• Title/Summary/Keyword: Pore Development

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Development of U-shaped Arterialvenous Shunt Using Porous Polyurethane (다공성 폴리우레탄을 이용한 동정맥 누관의 개발)

  • 정재승;김희찬;박광석;최진욱;민병구
    • Journal of Biomedical Engineering Research
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    • v.20 no.2
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    • pp.221-230
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    • 1999
  • A new technique for the preparation of porous polyurethane vascular prostheses was investigated. Synthetic vascular grafts with porous wall have been widely proposed, claiming that strength, suture retention, kink resistance, and other handling properties are improved over those with nonporous solid wall. Related to these facts, the control of pores and compliance match have been very important and interesting issues. Two kinds of polymer sheets were compared. One was the porous PU-sheet made at room temerature by the solvent/non-solvent exchange. And the other was the porous PU-sheet fabricated by thermal phase transition and solvent/non-solvent exchange in the thermal controlled bath. According to the result of the above experiments, polyurethane solution was injected into a mold designed for U-type graft. After freezing at low temperature, solvent was dissolved out with alcohol at < $0^{\circ}C$ and water at room temperature to form porous vessels. The average pore size and pore occupation were easily changed by changing polyurethane concentration and freezing rate. This technique can give a proper pore size for tissue ingrowth, and suitable compliances for matching with arteries and veins. In addition, the fabrication of more complicated shaped vessels such as the U-type vascular grafts is easily controlled by using a mold. This method might give a desired compliact graft for artificial implantaion with the commercially available medical polymers.

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A Case Study on Earthquake-induced Deformation of Quay Wall and Backfill in Pohang by 2D-Effective Stress Analysis (2차원 유효응력 해석에 의한 지진시 포항 안벽구조물의 변형 사례 분석)

  • Kim, Seungjong;Hwang, Woong-Ki;Kim, Tae-Hyung;Kang, Gi-Chun
    • Journal of the Korean Geotechnical Society
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    • v.35 no.7
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    • pp.15-27
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    • 2019
  • The purpose of this study is to investigate the mechanism about damages occurring at quay wall and backfill in Youngilman Port during Pohang earthquake (M5.4) on November 15, 2017. In the field investigation, the horizontal displacement of the caisson occurred between 5 cm and 15 cm, and the settlement at backfill occurred higher than 10 cm. 2D-effective Stress Analysis was performed to clarify the mechanism for the damage. The input earthquake motion used acceleration ($3.25m/s^2$) measured at bedrock of Pohang habor. Based on a numerical analysis, it was found that the effective stress decreased due to the increase of excess pore pressure in the backfill ground and the horizontal displacement of the caisson occurred by about 14 cm, and the settlement occurred by about 3 cm. In backfill, the settlements occurred between 6 cm and 9 cm. This is similar to field investigation results. Also, it was found that the backfill soil was close to the Mohr-Coulomb failure line due to the cyclic loading from the effective stress path and the stress-strain behavior. It may be related to decreasing of bearing capacity induced by the reduction of effective stress caused by the increase of the excess pore water pressure.

Preparation and Electrochemical Characterization of Activated Carbon Electrode by Amino-fluorination (아미노불소화 반응에 의한 활성탄소전극 제조 및 전기화학적 특성)

  • Lim, Jae Won;Jeong, Euigyung;Jung, Min Jung;Lee, Sang Ick;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.22 no.4
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    • pp.405-410
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    • 2011
  • High-performance of an electric double layer capacitance (EDLC) electrode was prepared by the amino-fluorination of activated carbon by using $NF_3$ gas. The pore structure and surface chemistry were investigated based on the specific capacitance of EDLC. The amino-fluorination of activated carbon introduced functional groups of nitrogen and fluorine which are beneficial for the specific capacitance of EDLC without the change of pore structures. The E-NF100AC electrode, which has nitrogen and fluorine functional groups less than 1 at%, showed the highly improved specific capacitance of 528 (${\pm}9$) F/g at 2 mV/s showing 122% improved value when comparing with that of non-functionalized E-RAC electrodes. Whereas, the E-NF200AC electrode, which has nitrogen and fluorine functional groups over 1 at%, showed the decreased specific capacitance because of perfluorinated introduction. So, it is concluded that the proper contents of nitrogen and fluorine groups improved the specific capacitance of EDLC.

Development of Pore Filled Anion Exchange Membrane Using UV Polymerization Method for Anion Exchange Membrane Fuel Cell Application (음이온교환막 연료전지 응용을 위한 UV 중합법을 이용한 세공 충진 음이온교환막 개발)

  • Ga Jin Kwak;Do Hyeong Kim;Sang Yong Nam
    • Membrane Journal
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    • v.33 no.2
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    • pp.77-86
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    • 2023
  • In this study, pore-filled ion exchange membranes with low membrane resistance and high hydroxide ion conductivity was developed. To improve alkali durability, a porous substrate made of polytetrafluoroethylene was used, and a copolymer was prepared using monomers 2-(dimethyl amino) ethyl methacrylate (DMAEMA) and vinyl benzyl chloride (VBC) for pores. divinyl benzene (DVB) was used as the cross-linker, and ion exchange membranes were prepared for each cross-linking agent content to study the effect of the cross-linker content on DMAEMA-DVB and VBC-DMAEMA-DVB copolymers. As a result, chemical stability is improved by using a PTFE material substrate, and productivity can be increased by enabling fast photo polymerization at a low temperature by using a low-pressure UV lamp. To confirm the physical and chemical stability of the ion exchange membrane required for an anion exchange membrane fuel cell, tensile strength, and alkali resistance tests were conducted. As a result, as the cross-linking degree increased, the tensile strength increased by approximately 40 MPa, and finally, through the silver conductivity and alkali resistance tests, it was confirmed that the alkaline stability increased as the cross-linking agent increased.

Analysis of Groundwater Level Reduction Effects to Burial Angle of Slope Reinforcement Materials (비탈면 보강재의 매설각에 따른 지하수위 저감효과 분석)

  • Hyeonjun Yoon;Sungyeol Lee;Wonjin Baek;Jaemo Kang;Jinyoung Kim;Hwabin, Ko
    • Journal of the Korean GEO-environmental Society
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    • v.24 no.8
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    • pp.5-11
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    • 2023
  • Due to frequent occurrences of concentrated heavy rainfall caused by abnormal climate conditions in recent years, collapses of steep slopes have been occurring frequently due to surface erosion and increased pore water pressure. Various methods are being applied to prevent slope collapses, such as increasing the resistance to movement and reducing pore water pressure. Research on these methods has been consistently conducted as they provide an efficient response to slope collapses by satisfying both the conditions of resistance to movement and pore water pressure simultaneously. Therefore, in this study, we propose an upward slope reinforcement method by burying drainage materials with an upward slope inclination, instead of the conventional horizontal application. This approach aims to satisfy both slope reinforcement and drainage functions effectively, offering a comprehensive solution for slope stabilization. Furthermore, to determine the optimal burial angle that exhibits the most effective reinforcement and drainage effects of the proposed method, we investigated the reinforcement and drainage effects under conditions where the horizontal drainage materials were set at angles ranging from 0° to 60° in increments of 10° on a representative cross-section. Additionally, indoor model experiments were conducted under the conditions of 40°, which showed the most outstanding drainage effect, and 20°, which exhibited the highest safety factor, to validate the numerical analysis results. The results showed that the burial angle of 40° exhibits a relatively higher drainage effect as with the numerical analysis results, while the angle of 20° results in inadequate drainage and observed slope collapse.

Liquefaction Resistance of Gravel-Sand Mixtures (자갈-모래 혼합토의 액상화 거동)

  • Kim, Bang-Sig;Kang, Byung-Hee;Yoon, Yeo-Won
    • Journal of the Korean Geotechnical Society
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    • v.23 no.10
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    • pp.47-56
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    • 2007
  • In this research, the effects of the gravel content on the liquefaction behavior for both of the isotropically and $K_0-anisotropically$ consolidated gravel-sand mixtures are investigated. for this purpose, the cyclic triaxial tests for the specimens with the same relative density (Dr=40%) and variations of gravel content were performed. On the other hand, a series of undrained cyclic triaxial tests were carried out on the isotropically consolidated gravel-sand mixtures with the same void ratio (e=0.7) and from 0% to 30% gravel contents. Void ratios of gravel-sand mixtures with the same relative density (Dr=40%) are found to decrease significantly with the increase of the gravel content from 0% to about 70% and increase thereafter. But the void ratio of the sand matrix among the gravel skeleton increases with the increase of the gravel contents. Test results are as follows : for the isotropically consolidated specimen with 40% of relative density and low gavel contents (GC=0%, 20%, 40%), pore water pressure development and axial strain behavior during undrained cyclic loading show similar behavior to those of the loose sand because of high void ratio, and the specimens with high gravel content (70%) both pore pressure and strata behaviors are similar to those of dense sand. And the isotropically consolidated specimens with the same void ratio (e=0.7) and higher gravel contents show the same behavior of pore water pressure and axial strain as that of the loose sand, but for the lower gravel content this behavior shows similar behavior to that of dense sand. The liquefaction strength of the isotropically consolidated specimens with the same relative density increases with gravel content up to 70%, and the strength decreases with the increase of the gravel content at the same void ratio. Thus, it is confirmed that the liquefaction strength of the gravel-sand mixtures depends both on relative density and void ratio of the whole mixture rather than the relative density of the sand matrix filled among gravels. On the other hand, the behavior of pore water pressure and axial strain for the $K_0-anisotropically$ consolidated gravel-sand mixtures shows almost the same cyclic behavior of the sand with no stress reversal even with some stress reversal of the cyclic loading. Namely, even the stress reversal of about 10% of cyclic stress amplitude, the permanent strain with small cyclic strain increases rapidly with the number of cycles, and the initial liquefaction does not occur always with less than maximum pore water pressure ratio of 1.0. The liquefaction resistance increases with the gravel contents between 0% and 40%, but tends to decrease beyond 40% of gravel content. In conclusion, the cyclic behavior of gravel-sand mixtures depends on factors such as gravel content, void ratio, relative density and consolidation condition.

Development of Light weight Aluminum Subframe using Hybrid forming process (복합성형공법 적용 경량 알루미늄 서브프레임 개발)

  • Kwon, T.W.;Park, B.C.;Jang, G.W.;Lee, W.S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2007.05a
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    • pp.361-363
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    • 2007
  • The light weight aluminum subframe for automobile chassis part was developed using hybrid process, i.e. extruforming, press stamping and MIG welding. To achieve a 30 % weight reduction compared with conventional steel subframe keeping satisfactory performance, the design of cross-section of extruforming part was introduced, then forming simulation was performed and the final design was determined. In addition, we tried to estibilish optimun aluminum welding conditions for good penetration depth and few pore defact, finally the prototype of aluminum subframe was assembled using MIG welding method.

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Improvement of gas sensing properties of carbon nanofibers based on polyacrylonitrile and pitch by steam activation

  • Kim, Jeongsik;Kim, Hyung-Il;Yun, Jumi
    • Carbon letters
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    • v.24
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    • pp.36-40
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    • 2017
  • Polyacrylonitrile/pitch nanofibers were prepared by electrospinning as a precursor for a gas sensor material. Pitch nanofibers were properly fabricated by incorporating polyacrylonitrile as an electrospinning supplement component. Polyacrylonitrile/pitch nanofibers were activated with steam at various temperatures followed by subsequent carbonization to make carbon nanofibers with a highly conductive graphitic structure. Steam activation was effective in facilitating gas adsorption onto the carbon nanofibers due to the increased surface area. The carbon nanofibers activated at $800^{\circ}C$ had a larger surface area and a lower micro pore fraction resulting in a higher variation in electrical resistance for improved CO gas sensing properties.

UNIFICATION OF THERMO-PHYSICS OF MATERIALS AND MECHANICS OF STRUCTURES - TOWARD A LIFE SPAN SIMULATOR OF STRUCTURAL CONCRETE -

  • Maekawa, K.;Ishida, T.
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.10a
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    • pp.29-46
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    • 1999
  • The performance based design obligates quantitative assessment of required performances by means of transparent and objective science. In this design scheme, simulation of both macro and micro-scale structural behaviors is thought to be a powerful tool. This paper proposes a way how to unify the structural safety and serviceability check method and durability assessment of RC structures. Though component chemical-physical processes are crudely assumed, system dynamics of micro-scale pore structure formation and macro-scale defects and deformation of structures was shown as possible and promising approach in future. The authors understand that the unification of structural and durability design has just started. For further progress and development, predictive tool of structural behaviors from birth to death of concrete under any specified environment and load serves as an essential technicality.

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Development of Ceramic Composite Membranes for Gas Separation: III. Examination of Membrane Characteristics by the Gas Permeation Model (기체분리용 세라믹 복합분리막의 개발: III. 기체투과 모델에 의한 막의 특성 규명)

  • 현상훈;윤성필;강범석
    • Journal of the Korean Ceramic Society
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    • v.29 no.11
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    • pp.905-911
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    • 1992
  • Model equations for the gas permeation through a ceramic composite membrane were derived for examining the existence of crack, the reproducibility, and the microstructural properties of composite membranes. From the results of analyzing the nitrogen permeability data through alumina-tube supported TiO2 and SiO2 composite membranes, the extent of cracking, and the formation and structure of membrane top-layers were modelled. It was proved that the crack-free and reproducible composite membranes could be easily prepared only by the pore-filled coating within pores of the support in the sol-gel coating process.

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