• Journal of Powder Materials
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• v.22 no.1
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• pp.15-20
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• 2015

The composite of porous silicon (Si) and amorphous carbon (C) is prepared by pyrolysis of a nano-porous Si + pitch mixture. The nano-porous Si is prepared by mechanical milling of magnesium powder with silicon monoxide (SiO) followed by removal of MgO with hydrochloric acid (etching process). The Brunauer-Emmett-Teller (BET) surface area of porous Si ($64.52m^2g^{-1}$) is much higher than that before etching Si/MgO ($4.28m^2g^{-1}$) which indicates pores are formed in Si after the etching process. Cycling stability is examined for the nano-porous Si + C composite and the result is compared with the composite of nonporous Si + C. The capacity retention of the former composite is 59.6% after 50 charge/discharge cycles while the latter shows only 28.0%. The pores of Si formed after the etching process is believed to accommodate large volumetric change of Si during charging and discharging process.

• Korean Journal of Materials Research
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• v.22 no.3
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• pp.118-122
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• 2012

We synthesized porous $Co_3O_4/RuO_2$ composite using the soft template method. Cetyl trimethyl ammonium bromide (CTAB) was used to make micell as a cation surfactant. The precipitation of cobalt ion and ruthenium ion for making porosity in particles was induced by $OH^-$ ion. The porous $Co_3O_4/RuO_2$ composite was completely synthesiszed after anealing until $250^{\circ}C$ at $3^{\circ}C$/min. From the XRD ananysis, we were able to determine that the porous $Co_3O_4$/RuO2 composite was comprised of nanoparticles with low crystallinity. The shape or structure of the porous $Co_3O_4/RuO_2$ composite was studied by FE-SEM and FE-TEM. The size of the porous $Co_3O_4/RuO_2$ composite was 20~40 nm. From the FE-TEM, we were able to determine that porous cavities were formed in the composite particles. The electrochemical performance of the porous $Co_3O_4/RuO_2$ composite was measured by CV and charge-discharge methods. The specific capacitances, determined through cyclic voltammetry (CV) measurement, were ~51, ~47, ~42, and ~33 F/g at 5, 10, 20, and 50 mV/sec scan rates, respectively. The specific capacitance through charge-discharge measurement was ~63 F/g in the range of 0.0~1.0 V cutoff voltage and 50 mAh/g current density.

• Journal of the Korean Ceramic Society
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• v.43 no.8 s.291
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• pp.509-514
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• 2006

In this study, chopped Hi-Nicalon SiC fiber Reinforced Porous Reaction Bonded SiC (RBSC) composites and it fabrication process were developed by using Si melt infiltration process. The porosity and average pore size in fabricated chopped SiC fiber reinforced porous RBSC composites were in the range of $30{\sim}40%$ and $40-90{\mu}m$, which mainly determined by the SiC powder size used as starting material and amount of residual Si in porous composites. The maximum flexural strength of chopped SiC fiber reinforced porous RBSC composite was as high as 80 MPa. The delayed fracture behavior was observed in chopped SiC fiber reinforced porous RBSC composites upon 3-point bending strength test.

• Journal of Integrative Natural Science
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• v.6 no.4
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• pp.244-250
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• 2013

Three types of functionalized flexible optical composite films based on Bragg structure porous silicon interferometer have been successfully fabricated by casting a toluene solution of polystyrene onto the free-standing porous silicon. The optical properties of composite films are measured. Surface functionalization of porous silicon is determined by FT-IR measurement. Reflectance and transparence properties of composite films are measured for the possible application of tunable optical filter and indicate that the transmission peak occurred at the identical location where the reflection peak appeared.

• KIEAE Journal
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• v.1 no.2
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• pp.47-54
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• 2001

Single sound absorbers such as porous materials, panels, and Helmholts resonators have limited performance with some extents of frequency region. For example, porous materials do not attenuate low frequency sounds, while panels do not absorb high frequency sounds. Composite absorption structure with coverings, porous materials, and air gaps are an alternative for wide band sound absorption. Slits, panels, perforated panels are those materials for coverings, glass wool, mineral wool, polyester, and polyurethane are frequently used porous materials. Air gap between the porous material and background surface is one of major factors which governs the absorption characteristics of composite absorption structures, especially in the low frequency area. Calculations and measurements show that the absorption coefficients of composite absorption structure, in mid and low frequency bands, are getting higher with increased air gaps. Perforated panels rather than slits and panels are good coverings with higher number as far as absorption coefficient is concerned. Perforated panels with porous materials and 37 cm of air gaps in background have high absorption coefficients for all frequency bands, above 0.7 to 1.0. All measurements are performed in reverberation chamber, Mokpo National University, according to ISO 354 and ISO 3382.

• Steel and Composite Structures
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• v.35 no.5
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• pp.659-670
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• 2020

This paper proposes the use of a porous core between layers of laminated composite plates to examine its effect on the natural frequencies of the resulted porous laminated composite sandwich plate (PLCSP) resting on a two-parameter elastic foundation. Moreover, it has been suggested that the dispersion of porosity has two different functionally graded (FG) patterns which are compared with a uniformly dispersed (UD) profile to find their best vibrational efficiency in the proposed PLCSPs. In FG patterns, two types of dispersions, including symmetric (FG-S) and asymmetric (FG-A) patterns have been considered. To derive the governing Eigen value equation of such structures, the first order shear deformation theory (FSDT) of plates has been employed. Accordingly, a finite element method (FEM) is developed to solve the derived Eigen value equation. Using the mentioned theory and method, the effects of porosity parameters, fiber orientation of laminated composite, geometrical dimensions, boundary conditions and elastic foundation on the natural frequencies of the proposed PLCSPs have been studied. It is observed that embedding porosity in core layer leads to a significant improvement in the natural frequencies of PLCSPs. Moreover, the natural frequencies of PLCSPs with FG porous core are higher than those with UD porous core.

• Journal of Integrative Natural Science
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• v.6 no.3
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• pp.183-186
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• 2013

Well defined 1-dimentional (1-D) photonic crystals of polystyrene replicas have been successfully obtained by removing the porous silicon from the free-standing rugate porous silicon/phenylmethylpolysiloxane composite film. Rugate porous silicon was prepared by an electrochemical etching of silicon wafer in HF/ethanol mixture solution. Exfoliated rugate porous silicon was obtained by an electropolishing condition. A composite of rugate porous silicon/phenylmethylpolysiloxane composite film was prepared by casting a toluene solution of phenylmethylpolysiloxane onto the top of rugate porous silicon film. After the removal of the template by chemical dissolution, the phenylmethylpolysiloxane castings replicate the photonic features and the nanostructure of the master. The photonic phenylmethylpolysiloxane replicas are robust and flexible in ambient condition and exhibit an excellent reflectivity in their reflective spectra. The photonic band gaps of replicas are narrower than that of typical semiconductor quantum dots.

• Advanced Composite Materials
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• v.18 no.1
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• pp.61-75
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• 2009

The effect of porous matrix on thermal fatigue behavior of 3D-orthogonally woven SiC/SiC composite was evaluated in comparison with that having relatively dense matrix. The porous matrix yields open air passages through its thickness which can be utilized for transpiration cooling. On the other hand, the latter matrix is so dense that the air passages are sealed. A quantity of the matrix was varied by changing the number of repetition cycles of the polymer impregnation pyrolysis (PIP). Strength degradation of composites under thermal cycling conditions was evaluated by the $1200^{\circ}C$/RT thermal cycles with a combination of burner heating and air cooling for 200 cycles. It was found that the SiC/SiC composite with the porous matrix revealed little degradation in strength during the thermal cycles, while the other sample showed a 25% decrease in strength. Finally it was demonstrated that the porous structure in 3D-SiC/SiC composite improved the thermal fatigue durability.

• Journal of Mechanical Science and Technology
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• v.19 no.11
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• pp.2025-2031
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• 2005

Eshelby type micro mechanics model with a newly developed piezoelectric Eshelby tensor is proposed for predicting the effective electroelastic properties of the piezoelectric composite. The model is applied for piezoelectric solids containing both porosities and metal inhomogeneities. The effective electroelastic moduli of the composites such as stiffness, piezoelectric constants, and dielectric constants are predicted by the present model, which are extensively compared with the existing experimental results from the literatures. The validity of Eshelby type model for predicting the effective properties of the composite is thoroughly examined. It can be concluded from this study that a new mechanism is needed to compute correctly the dielectric constants among the effective properties of the composites.

• Structural Engineering and Mechanics
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• v.72 no.6
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• pp.763-774
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• 2019

The main aim of this paper is enhancing design of traditional laminated composite plates subjected to static loads. In this regard, this paper suggests embedding a lightweight porous layer in the middle of laminated composite as the core layer of the resulted sandwich plate. The static responses of the suggested structures with uniform, symmetric and non-symmetric porosity distributions are compared to optimize their design. Using the first order shear deformation theories, the static governing equations of the suggested laminated composite plates with a porous layer (LCPPL) rested on two-parameter foundation are obtained. A finite element method is also utilized to solve the governing equations of LCPPLs. Effects of laminated composite and porosity characteristics as well as geometry dimension, edges' boundary conditions and foundation coefficients on the static deflection and stress distribution of the suggested composite plates have been investigated. The results reveal that the use of core between the layers of laminated composites leads to a sharp reduction in the static deflections of LCPPLs. Furthermore, in compare with perfect cores, the use of porous core between the layers of laminated composite plates can offer a considerable reduction in structural weight without a significant difference in their static responses.