • /
    • 2012
  • 현재 도시유역의 홍수피해를 경감시키기 위한 방안으로 우수유출 저감시설에 대한 연구가 활발히 진행 중에 있다. 그러나 침투형 우수유출 저감시설의 경우 침투량 산정에 필요한 여러 인자 중 토성에 의해 저감 능력에 많은 차이를 보이고 있으며, 강우시 침투로 인한 토양내 함수비의 변화와 선행강우 조건 등에 의해 정량적인 분석이 어려워 활용도가 미흡한 실정이다. 따라서 본 연구에서는 2009년 국립방재연구원에서 시행한 침투실험 자료의 조건과 동일하게 투수계수 및 형상이 다른 두 종류의 투수성 보도블록 A, B와 토양내 선행강우의 유무에 대하여 표 1과 같이 검증 케이스로 구분하고, 4 가지의 강우강도로 모의 조건을 설정한 후 불포화 투수층의 침투해석을 실시하고 실험결과를 이용하여 모의결과에 대한 검증을 시행하였으며, 모의 결과의 검증을 뒷받침하기 위하여 통계적인 적합도를 나타내는 평균제곱오차(RMSE), 평균편차비율(PBIAS), 모형 효율성 계수(NSE), 지속성 모형효율성 계수(PME)을 산정해 보았다. 검증 결과 그림 1과 같이 투수성 보도블록 B의 형태가 투수성 보도블록 A의 형태보다 적합도가 높게 나타났고, 50mm/hr의 강우강도에서 변동성이 크게 나타났으나, 50mm/hr를 제외한 나머지 강우조건에서 양호한 적합도를 보였으며, 선행강우가 있는 조건이 선행강우가 없는 조건에 비해 높은 적합도를 나타내었다.

  • PDF

Enhancement of Condensation Heat Transfer of Anodized Aluminum by Teflon Coating and Oil-Impregnation (테플론 코팅과 오일 담지를 이용한 알루미늄 양극산화피막의 응축 열전달 향상)

  • Kang, Minjoo;Lee, Jonghoon;Cha, Soojin;Shin, Yeaji;Kim, Donghyun;Kim, Kyung-Ja;Lee, Junghoon
    • Journal of the Korean institute of surface engineering
    • /
    • v.54 no.2
    • /
    • pp.90-95
    • /
    • 2021
  • Surface modification technique enabling the control of condensation provides various benefit in various engineering systems, such as heat transfer, desalination, power plants, and so on. In this study, lubricant oil-impregnation into Teflon-coated nanoporous anodic oxide layer of aluminum to enhance a de-wetting and mobility of water droplet on surface. Due to the surface treatment improving water-repellency, the condensation mode is changed to dropwise, thus the frequency of sliding condensed water droplet on surface is increased. For these reasons, the surface of oil-impregnated Teflon-coated nanoporous anodic aluminum oxide shows significantly enhanced condensation heat transfer compared to bare aluminum surface. In addition, the porosity of anodic aluminum oxide affected the mobility of water droplet even with oil-impregnation and Teflon-coating, indicating that the optimization of porous structure of anodic oxide is required for maximizing the condensation heat transfer.