• 제목/요약/키워드: Pores

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고분자전해질형 연료전지의 공기 채널 내에서의 액적 거동에 대한 수치적 연구 (Numerical Study of Droplet Dynamics in a PEMFC Air Flow Channel)

  • 최지영;손기헌
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2008년도 추계학술대회B
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    • pp.2390-2395
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    • 2008
  • The water droplet motion in an air flow microchannel with pores through which water emerges is studied numerically by solving the equations governing the conservation of mass and momentum. The gas-liquid interface is tracked by a level set method which is based on a sharp-interface representation for accurately imposing the matching conditions at the interface and is modified to implement the contact angle conditions on the wall and pores. The numerical results show that the droplet growth and detachment pattern depend significantly on the contact angle and inlet air velocity. Also, the dynamic interaction between the droplets growing on multiple pores is investigated. The pore arrangement subject to droplet merging is found to be not effective for water removal.

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한국산 곰치과 어류 1 미기록종, Strophidon sathete (First Record of the Slender Giant Moray, Strophidon sathete (Muraenidae, Anguilliformes) from Korea)

  • 김병엽;고수진;김맹진;송춘복
    • 한국어류학회지
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    • 제32권1호
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    • pp.21-25
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    • 2020
  • 곰치과에 속하는 Strophidon sathete 1개체(전장 1,302 mm)가 2019년 4월 제주도 남방 해역에서 외끌이 기선저인망으로 처음 채집되었다. 이 종의 특징은 무늬가 없고, 몸이 가늘며, 주둥이 약간 둥근 형태를 띠며, 3개의 안상골공(superorbital pores), 4개의 안하골공(infraobital pores), 그리고 6개의 하악골공(mandibular pores)을 갖는다. 형태적으로 가지굴(Gymnothorax albimarginatus)과 유사하지만 등지느러미와 뒷지느러미가 전체적으로 어둡고(vs. 말단에 하얀색을 띰), 전장에 대해 체고비율이 1.8~3.1% (vs. 3.2~5.7%), 그리고 전장이 50~70 cm보다 작을 때 반문이 없는 것(vs. 반문이 있음)으로 구분할 수 있다. 따라서 몸의 굵기가 유사종에 비해 상대적으로 가는 형태적 특징에 근거해서 이 미기록종의 국명을 "가는곰치"로 제안한다.

MoO3/camphene 슬러리의 동결건조 및 수소환원에 의한 Mo 다공체 제조 (Fabrication of Porous Mo by Freeze-Drying and Hydrogen Reduction of MoO3/Camphene Slurry)

  • 이원석;오승탁
    • 한국분말재료학회지
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    • 제19권6호
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    • pp.446-450
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    • 2012
  • In order to fabricate the porous Mo with controlled pore characteristics, unique processing by using $MoO_3$ powder as the source and camphene as the sublimable material is introduced. Camphene-based 15 vol% $MoO_3$ slurries, prepared by milling at $50^{\circ}C$ with a small amount of dispersant, were frozen at $-25^{\circ}C$. Pores were generated subsequently by sublimation of the camphene during drying in air for 48 h. The green body was hydrogen-reduced at $750^{\circ}C$, and sintered at $1000-1100^{\circ}C$ for 1 h. After heat treatment in hydrogen atmosphere, $MoO_3$ powders were completely converted to metallic W without any reaction phases. The sintered samples showed large pores with the size of about $150{\mu}m$ which were aligned parallel to the camphene growth direction. Also, the internal wall of large pores and near bottom part of specimen had relatively small pores due to the difference in the camphene growth rate during freezing process. The size of small pores was decreased with increase in sintering temperature, while that of large pores was unchanged. The results are strongly suggested that the porous metal with required pore characteristics can be successfully fabricated by freeze-drying process using metal oxide powders.

구형 PMMA와 WO3 분말이 혼합된 Camphene 슬러리의 동결건조에 의한 W 다공체 제조 (Fabrication of Porous W by Freeze-Drying Process of Camphene Slurries with Spherical PMMA and WO3 Powders)

  • 이한얼;전기철;김영도;석명진;오승탁
    • 한국재료학회지
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    • 제25권11호
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    • pp.602-606
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    • 2015
  • Porous W with spherical and directionally aligned pores was fabricated by the combination of sacrificial fugitives and a freeze-drying process. Camphene slurries with powder mixtures of $WO_3$ and spherical PMMA of 20 vol% were frozen at $-25^{\circ}C$ and dried for the sublimation of the camphene. The green bodies were heat-treated at $400^{\circ}C$ for 2 h to decompose the PMMA; then, sintering was carried out at $1200^{\circ}C$ in a hydrogen atmosphere for 2 h. TGA and XRD analysis showed that the PMMA decomposed at about $400^{\circ}C$, and $WO_3$ was reduced to metallic W at $800^{\circ}C$ without any reaction phases. The sintered bodies with $WO_3$-PMMA contents of 15 and 20 vol% showed large pores with aligned direction and small pores in the internal walls of the large pores. The pore formation was discussed in terms of the solidication behavior of liquid camphene with solid particles. Spherical pores, formed by decomposition of PMMA, were observed in the sintered specimens. Also, microstructural observation revealed that struts between the small pores consisted of very fine particles with size of about 300 nm.

나노크기 Cu 분산입자를 갖는 Al2O3 다공체의 제조 및 미세조직 특성 (Synthesis and Microstructure of Porous Al2O3 with Nano-Sized Cu Dispersions)

  • 유호석;김안기;현창용
    • 한국재료학회지
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    • 제23권1호
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    • pp.67-71
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    • 2013
  • Porous $Al_2O_3$ dispersed with nano-sized Cu was fabricated by freeze-drying process and solution chemistry method using Cu-nitrate. To prepare porous $Al_2O_3$, camphene was used as the sublimable vehicle. Camphene slurries with $Al_2O_3$ content of 10 vol% were prepared by milling at $50^{\circ}C$ with a small amount of oligomeric polyester dispersant. Freezing of the slurry was done in a Teflon cylinder attached to a copper bottom plate cooled to $-25^{\circ}C$ while unidirectionally controlling the growth direction of the camphene. Pores were subsequently generated by sublimation of the camphene during drying in air for 48 h. The green body was sintered in a furnace at $1400^{\circ}C$ for 1 h. Cu particles were dispersed in porous $Al_2O_3$ by calcination and hydrogen reduction of Cu-nitrate. The sintered samples showed large pores with sizes of about $150{\mu}m$; these pores were aligned parallel to the camphene growth direction. Also, the internal walls of the large pores had relatively small pores due to the traces of camphene left between the concentrated $Al_2O_3$ particles on the internal wall. EDS analysis revealed that the Cu particles were mainly dispersed on the surfaces of the large pores. These results strongly suggest that porous $Al_2O_3$ with Cu dispersion can be successfully fabricated by freeze-drying and solution chemistry routes.

NiO/camphene 슬러리의 동결건조 및 수소환원 공정에 의한 Ni 다공체 제조 (Fabrication of Porous Ni by Freeze Drying and Hydrogen Reduction of NiO/Camphene Slurry)

  • 정재헌;오승탁;현창용
    • 한국분말재료학회지
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    • 제26권1호
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    • pp.6-10
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    • 2019
  • In this study, freeze drying of a porous Ni with unidirectionally aligned pore channels is accomplished by using a NiO powder and camphene. Camphene slurries with NiO content of 5 and 10 vol% are prepared by mixing them with a small amount of dispersant at $50^{\circ}C$. Freezing of a slurry is performed at $-25^{\circ}C$ while the growth direction of the camphene is unidirectionally controlled. Pores are generated subsequently by sublimation of the camphene during drying in air for 48 h. The green bodies are hydrogen-reduced at $400^{\circ}C$ and then sintered at $800^{\circ}C$ and $900^{\circ}C$ for 1 h. X-ray diffraction analysis reveals that the NiO powder is completely converted to the Ni phase without any reaction phases. The sintered samples show large pores that align parallel pores in the camphene growth direction as well as small pores in the internal walls of large pores. The size of large and small pores decreases with increasing powder content from 5 to 10 vol%. The influence of powder content on the pore structure is explained by the degree of powder rearrangement in slurry and the accumulation behavior of powders in the interdendritic spaces of solidified camphene.

무작위 에칭 흑연 기공을 가지는 탄소기반 흡착제에 의한 산소, 질소 및 아르곤의 흡착 계산 (Adsorption Calculation of Oxygen, Nitrogen and Argon in Carbon-Based Adsorbent with Randomly Etched Graphite Pores)

  • 서양곤
    • 청정기술
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    • 제24권4호
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    • pp.348-356
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    • 2018
  • 분자전산 모사 방법에 의하여 슬릿 기공과 무작위 에칭 흑연(randomly etched graphite, REG) 기공을 가지는 탄소계 흡착제에서 산소, 질소 그리고 아르곤에 대한 흡착 평형을 계산 하였다. 흡착량 계산에서 흡착제와 흡착질의 신뢰할 만한 모델은 공업적 흡착 분리 공정의 정확한 설계에 매우 중요하다. $5.6{\AA}$의 가장 작은 물리적 기공 크기에서 오직 산소만이 기공의 중심에 흡착하였으며, $5.9{\AA}$부터 질소와 아르곤이 흡착을 시작하였다. 균일한 표면을 가지는 슬릿기공이 결함 기공의 불용 부피와 접근이 불가능한 부피로 인하여 표면에 이질성을 가지는 REG 기공보다 더 높은 흡착 능력을 보였다. 탄소계 흡착제의 경우 질소보다 산소가 높은 흡착량을 보였으며, 기공이 큰 경우 산소와 아르곤의 흡착량은 동일함을 보였다. 298 K에서 흡착 등온선 계산으로부터 압력이 증가할수록 질소에 대한 산소의 흡착량의 비율이 높아짐을 보였다.

프랙탈 차원에 의한 소자 표면의 정량화 분석 (Quantification Analysis of Element Surface by Fractal Dimension)

  • 홍경진
    • 한국인터넷방송통신학회논문지
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    • 제23권1호
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    • pp.145-149
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    • 2023
  • 표면의 고해상도 이미지는 나노(nano)사이즈 부터 마이크로미터까지 특정한 크기를 갖는 기공이나 형상에 대한 자세한 정보를 제공한다. 그러나 표면의 고해상도 이미지로 부터 기공이나 형상에 대한 효율적인 연관성을 결정하는 것은 아직 확실하지 않다. 기공이나 형상의 효율적 연관성을 위하여 소자의 표면특성은 SEM 사진을 촬영하고 이미지를 이진화하여 프랙탈 차원으로 고찰하였다. 소자의 표면 분석을 위하여 프랙탈 프로그램은 직접 코딩하였다. 소자 표면 특성과 전기적 특성은 프랙탈 차원과 연관성이 있을 것으로 생각된다. 프랙탈 차원은 내부 기공의 증가와 더불어 감소하였다. 소자 표면의 구조적 특성인 입자의 밀도와 입계는 프랙탈 차원과 연관이 있었다. 입자의 크기는 프랙탈 차원의 증가와 더불어 감소하였으며 균일하게 형성되었다. 입자가 균일하게 형성되면 기공이 적게 존재하여 프랙탈 차원이 증가하였다.

Changing the Surface-Liquid Crystal Interaction through the Adsorption of Silica Nanoparticles

  • Finotello, Daniele;Jin, Tao
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
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    • pp.847-848
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    • 2004
  • We studied a low density 8CB liquid crystal-hydrophobic aerosil dispersions imbedded in submicron-size cylindrical pores. The nanosize spherical aerosil particles are adsorbed at the pore wall and hinder the planar anchoring. The adsorption is temperature dependent, and an axial to radial molecular configuration transition occurs within the cylindrical pores.

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Identification and Three-Dimensional Characterization of Micropore Networks Developed in Granite using Micro-Focus X-ray CT

  • Choo, Chang-Oh;Takahashi, Manabu;Jeong, Gyo-Cheol
    • 지질공학
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    • 제24권2호
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    • pp.179-189
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    • 2014
  • We analyzed the three-dimensional distribution of micropores and internal structures in both fresh and weathered granite using micro-focus X-ray computed tomography (micro-CT). Results show that the pore radius in fresh granite is mostly in the range of $17-50{\mu}m$, the throat radius is in the range of $5-25{\mu}m$, and the coordination number (CN) of pores is less than 10. In contrast, the pore radius in weathered granite is mostly in the range of $20-80{\mu}m$, the throat radius is in the range of $8-30{\mu}m$, and the CN is less than 12. In general, a positive linear relationship exists between pore radius and CN. In addition, both the size and the density of pores increase with an increasing degree of rock weathering. The size of the throats that connect the pores also increases with an increasing degree of weathering, which induces fracture propagation in rocks. Micro-CT is a powerful and versatile approach for investigating the three-dimensional distributions of pores and fracture structures in rocks, and for quantitatively assessing the degree of pore connectivity.