• 제목/요약/키워드: Polyolefin

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Chlorinated Polyolefine (CPO)-g-β Carboxy Ethyl Acid (β-CEA) 수지의 합성 및 이를 Base Polymer로 하는 프라이머의 제조 및 물성 (Preparation and Characterization of Primer and Synthesized Chlorinated Polyolefine (CPO)-g-Carboxy Ethyl Acid (β-CEA))

  • 정부영;천정미;오상택;김태균;천제환
    • 접착 및 계면
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    • 제12권2호
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    • pp.62-66
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    • 2011
  • 본 연구에서는 PP (Polypropylene) 수지에 접착력이 우수한 저유해성 프라이머를 제조하기 위하여, 라디칼 중합법을 사용하여 $\beta$-carboxy ethyl acid ($\beta$-CEA)가 그라프트 중합된 Chlorinated Polyolefine (CPO)을 합성하였다. 또한 합성된 CPO-g-$\beta$-CEA를 이용하여, PP용 프라이머를 제조하고 유해성과 접착특성을 살펴보았다. 합성된 CPO-g-$\beta$ CEA의 구조 및 특성을 알아보기 위하여 FT-IR, DSC, UTM을 사용하였으며, 그라프트율은 $\beta$-CEA를 5 wt% 사용하였을 때 최적으로 나타났다. 또한 합성된 CPO-g-$\beta$-CEA에 접착증진제인 PX-95를 함량별로 사용하여 PP용 프라이머를 제조하고 접착력을 평가한 결과, 접착증진제의 함량이 3 wt%인 경우 접착력이 4.0 kgf/cm로 가장 높게 나타났다.

원예시설 결합기술의 수용효과와 보완성 분석 (Effect of Adoption and Complementarity of Production Technology Bundles in Horticultural Greenhouse)

  • 최돈우;김태균
    • 한국산학기술학회논문지
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    • 제16권9호
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    • pp.5906-5913
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    • 2015
  • 이 논문의 목적은 비닐하우스의 결합기술에 대한 수용효과와 보완성을 분석하는 것이다. 분석대상 기술은 10m 이상 하우스, polyolefin 필름, 권취환기, 15온스 이상 보온덮개 등 네 가지이며, 분석결과는 다음과 같이 요약된다. 첫째, 10m 이상 하우스, PO필름, 권취환기, 15온스 이상 보온덮개의 기술들이 단독으로 수용되었을 경우, 그리고 10m 이상 하우스와 권취환기의 기술결합, 10m 이상 하우스와 15온스 이상 보온덮개의 기술결합에서 순수익이 증가한다. 둘째, 권취환기를 활용하고 있는 경우, 10m 이상 하우스와 PO필름을 수용한다면 보완적 효과를 가져 올 수 있다. 셋째, 10m 이상 하우스와 권취환기는 항상 보완성을 가지는 조합으로 분석된다. 넷째, 10m 이상 하우스와 15온스 이상 보온덮개 기술조합은 PO필름과 권취환기를 모두 활용하지 않는 경우 보완적이다. 본 연구의 결과는 정부의 기술보급 정책에 기여할 것으로 기대된다.

ABS/PC/POE 열가소성 복합재료의 특성평가 및 시뮬레이션을 통한 물리적 성능 예측 연구 (Characterization of ABS/PC/POE Thermoplastic Composites and Prediction of Mechanical Properties by Geometry Simulation)

  • 유성훈;이종혁;여동현;신용호;박종수;심지현
    • 한국염색가공학회지
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    • 제34권2호
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    • pp.117-126
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    • 2022
  • In this study, thermoplastic composites were manufactured using ABS(acrylonitrile butadiene styrene), PC(polycarbonate), and POE(polyolefin elastomer), which are thermoplastic plastics. Twin screw extruder and injection molding were used to manufacture thermoplastic composites. When the ABS/PC/POE thermoplastic composite material was manufactured, the POE mass fraction was set to 1 to 5 wt.%, and the thermal and mechanical properties according to the POE mass fraction were analyzed. Based on the physical properties of ABS/PC/POE, a 3D model in the form of an e-bike frame was created. After setting the boundary conditions, when an external load is applied, geometry simulation was performed to predict product performance. The ABS/PC/POE thermoplastic composite material exhibited the best physical properties when the mass fraction of POE was 3 wt.%. In the simulation results for the physical properties of the 3D model in the form of an e-bike frame, the best physical properties were shown when the mass fraction of POE was 2 ~ 3 wt.%. As a result, the manufacturing conditions for ABS/PC/POE thermoplastic composite materials were set, and research was conducted to reduce product development costs and development time.

Boron nitride based processing aids

  • Hatzikiriakos, Savvas G.;Rathod, Nimish
    • Korea-Australia Rheology Journal
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    • 제15권4호
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    • pp.173-178
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    • 2003
  • Boron nitride is a new processing aid that is capable of eliminating gross melt fracture in several polymer processing operations. Its combinations with other processing aids i.e. fluoropolymers offer additional possibilities of obtaining enhanced processing aids that may take the processes to rates not realized before. A variety of different such combinations are discussed in this paper. The essential componenets are (1) boron nitride capable of eliminating gross melt fracture and (2) suitable lubricant capable of eliminating surface melt fracture such as stearates for the polyolefin processing and polyethylenes for the processing of fluoropolymers.

Grapefruit Seed Extract와 Ascorbic Acid의 혼합 처리가 콩나물 변패 미생물과 저장 품질에 미치는 영향 (Effect of Grapefruit Seed Extract and Ascorbic Acid on the Spoilage Microorganisms and Keeping Quality of Soybean Sprouts)

  • 박우포;조성환;이동선
    • 한국식품영양과학회지
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    • 제27권6호
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    • pp.1086-1093
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    • 1998
  • The antimicrobial effect of mixed solutions of grapefruit seed extract(250ppm) and ascorbic acid(1%) on the spoilage microorganisms such as Staphylococcus epidermis, Escherichia coli, Pseudomonas syringae, Candida albicans and Corynebacterium xerosis isolated from the spoiled soybean sprouts were investigated. Cell wall and membrane were partially destroyed and the contents of the destroyed cell were exuded after treatment. Packages with 30 m cast polypropylene(CPP), 16 m polyolefin(RD 106) and 10 m high density polyethylene(HDPE) were applied for soybean sprouts dipped in mixed solutions respectively. Oxygen and carbon dioxide concentration inside packages were dependent on the kind of films during storage at 5oC. The antimicrobial activity of mixed solutions was maintained for 5 days at CPP package. Package with HDPE showed a severe browning than the others after 5 days. Ascorbic acid content of mixed solution treatment was higher than that of control for each package.

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Polyolefin용 수성 Gravure Ink의 인쇄작성 (Printability of an Aqueous Gravure Ink for Polyolefin)

  • 김종원
    • 한국인쇄학회지
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    • 제12권1호
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    • pp.1.1-11
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    • 1994
  • The photosensitive properties and carrier transport in the organic photoconductor with the carrier transport layers(CTL) of polymer matrix doped with two carrier transport materials above carrier generation layer(CGL) containing oxotitanium phthalocyanine (TiOPc) were investigated. The CGL of TiOPc dispersed in poly(vinylbutyral) was formed as thickness of 0.1${\mu}{\textrm}{m}$and the carrier transport layer was prepared by coating polycarbonate and polyester doped with oxadiazoly(OXD), polyvinylcarbazole (PVK), trinitro fluorenone(TNF) as thickness of 10~15${\mu}{\textrm}{m}$, respectively. We have measured half decay exposure,sensitivity and xerographic gain from the photo-induced discharge curve(PIDC). In this work, it was found that the characteristics of carrier transport were mainly caused by the ionization potential difference of constitutive materials in molecularly doped polymer.

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지중배전케이블 외피용 컴파운드의 이온투과 특성 비교 (Effect of Ionic Impurities in Materials for CN/CV Underground Distribution Power Cable Jackets)

  • 김동명;권태호
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2008년도 Techno-Fair 및 추계학술대회 논문집 전기물성,응용부문
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    • pp.167-168
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    • 2008
  • The permeation of $Ca^{2+}$ ions through the materials such as polyvinyl chloride (PVC) and non-halogenated flame retardant cross linked polyolefin (FR-XLPO) used for CN-CV underground distribution power cable jackets was investigated. The permeation of $Ca^{2+}$ ions was found to increase with the increase of time. The FR-XLPO showed higher permeation of $Ca^{2+}$ ions, by a factor of about two, than the PVC. This was explained by the destruction of structural integrity caused by mixing a large amount of mineral flame retardant such as $Mg(OH)_2$ used to impart non-flame ability to the jacket material.

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Karl Fischer를 통한 전력케이블용 반도전 Composite 특성 연구 (A Study on the Property of Semiconductive Shield Composite through Karl Fischer Method in Power Cable)

  • 양훈;박대희
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2008년도 Techno-Fair 및 합동춘계학술대회 논문집 전기물성,응용부문
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    • pp.187-188
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    • 2008
  • In this paper, we have investigated water content of semiconductive shield materials for power cables, EEA(Ethylene Ethyl Acrylate) is used polymer matrix. And filler is used CNT(Carbon Nanotube) and CB(Carbon Black). EEA, CNT and CB is favor moisture. In case of EEA, it has polyolefin resin that strong polarity combination. To research water content, experimental method used KF(Karl Fischer). KF method is Electrochemical titration based on chemical reaction. As a result, specification by KEPCO(Korea Electric Power Corporation) is lower than 800ppm. CNT and CB ratio of 80 versus 20 is best specimen that had lowest moisture content. It seem likely to increase crosslinking rate, CNT between CB.

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투명 백 시트와 봉지재 물질 조합에 따른 소형 슁글드 실리콘 태양전지 모듈의 열화 특성 분석 (Degradation Characteristics according to Encapsulant Materials Combining with Transparent Backsheet on the Mini Shingled Si Photovoltaic Modules)

  • 손형진;김성현
    • Current Photovoltaic Research
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    • 제8권1호
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    • pp.12-16
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    • 2020
  • This study investigates the degradation characteristics of different material types of ethyl vinyl acetate (EVA) and polyolefin (POE) with combining transparent backsheet. To this end, we fabricated samples with structure of glass/encapsulant/transparent backsheet for each type of encapsulants, and shingled Si modules with the same structure. The samples were then subjected to accelerated test by storing under damp heat condition of 85℃ and 85% RH. As a result, encaplsulant discoloration was observed, which the transmittance of the samples with EVA decreased in a rapid rate than the samples with POE. The discoloration also affected a power degradation of the shingled modules with a reduction of current density, resulting that the module with EVA showed more drop on the efficiency than the modules with POE. Furthermore, corrosion of the soldered ribbon caused by acetic acid produced from the degraded EVA also contributed in fill factor reduction.