• Title/Summary/Keyword: Pore Development

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Adsorption properties of surface - modified activated carbon (활성탄의 표면 구조 변화에 따른 흡착 특성 연구)

  • 김정렬;서문원;신창호;김영호;이근회;지상운
    • Journal of the Korean Society of Tobacco Science
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    • v.16 no.2
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    • pp.191-197
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    • 1994
  • Relationships between surface structure and adsorption properties of smoke components were investigated in surface-modified and un-modified activated carbon filter cigarettes. Commercially available activated carbon was treated with nitric acid and hydrogen peroxide as oxidant, and their pore volume, surface structure, BET surface area, pore type and size were studied. BET surface area and pore volume were decreased by nitric acid treatment, but median pore diameter was 8.1 $\AA$, which showed better development of pore compared with that of un-modified activated carbon, 6.9 $\AA$. In case of hydrogen peroxide treatment, BET surface area and pore volume were increased. Their pore was found to be a slit type based on V-t plot analysis. Neutralization capacities for bases of different strength (NaHCO3, Na2CO3, NaOEt and NaOH) showed that the majority of the acidic surface groups are of weak acidity. Modification of the activated carbon surface led to a slight change in adsorption properties when analyzing the smoke of triple-filter cigarette with surface-modified activated carbon.

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Active Exchange of Water and Nutrients between Seawater and Shallow Pore Water in Intertidal Sandflats

  • Hwang, Dong-Woon;Kim, Gue-Buem;Yang, Han-Soeb
    • Ocean Science Journal
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    • v.43 no.4
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    • pp.223-232
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    • 2008
  • In order to determine the temporal and spatial variations of nutrient profiles in the shallow pore water columns (upper 30 cm depth) of intertidal sandflats, we measured the salinity and nutrient concentrations in pore water and seawater at various coastal environments along the southern coast of Korea. In the intertidal zone, salinity and nutrient concentrations in pore water showed marked vertical changes with depth, owing to the active exchange between the pore water and overlying seawater, while they are temporally more stable and vertically constant in the sublittoral zone. In some cases, the advective flow of fresh groundwater caused strong vertical gradients of salinity and nutrients in the upper 10 cm depth of surface sediments, indicating the active mixing of the fresher groundwater with overlying seawater. Such upper pore water column profiles clearly signified the temporal fluctuation of lower-salinity and higher-Si seawater intrusion into pore water in an intertidal sandflat near the mouth of an estuary. We also observed a semimonthly fluctuation of pore water nutrients due to spring-neap tide associated recirculation of seawater through the upper sediments. Our study shows that the exchange of water and nutrients between shallow pore water and overlying seawater is most active in the upper 20 cm layer of intertidal sandflats, due to physical forces such as tides, wave set-up, and density-thermal gradient.

Micromechanics based Models for Pore-Sructure Formation and Hydration Heat in Early-Age Concrete (초기재령 콘크리트의 세공구조 형성 및 발영특성에 관한 미시역학적 모델)

  • 조호진;박상순;송하원;변근주
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.04a
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    • pp.123-128
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    • 1999
  • Recently, as a performance based design concept is introduced, assurance of expected performances on serviceability and safety in the whole span of life is exactly requested. So, quantitative assessments about durability related properties of concrete in early-age long term are come to necessary, Especially in early age, deterioration which affects long-term durability performance can be occurred by hydration heat and shrinkage, so development of reasonable hydration heat model which can simulate early age behavior is necessary. The micor-pore structure formation property also affects shrinkage behavior in early age and carbonations and chloride ion penetration characteristic in long term, So, for the quantitative assessment on durability performance of concrete, modelings of early age concrete based on hydration process and micor-pore structure formation characteristics are important. In this paper, a micromechanics based hydration heat evolution model is adopted and a quantitative model which can simulate micro-pore structure development is also verified with experimental results. The models can be used effectively to simulate the early-age behavior of concrete composed of different mix proportions.

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Thermal stress and pore pressure development in microwave heated concrete

  • Akbarnezhad, A.;Ong, K.C.G.
    • Computers and Concrete
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    • v.8 no.4
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    • pp.425-443
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    • 2011
  • Most previous studies have generally overlooked the contribution of thermal stresses generated within the concrete mass when subjected to microwave heating and reported on pore-pressure as being the dominant cause of surface spalling. Also, the variation in electromagnetic properties of concrete and its effects on the microwave heating process have not been studied in detail. In this paper, finite element modeling is used to examine the simultaneous development of compressive thermal stresses and pore-pressure arising from the microwave heating of concrete. A modified Lambert's Law formulation is proposed to estimate the microwave power dissipation in the concrete mass. Moreover, the effects of frequency and concrete water content on the concrete heating rate and pattern are investigated. Results show high compressive stresses being generated especially in concrete with a high water content when heated by microwaves of higher frequencies. The results also reveal that the water content of concrete plays a crucial role in the microwave heating process.

Development and Application of Image Analysis Program for Investigation of Pore Characteristics in Transverse Surface of Hardwoods

  • Kwon, Oh-Kyung;Lee, Phil-Woo
    • Journal of the Korean Wood Science and Technology
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    • v.26 no.2
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    • pp.29-37
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    • 1998
  • An image analysis program with the function of measuring various quantitative characteristics in the transverse surface of wood was developed using Delphi 2.0. Data on pore characteristics (conditions for image processing, proportion of pores in relationship to other elements, tangential diameter, area, tangential and radial diameter, x and y coordinates of pore center, and geometric coefficients) were saved in text file format. In addition, the pore area histogram in the tangential and radial directions was saved as a BMP (bitmap) type file. Analyses indicated that quantitative characteristics such as the relative radial distribution of pores in a growth ring, pore tangential area histogram, and proportion of pore in lumen area appear to be useful in separating four diffuse-porous woods and four ring-porous woods on the species level.

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Development of Pore-filled Ion-exchange Membranes for Efficient All Vanadium Redox Flow Batteries

  • Kang, Moon-Sung
    • Journal of the Korean Electrochemical Society
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    • v.16 no.4
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    • pp.204-210
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    • 2013
  • Thin pore-filled cation and anion-exchange membranes (PFCEM and PFAEMs, $t_m=25-30{\mu}m$) were prepared using a porous polymeric substrate for efficient all-vanadium redox flow battery (VRB). The electrochemical and charge-discharge performances of the membranes have been systematically investigated and compared with those of commercially available ion-exchange membranes. The pore-filled membranes were shown to have higher permselectivity as well as lower electrical resistances than those of the commercial membranes. In addition, the VRBs employing the pore-filled membranes exhibited the respectable charge-discharge performances, showing the energy efficiencies (EE) of 82.4% and 84.9% for the PFCEM and PFAEM, respectively (cf. EE = 87.2% for Nafion 1135). The results demonstrated that the pore-filled ion-exchange membranes could be successfully used in VRBs as an efficient separator by replacing expensive Nafion membrane.

Characteristics of failure surfaces induced by embankments on soft ground

  • Hong, Eun-Soo;Song, Ki-Il;Yoon, Yeo-Won;Hu, Jong-Wan
    • Geomechanics and Engineering
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    • v.6 no.1
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    • pp.17-31
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    • 2014
  • This paper investigates the development of failure surfaces induced by an embankment on soft marine clay deposits and the characteristics of such surfaces through numerical simulations and its comparative study with monitoring results. It is well known that the factor of safety of embankment slopes is closely related to the vertical loading, including the height of the embankment. That is, an increase in the embankment height reduces the factor of safety. However, few studies have examined the relationship between the lateral movement of soft soil beneath the embankment and the factor of safety. In addition, no study has investigated the distribution of the pore pressure coefficient B value along the failure surface. This paper conducts a continuum analysis using finite difference methods to characterize the development of failure surfaces during embankment construction on soft marine clay deposits. The results of the continuum analysis for failure surfaces, stress, displacement, and the factor of safety can be used for the management of embankment construction. In failure mechanism, it has been validated that a large shear displacement causes change of stress and pore pressure along the failure surface. In addition, the pore pressure coefficient B value decreases along the failure surface as the embankment height increases. This means that the rate of change in stress is higher than that in pore pressure.

Micro-porous Nickel Produced by Powder Metallurgy

  • Yamada, Y.;Li, Y.C.;Banno, T.;Xie, Z.K.;Wen, C.E.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.602-603
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    • 2006
  • Micro-porous nickel (Ni) with an open cell structure was fabricated by powder metallurgy. The pore size of the micro-porous Ni approximated $30{\mu}m$ and $150{\mu}m$. For comparison, porous Ni with a macro-porous structure were also prepared by both powder metallurgy (pore size $800{\mu}m$) and the traditional chemical vapour deposition method (pore size $1300{\mu}m$). The mechanical properties of the micro-and macro-porous Ni samples were evaluated using compressive tests. Results indicate that the micro-porous Ni samples exhibited significantly enhanced mechanical properties, compared to those of the macro-porous Ni samples.

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Three Dimensional Measurements of Pore Morphological and Hydraulic Properties (토양 공극 형태와 수문학적 특성에 대한 3 차원적 측정)

  • Chun, Hyen-Chung;Gimenez, Daniel;Yoon, Sung-Won;Heck, Richard;Elliot, Tom;Ziska, Laise;Geaorge, Kate;Sonn, Yeon-Kyu;Ha, Sang-Keun
    • Korean Journal of Soil Science and Fertilizer
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    • v.43 no.4
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    • pp.415-423
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    • 2010
  • Pore network models are useful tools to investigate soil pore geometry. These models provide quantitative information of pore geometry from 3D images. This study presents a pore network model to quantify pore structure and hydraulic characteristics. The objectives of this work were to apply the pore network model to characterize pore structure from large images to quantify pore structure, calculate water retention and hydraulic conductivity properties from a three dimensional soil image, and to combine measured hydraulic properties from experiments with calculated hydraulic properties from image. Soil samples were taken from a site located at the Baltimore science center, which is located inside of the city. Undisturbed columns were taken from the site and scanned with a computer tomographer at resolutions of 22 ${\mu}m$. Pore networks were extracted by medial-axis transformation and were used to measure pore geometry from one of the scanned samples. Water retention and unsaturated hydraulic conductivity values were calculated from the soil image. Properties of soil bulk density, water retention and unsaturated hydraulic conductivity were measured from three replicates of scanned soil samples. 3D image analysis provided accurate detailed pore properties such as individual pore volumes, pore length, and tortuosity of all pores. These data made possible to calculate accurate estimations of water retention and hydraulic conductivity. Combination of the calculated and measured hydraulic properties gave more accurate information on pore sizes over wider range than measured or calculated data alone. We could conclude that the hydraulic property computed from soil images and laboratory measurements can describe a full structure of intra- and inter-aggregate pores in soil.

Dynamic Analysis of Gravity Quay Wall Considering Development of Excess Pore Pressure in Backfill Soil (과잉간극수압 발생을 고려한 중력식 안벽구조물의 동적해석)

  • Ryu, Moo-Sung;Hwang, Jai-Ik;Kim, Sung-Ryul
    • Journal of Ocean Engineering and Technology
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    • v.24 no.5
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    • pp.39-47
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    • 2010
  • In this paper, a total stress analysis method for gravity quay walls is suggested. The method can evaluate the displacement of the quay walls considering the effect of excess pore pressure developed in backfill soils. This method changes the stiffness of backfill soils according to the expected magnitude of the excess pore pressure. For practical application, evaluation methods are suggested for determining the excess pore pressure ratio developed in the backfill soils and the backfill stiffness that corresponds to the excess pore pressure ratio. This method is important in practical applications because the displacement of the quay walls can be evaluated by using only the basic input properties in the total stress analysis. The applicability of the suggested method was verified by comparing the results of the analysis with the results of 1-g shaking table tests. From the comparison, it was found that the calculated displacements from the suggested method showed good agreement with the measured displacements of the quay walls. It was also found that the excess pore pressure in backfill soils is a governing influence on the dynamic behavior of quay walls.