• Title/Summary/Keyword: Porous Layer

Search Result 754, Processing Time 0.024 seconds

A Study on the Manufacturing of Porous Membrane for Separation of Gas Mixture by Al Anodizing Method (Al장극산화법에 의한 반휴분이용 다공성 격영의 제조에 관한 연구)

  • 윤은열;라경용
    • Journal of the Korean institute of surface engineering
    • /
    • v.15 no.2
    • /
    • pp.69-76
    • /
    • 1982
  • With a view to manufacturing membranes for separation of gas mixtures, Al foils were anodized in a 2% oxalic-acid electrolyte at 40V and 80V. When anodizing was completed and Barrier layer existed at the extreme back site of the foil, the anodized foil was made to react with only electrolyte, with switching off the electric power. When the size and density of pores were changed through voltage change, the membr-anes did not show large difference in the permeability. Reacting with electrolyte, the existing Barrier layer turns into porous layer. During this process, several small pores grow from one relatively large pore, getting to the back site. The number and size of the small pores getting to the back surface increase as time passing. This change of Barrier layer into porous layer is thought to be directly related to the permeability change of the membranes. The selectivity of an anodized Al membrane was not related to the voltage change, and was high, being similar to the theoretical selctivity of metallic membranes, according to my observation.

  • PDF

Formation of Solution-derived Hydroxyapatite Layer on the Surface of a Shell (용액 반응에 의한 패각 표면의 수산화아파타이트 층 생성 거동)

  • Kim, Hui-Lae;Song, Tae-Woong
    • Journal of the Korean Ceramic Society
    • /
    • v.39 no.12
    • /
    • pp.1177-1182
    • /
    • 2002
  • Highly surfaced and porous hydroxyapatite body was artificially formed on the surface of a shell through a reaction with phosphatic solutions. As a result of qualitative observation, hydroxyapatite seemed to be crystallized by solution-precipitation process accelerated by the nucleation surface of a shell. The process of formation of hydroxyapatite layer was as follows. 1. Dense nucleation and growth on the surface of solid phase 2. Formation of microporous layer by contact and entanglement between crystallines 3. diffusion of solution through the porous layer and thickness growth of layer towards inside

A Study on Characteristics of Light Emitting Diode with Porous Silicon (다공성 실리콘을 이용한 LED의 발광 특성에 관한 연구)

  • Lee Sung-Hoon;Lee Chi-Woo
    • Journal of the Korean Electrochemical Society
    • /
    • v.3 no.1
    • /
    • pp.39-43
    • /
    • 2000
  • The light emitting diode (LED) was fabricated from n-type porous silicon. We investigated both the current-voltage characteristics of the LED with various electrode materials and changes of electroluminescence with applied current density. Also we probed changes in electroluminescence as a function of operation time at a given current. In order to Improve the contact area between the electrode material and porous silicon layer, we deposited indium on porous silicon layer by electroplating and investigated the electric characteristics of the LED and changes of electroluminescence.

Enhanced Photoelectrochemical Behavior of Gold-coated Porous n-Si Electrochemically Modified with Polyaniline

  • Park, Soo-Jin;Chae, Won-Seok;Kim, Kang-Jin
    • Analytical Science and Technology
    • /
    • v.8 no.4
    • /
    • pp.637-642
    • /
    • 1995
  • The presence of a porous Si layer(PSL) formed on the surface of crystalline silicon by electrochemical etclling in HF solution is found to enhance the stability of n-Si photoanodes, but porous n-Si thus formed is still liable to corrode upon exposure to excitation light. To improve the stability of the porous n-Si electrodes and to reduce the photo-induced corrosion, we have examined the PEC behavior of porous n-Si modified with polyaniline(PANI) and 3 nm thick layer of Au. Comparisons were made between Au/PSL and PANl/Au/PSL photoelectrodes.

  • PDF

Activated Carbons as Electrode Materials in Electric Double-Layer Capacitors I. Electrochemical Properties of Activated Carbons in Relation to their Porous Structures and Surface Oxygen Functional Groups

  • Kim, Chang-Hee;Pyun, Su-Il
    • Journal of the Korean Ceramic Society
    • /
    • v.40 no.9
    • /
    • pp.819-826
    • /
    • 2003
  • This article is concerned with the overview of activated carbons as electrode materials in electric double-layer capacitors. Firstly, this article introduced various types of activated carbons with their precursors and manufacturing conditions which can be divided into two main steps of the carbonization and activation processes. Secondly, the present article gave the detailed discussion about the porous structures and examined previous works on the electrochemical behaviors of activated carbons in relation to their porous structures, along with our recent works. Finally, this article characterized the surface oxygen functional groups and presented their influence on the electrochemical properties of activated carbons by reviewing our recent results.

Numerical Simulation of Overtopping of Cnoidal Waves on a Porous Breakwater Using the Boussinesq Equations: Comparison with Solutions of the Navier-Stokes Equations (Boussinesq 식을 사용하여 Cnoid 파의 투수방파제 월파 해석: Navier-Stokes 식 결과와 비교)

  • Huynh, Thanh Thu;Lee, Changhoon;Ahn, Suk Jin
    • Journal of Korean Society of Coastal and Ocean Engineers
    • /
    • v.31 no.2
    • /
    • pp.41-49
    • /
    • 2019
  • We approximately obtain heights of cnoidal waves overtopping on a porous breakwater using both the one-layer Boussinesq equations (Vu et al., 2018) and the two-layer Boussinesq equations (Huynh et al., 2017). For cnoidal waves overtopping on a porous breakwater, we find through numerical experiments that the heights of cnoidal waves overtopping on a low-crested breakwater (obtained by the Navier-Stokes equations) are smaller than the heights of waves passing through a high-crested breakwater (obtained by the one-layer Boussinesq equations) and larger than the heights of waves passing through a submerged breakwater (obtained by the two-layer Boussinesq equations). As the cnoidal wave nonlinearity becomes smaller or the porous breakwater width becomes narrower, the heights of transmitting waves obtained by the one-layer and two-layer Boussinesq equations become closer to the height of overtopping waves obtained by the Navier-Stokes equations.

Sensing Properties of Porous Silicon Layer for Organic Vapors (다공질 실리콘의 유기가스 검지 특성)

  • 김성진;이상훈;최복길
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.15 no.11
    • /
    • pp.963-968
    • /
    • 2002
  • In this work, porous silicon (PS) layer is investigated as a sensing material to detect organic vapors such as ethanol (called alcohol), methanol, and acetone in low concentrations. To do this, PS sensors were fabricated. They have a membrane structure and comb-type electrodes were used to detect the change of electrical resistance effectively. PS layer on Si substrates was formed by anodization in HF solution of 25%. From fabricated sensors, current-voltage (Ⅰ-Ⅴ) curves were measured for gases evaporated from 0.1 to 0.5% organic solution concentrations at 36$\^{C}$. As the result, all curves showed rectifying behavior due to a diode structure between Si and the PS layer. The conductance of most sensors increased largely at high voltage of 5V, but the built-in potential on the measured Ⅰ-Ⅴ curve was lowered inversely by the adsorption effect of the organic vapors with high dipole moment.

CONVECTION IN A HORIZONTAL POROUS LAYER UNDERLYING A FLUID LAYER IN THE PRESENCE OF NON LINEAR MAGNETIC FIELD ON BOTH LAYERS

  • Bukhari, Abdul-Fattah K.;Abdullah, Abdullah A.
    • Journal of the Korean Society for Industrial and Applied Mathematics
    • /
    • v.11 no.1
    • /
    • pp.1-11
    • /
    • 2007
  • A linear stability analysis applied to a system consist of a horizontal fluid layer overlying a layer of a porous medium affected by a vertical magnetic field on both layers. Flow in porous medium is assumed to be governed by Darcy's law. The Beavers-Joseph condition is applied at the interface between the two layers. Numerical solutions are obtained for stationary convection case using the method of expansion of Chebyshev polynomials. It is found that the spectral method has a strong ability to solve the multilayered problem and that the magnetic field has a strong effect in his model.

  • PDF

Shear wave in a fiber-reinforced anisotropic layer overlying a pre-stressed porous half space with self-weight

  • Kakar, Rajneesh;Kakar, Shikha
    • Smart Structures and Systems
    • /
    • v.18 no.5
    • /
    • pp.911-930
    • /
    • 2016
  • The main purpose of this paper is to study the effects of initial stress, gravity, anisotropy and porosity on the propagation of shear wave (SH-waves) in a fiber-reinforced layer placed over a porous media. The frequency equations in a closed form have been derived for SH-waves by applying suitable boundary conditions. The frequency equations have been expanded and approximated up to $2^{nd}$ order of Whittaker's function. It has been observed that the SH-wave velocity decreases as width of fiber-reinforced layer increases. However, with the increase of initial stress, gravity parameter and porosity, the phase velocity increases. The results obtained are in perfect agreement with the standard results investigated by other relevant researchers.

Formation and Chemical Dissolution Behaviors of Nano Porous Alumina (나노 기공성 알루미나의 생성과 화학적 용해 거동)

  • Oh, Han-Jun;Jeong, Yong-Soo;Chi, Choong-Soo
    • Journal of the Korean institute of surface engineering
    • /
    • v.43 no.5
    • /
    • pp.217-223
    • /
    • 2010
  • For an application as templates of high performance with proper pore size and shape, porous anodic alumina films were prepared by anodization in oxalic acid, and formation behaviors of anodic alumina layer as well as dissolution process in acid solution have been investigated. The surface characteristics on anodic alumina layer were shown to be dependent on the fabrication parameters for anodization. For the dissolution behaviors of anodic alumina, the thickness of the barrier-type alumina layer decreased linearly with the rate of 0.98 nm/min in $H_3PO_4$ solution at $30^{\circ}C$. The changes of the anodic alumina layers were analyzed by SEM and TEM.