• Title/Summary/Keyword: Polyvinylpyrrolidone

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A Comparative Study on the Characteristics of the MWCNTs and PVP Added Nanofluids (다중벽 탄소나노튜브와 PVP가 첨가된 나노유체의 특성 비교 연구)

  • Park, Sung-Seek;Park, Youn-Cheol;Kim, Nam-Jin
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.23 no.1
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    • pp.47-53
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    • 2011
  • In this study, the characteristics of multi-walled carbon nanotubes added nanofluid were investigated. Sodium Dodecyl Sulfate, SDS, and Polyvinylpyrrolidone, PVP, were employed as the dispersant. SDS or PVP was added in pure water. And then, 0.0005, 0.001, 0.002, 0.003. 0.004, 0.005,0.01, and 0.02 vol% of CM-95 and CM-100 were dispersed respectively. The thermal conductivity and the viscosity were measured with a transient hot-wire instrument built for this study and the DV II+ Pro viscometer. The results showed that PVP had good thermal conductivity at 300 wt% and the thermal conductivity of CM-100 was better than that of CM-95. However, the viscosity of CM 100 was higher than that of CM 95.

Fabrication of CuSn Nanofibers Prepared via Electrospinning

  • Choi, Jinhee;Park, Juyun;Choi, Ahrom;Lee, Seokhee;Koh, Sung-Wi;Kang, Yong-Cheol
    • Journal of Integrative Natural Science
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    • v.10 no.4
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    • pp.245-248
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    • 2017
  • The Cu and CuSn/PVP nanofibers were fabricated by electrospinning method by controlling various parameters. The precursor solution was prepared with copper(II) acetate monohydrate ($Cu(CH_3COO)_2$) and tin chloride dihydrate ($SnCl_2{\cdot}2H_2O$), and polyvinylpyrrolidone (PVP) for adjusting viscosity. The fabricated nanofibers were calcined at 873 K in Ar atmospheric environment for 5 hours to remove the solvent and polymer. The morphology and diameter of nanofibers were measured by optical microscopy (OM) with Motic image plus 2.0 program. The components and chemical environment were investigated with X-ray photoelectron spectroscopy (XPS). From the XPS survey spectra, we confirmed that CuSn/PVP nanofibers were successfully fabricated. The XPS peaks of C 1s and N 1s were remarkably decreased after calcination of the nanofibers at 873 K. It implies that the PVP was completely decomposed after calcination at 873 K.

Effect of Solvents on the Structure of Electrospun PVP Fiber (PVP의 전기방사 섬유 제조에서 용매에 따른 구조 변화)

  • Park, Ju-Young;Lee, In-Hwa
    • Applied Chemistry for Engineering
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    • v.19 no.5
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    • pp.484-490
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    • 2008
  • Electrospun of PVP (polyvinylpyrrolidone) ultra fine fibers were fabricated using various solvents including methanol, ethanol, 2-propanol, butanol, acetone, methylene chloride, and DMF, which possess different properties such as boiling point, dielectric constant, and dipole moment. Electrospun PVP fiber was influenced by viscosity, conductivity, and surface tension of spinning solution. Therefore, the electrospun PVP fiber was successfully prepared under critical conditions of viscosity > $0.114kg/m{\cdot}s$, conductivity > 1.02 mS/m, surface tension < 30.0 mN/m. In case of an ethanol solvent system, average diameter of PVP fiber increased from 1701 nm to 5454 nm as increased the applied voltage from 10 kV to 20 kV.

Preparation of ZnO2 Nanoparticles Using Organometallic Zinc(II) Isobutylcarbamate in Organic Solvent

  • Kim, Kyung-A;Cha, Jae-Ryung;Gong, Myoung-Seon;Kim, Jong-Gyu
    • Bulletin of the Korean Chemical Society
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    • v.35 no.2
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    • pp.431-435
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    • 2014
  • Zinc peroxide nanoparticles ($ZnO_2$ NPs) were prepared by reacting zinc(II) isobutylcarbamate, as an organometallic precursor, with hydrogen peroxide ($H_2O_2$) at $60^{\circ}C$. Polyethylene glycol and polyvinylpyrrolidone were used as stabilizers, which suppressed aggregation of the $ZnO_2$ NPs. Conditions such as concentrations of $H_2O_2$ and the stabilizer were systemically controlled to determine their effect on the formation of nano-sized $ZnO_2$ NPs. The formation of stable $ZnO_2$ NPs was confirmed by UV-vis, Raman spectroscopy, X-ray photoelectron spectroscopy, transmission electron microscopy (TEM), scanning electron microscopy (SEM), and X-ray diffraction. The TEM images revealed that polyvinylpyrrolidone-stabilized $ZnO_2$ NPs (diameter, 10-30 nm) were well dispersed in the organic solvent. Quite pure ZnO NPs were obtained from the peroxide powder by simple heat treatment of $ZnO_2$. The transition temperature of $170^{\circ}C$ was determined by differential scanning calorimetry.

Preparation and Characteristics of Polyethersulfone Microfiltration Membranes (폴리에테르술폰 정밀여과막의 제조 및 특성 연구)

  • Kim, No-Won
    • Membrane Journal
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    • v.17 no.4
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    • pp.329-337
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    • 2007
  • This is the research about a new method to make the internal separation layer with smallest pore size in polyethersulfone (PES) membrane by adding p-toluenesulfonic acid (TSA) and polyvinylpyrolidone (PVP) to polymeric PES solution. The preparation and morphological characterization of PES sheet membranes containing PVP as a hydrophilic swelling material and TSA as a demixing material were performed. As a result by microflow porometery, the PVP and TSA added PES membranes showed good permeabilities and narrow pore size distributions, comparable to those of the commercial membranes. The concentration of PVP affected the PES characteristics on air permeability and surface structure. The concentration of TSA influenced on pore size distribution but do not affect air permeability. The surface images of FE-SEM shows similar pore size when TSA added or not. However, the cross-section images of FE-SEM show that the TSA added PES membranes have a increase of internal layer thickness with smallest pore size.

Interfacial and Rheological Properties of Selected Hydrogel Formulations for Soft Contact Lens (소프트 콘텍트 렌즈용 하이드로젤의 계면학적 및 유변학적 특성 연구)

  • Noh, Hye-Ran
    • Polymer(Korea)
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    • v.36 no.2
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    • pp.190-195
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    • 2012
  • Interfacial and rheological properties of selected hydrogel formulations were studied to understand the contact-lens comfort in end use. It was concluded that protein adsorption from aqueous solution decreased monotonically with increasing surface energy (water wettability) of tested hydrogels. Also, it has revealed that friction coefficient of polydimethylsiloxane-polyvinylpyrrolidone (PDMS-PVP) was significantly larger that 2-hydroxyethyl methacrylate (HEMA) based hydrogels. Interestingly, in artificial tear solution, friction coefficients of HEMA based hydrogels were larger than silicone hydrogels.

Electrospun Calcium Metaphosphate Nanofibers: I. Fabrication

  • Kim, Ye-Na;Lee, Deuk-Yong;Lee, Myung-Hyun;Lee, Se-Jong
    • Journal of the Korean Ceramic Society
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    • v.44 no.5 s.300
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    • pp.144-147
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    • 2007
  • Calcium metaphosphate (CMP) nanofibers with a diameter of ${\sim}600nm$ were prepared using electrospun CMP/polyvinylpyrrolidone (PVP) fibers through a process of drying for 5 h in air followed by annealing for 1 h at $650^{\circ}C$ in a vacuum. The viscosity of the CMP/PVP precursor containing 0.15 g/ml of PVP was 76 cP. Thermal analysis results revealed that the fibers were crystallized at $569^{\circ}C$. The crystal phase of the as-annealed fiber was determined to be ${\delta}-CMP\;({\delta}-Ca(PO_3)_2)$. However, the morphology of the fibers changed from smooth and uniform (as-spun fibers) to linked-particle characteristics with a tubular form most likely due to the decomposition of the inner PVP matrix. It is expected that this large amount of available surface area has the potential to provide unusually high bioactivity and fast responses in clinical hard tissue applications.

Analysis of Physical Properties of Hydrogel Lenses Polymer Containing Styrene and PVP

  • Lee, Min-Jae;Sung, A-Young
    • Korean Journal of Materials Research
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    • v.29 no.7
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    • pp.399-407
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    • 2019
  • This research is carried out to analyze the effects of Styrene and PVP on the properties of silicone hydrogel lenses. Styrene group and PVP(Polyvinylpyrrolidone) are used as additives for a basic combination containing silicone monomer, TSMA(trimethylsilyl methacrylate) and DMA(n,n-dimethylacrylamide) added to the mix at ratios of 1~10 %. Silicone hydrogel lens is produced by cast-mold method. The polymerized lens sample is hydrated in a 0.9 % saline solution for 24 hours before its optical and physical characteristics are measured. Measurement of the physical characteristics of the produced material shows that the refractive index is 1.3682~1.4321, water content 77.11~45.73 %, visible light transmittance 95.14~88.20 %, and tensile strength 0.0652~0.3113 kgf. The results show a decrease of refractive index as the ratio of additives and water content decreases. The result of the stabilization test of polymerization show an increase of extractables along with increase of the ratio of additives, but the difference is not significant for all samples, so it can be judged that the stabilization of the polymer is maintained. Therefore, the additions of styrene and PVP should be taken into consideration for their effects on the physical properties of silicone hydrogel lens.