• 제목/요약/키워드: Porosity improvement

검색결과 172건 처리시간 0.023초

Preparation and Performance of Aluminosilicate Fibrous Porous Ceramics Via Vacuum Suction Filtration

  • Qingqing Wang;Shaofeng Zhu;Zhenfan Chen;Tong Zhang
    • 한국재료학회지
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    • 제34권1호
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    • pp.12-20
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    • 2024
  • This study successfully prepared high-porosity aluminosilicate fibrous porous ceramics through vacuum suction filtration using aluminosilicate fiber as the primary raw material and glass powder as binder, with the appropriate incorporation of glass fiber. The effects of the composition of raw materials and sintering process on the structure and properties of the material were studied. The results show that when the content of glass powder reached 20 wt% and the samples were sintered at the temperature of 1,000 ℃, strong bonds were formed between the binder phase and fibers, resulting in a compressive strength of 0.63 MPa. When the sintering temperatures were increased from 1,000 ℃ to 1,200, the open porosity of the samples decreased from 89.08 % to 82.38 %, while the linear shrinkage increased from 1.13 % to 10.17 %. Meanwhile, during the sintering process, a large amount of cristobalite and mullite were precipitated from the aluminosilicate fibers, which reduced the performance of the aluminosilicate fibers and hindered the comprehensive improvement in sample performance. Based on these conditions, after adding 30 wt% glass fiber and being sintered at 1,000 ℃, the sample exhibited higher compressive strength (1.34 MPa), higher open porosity (89.13 %), and lower linear shrinkage (5.26 %). The aluminosilicate fibrous porous ceramic samples exhibited excellent permeability performance due to their high porosity and interconnected three-dimensional pore structures. When the samples were filtered at a flow rate of 150 mL/min, the measured pressure drop and permeability were 0.56 KPa and 0.77 × 10-6 m2 respectively.

목질폐잔재 탄화물의 토양개량 효과(2) (Effect of Carbonized Wastewoods on Soil Improvement(2))

  • 신창섭;김병로
    • Journal of the Korean Wood Science and Technology
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    • 제34권6호
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    • pp.21-28
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    • 2006
  • 본 연구는 목탄의 모양과 탄화된 수종의 종류에 따른 토양개량 효과를 시험하기 위해 수행되었다. 결과에 따르면 서양측백과 칠엽수 묘목 모두 무처리 토양에서보다 목탄 처리 토양에서 더 잘 자랐다. 분말탄의 경우, 서양측백나무 묘목 생장은 잣나무 목탄으로 처리된 토양에서 가장 좋았으며 낙엽송, 파티클보드, 상수리나무 목탄 순으로 컸다. 입상탄의 경우 묘목 생장은 낙엽송, 파티클보드, 잣나무 목탄의 순으로 컸다. 또한 토양공극과 유기물 함량도 무처리 토양에서보다 목탄 처리 토양에서 더 큰 것으로 분석되었다. 목탄 처리 토양에서 묘목생장이 더 좋았던 것은 근계에서의 통기성과 유기물 흡착이 증가되었기 때문인 것으로 추정된다.

토양개량제 혼합비율이 Green Topsoil의 물리 화학성에 미치는 영향 (Effects of Source and Mixing Ratio of Topsoil onPhysicoChemical Properties of Green)

  • 박찬무;한동식;황규석;이용범
    • 아시안잔디학회지
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    • 제5권2호
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    • pp.59-68
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    • 1991
  • This experiment was carried out to investigate the mixing ratio of soil amending materials such as peat perlite, active carbon and zeolite for improvements of physiochemical properties of topsoil, of creeping bentgrass (Agrostis palustris var. Penncross). The results were as followed :1.Appropriate addition of soil improvement material was increased the soil porosity due to the decrease of bulk density. Over supplement of soil improvement material induced the decrease of infiltration of water into soil.2Content of organic matter was increased in treatment of peat and active carbon . Soil reaction was decreased in peat treatment, but increased in perlite, zeolite and active carbon. Exchangeable cation capacity was increased by the addition of all kinds of soil improvement materials used in this experiment.

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Influence of kneading ratio on the binding interaction of coke aggregates on manufacturing a carbon block

  • Kim, Jong Gu;Kim, Ji Hong;Bai, Byong Chol;Choi, Yun Jeong;Im, Ji Sun;Bae, Tae-Sung;Lee, Young-Seak
    • Carbon letters
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    • 제28권
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    • pp.24-30
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    • 2018
  • Coke aggregates and carbon artifacts were produced to investigate the interactions of coke and pitch during the kneading process. In addition, the kneading ratio of the coke and binder pitch for the coke aggregates was controlled to identify the formation of voids and pores during carbonization at $900^{\circ}C$. Experiments and thermogravimetric analysis revealed that carbon yields were improved over the theoretical yield calculated by the weight loss of the coke and binder pitch; the improvement was due to the binding interactions between the coke particles and binder pitch by the kneading process. The true, apparent, and bulk densities fluctuated according to the kneading ratio. This study confirmed that an excessive or insufficient kneading ratio decreases the density with degradation of the packing characteristics. The porosity analysis indicated that formation of voids and pores by the binder pitch increased the porosity after carbonization. Image analysis confirmed that the kneading ratio affected the formation of the coke domains and the voids and pores, which revealed the relations among the carbon yields, density, and porosity.

고로슬래그 미분말 콘크리트의 분말도 및 치환율에 따른 염해 저항성 평가 (Evaluation of Chloride Penetration in Concrete with Ground Granulated Blast Furnace Slag considering Fineness and Replacement Ratio)

  • 이현호;권성준
    • 한국건설순환자원학회논문집
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    • 제1권1호
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    • pp.26-34
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    • 2013
  • RC 구조물의 내구성능 피복두께의 변화뿐 아니라 배합조건에 따라 크게 변화한다. 고로슬래그 미분말은 유용한 혼화재료이며, 최근들어 염해에 대한 저항성을 확보하기 위해 많이 사용되고 있다. 본 연구는 고로슬래그 미분말을 30~70%로, 분말도를 $4,000{\sim}8,000cm^2/g$으로 변화시키면서 공극률, 압축강도, 확산계수의 변화를 분석하였다. 실험결과 고로슬래그 미분말을 혼입한 콘크리트는 보통 콘크리트에 비하여 조밀한 공극구조, 높은 강도발현과 확산계수 감소를 확보하였으며, 분말도보다 치환율에 더욱 민감하게 변화하였다. 고로슬래그 미분말 콘크리트에서 재령이 3일에서 91일로 증가함에 따라 공극률은 77.47% 수준으로 감소하였으며, 압축강도는 373%로 증가하였다. 또한 염화물 확산계수는 OPC 콘크리트의 64.4% 수준으로 감소하여 내구적 저항성이 크게 개선됨을 알 수 있었다.

Optimization of nutrients requirements for bioremediation of spent-engine oil contaminated soils

  • Ogbeh, Gabriel O.;Tsokar, Titus O.;Salifu, Emmanuel
    • Environmental Engineering Research
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    • 제24권3호
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    • pp.484-494
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    • 2019
  • This paper presents a preliminary investigation of the optimum nutrients combination required for bioremediation of spent-engine oil contaminated soil using Box-Behnken-Design. Three levels of cow-manure, poultry-manure and inorganic nitrogen-phosphorus-potassium (NPK) fertilizer were used as independent biostimulants variables; while reduction in total petroleum hydrocarbon (TPH) and total soil porosity (TSP) response as dependent variables were monitored under 6-week incubation. Ex-situ data generated in assessing the degree of biodegradation in the soil were used to develop second-order quadratic regression models for both TPH and TSP. The two models were found to be highly significant and good predictors of the response fate of TPH-removal and TSP-improvement, as indicated by their coefficients of determination: $R^2=0.9982$ and $R^2=1.000$ at $p{\leq}0.05$, respectively. Validation of the models showed that there was no significant difference between the predicted and observed values of TPH-removal and TSP-improvement. Using numerical technique, the optimum values of the biostimulants required to achieve a predicted maximum TPH-removal and TSP-improvement of 67.20 and 53.42%-dry-weight per kg of the contaminated soil were as follows: cow-manure - 125.0 g, poultry-manure - 100.0 g and NPK-fertilizer - 10.5 g. The observed values at this optimum point were 66.92 and 52.65%-dry-weight as TPH-removal and TSP-improvement, respectively.

단결정 YBCO 벌크 초전도체 제조에 대한 액상침투법과 고전적 용융공정의 비교연구 (Comparative Study on the Fabrication of Single Grain YBCO Bulk Superconductors using Liquid Infiltration and Conventional Melt Growth Processes)

  • 아시프 마흐무드;전병혁;김찬중
    • Progress in Superconductivity
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    • 제11권1호
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    • pp.42-46
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    • 2009
  • With an aim of comparison, single grain Y-Ba-Cu-O (YBCO) bulk superconductors were fabricated using a liquid infiltration growth (LIG) process and a conventional melt growth (MTG) process with top seeding. The MTG process uses an $YBa_2Cu_3O_{7-x}$(Y123) powder as a precursor, while the LIG process uses $Y_2BaCuO_5(Y211)/Ba_3Cu_5O_8(Y035)$ pre-forms. The growth of a single Y123 domain on the top seed was successful in the both processes. Different feature between the two processes is the interior microstructure regarding the critical current density ($J_c$). The LIG-processed YBCO sample showed a lower porosity, more uniform distribution of Y211 particles and the enhanced Y211 refinement compared to the conventional MTG process. The $J_c$ improvement in the LIG process is attributed to the dispersion of finer Y211 particles as well as lower porosity within the Y123 superconducting matrix.

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염료감응형 태양전지 $TiO_{2}$ 광전극 표면의 초음파 열처리에 관한 연구 (A study of DSC using Ultrasonic and Thermal treatment on nano-crystalline $TiO_{2}$ surface)

  • 홍지태;최진영;서현웅;김종락;김희제
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2007년도 춘계학술대회
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    • pp.317-319
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    • 2007
  • Recently, there were many researches for efficiency improvement of DSC. Among of these works, research of surface treatment is still a prerequisite for electron diffusion, light-harvesting and surface state of $DSC^{4)}$. Using of the surface treatment, it can be raise up porosity of $TiO_{2}$ nano-crystalline structure on $photo-electrode^{5)}$. There are chemical, physical, electrical and optical methods which raise up its porosity. In this paper, we have designed and manufactured MOPA-type ultrasonic circuit (100W, frequency and duty variable). Manufactured ultrasonic circuit to use to force cavity density and power into $TiO_{2}$ paste. Then, we have optimized forcing time, frequency and duty of ultrasonic irradiation for surface treatment of photo-electrode of DSC. In I-V characteristic test of DSC, ultrasonic and thermal treated DSC shows 19% improved its efficiency against established DSC.

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Development of Macro-Porous Silicon Based Dye-Sensitized Solar Cells with Improved Light Trapping

  • Aliaghayee, Mehdi;Fard, Hassan Ghafoori;Zandi, Ashkan
    • Journal of Electrochemical Science and Technology
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    • 제7권3호
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    • pp.218-227
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    • 2016
  • The light harvesting efficiency is counted as an important factor in the power conversion efficiency of DSSCs. There are two measures to improve this parameter, including enhancing the dye-loading capacity and increasing the light trapping in the photoanode structure. In this paper, these tasks are addressed by introducing a macro-porous silicon (PSi) substrate as photoanode. The effects of the novel photoanode structure on the DSSC performance have been investigated by using energy dispersive X-ray spectroscopy, photocurrent-voltage, UV-visible spectroscopy, reflectance spectroscopy, and electrochemical impedance spectroscopy measurements. The results indicated that bigger porosity percentage of the PSi structure improved the both anti-reflective/light-trapping and dye-loading capacity properties. PSi based DSSCs own higher power conversion efficiency due to its remarkable higher photocurrent, open circuit voltage, and fill factor. Percent porosity of 64%, PSi(III), resulted in nearly 50 percent increment in power conversion efficiency compared with conventional DSSC. This paper showed that PSi can be a good candidate for the improvement of light harvesting efficiency in DSSCs. Furthermore, this study can be considered a valuable reference for more investigations in the design of multifunctional devices which will profit from integrated on-chip solar power.

Preparation of Yba2Cu3Ox Superconductor Prepared with Additives of PbO and Ag2O

  • Chu, Soon-Nam;Park, Jung-Cheul;Jeon, Yong-Woo
    • Transactions on Electrical and Electronic Materials
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    • 제10권1호
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    • pp.31-34
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    • 2009
  • The improvement of preparation process of ${YBa_2}{Cu_3}{O_x}$ superconductor and its conducting properties is important for practical applications. In this study, the additives such as $Ag_{2}O$ and PbO were used to improve the preparation conditions of ${YBa_2}{Cu_3}{O_x}$ superconducting bulk samples and the properties of ${YBa_2}{Cu_3}{O_x}$ superconductors prepared with powders using sol-gel method and solid state reaction method were studied. The effects of the different powders and the additives to the density, grain alignment, and porosity of samples, that affect the critical current density of superconductor, also have been investigated. It is found that the properties of ${YBa_2}{Cu_3}{O_x}$ prepared with sol-gel synthesized powder and the additives showed better superconductivities than those of conventionally prepared superconductors.