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http://dx.doi.org/10.17702/jai.2011.12.2.062

Preparation and Characterization of Primer and Synthesized Chlorinated Polyolefine (CPO)-g-Carboxy Ethyl Acid (β-CEA)  

Jeong, Booyoung (Korea Institute of Footwear Technology)
Cheon, Jungmi (Korea Institute of Footwear Technology)
Oh, Sangtaek (Korea Institute of Footwear Technology)
Kim, Taekyun (Hwaseung T&C Co., Ltd.)
Chun, Jaehwan (Korea Institute of Footwear Technology)
Publication Information
Journal of Adhesion and Interface / v.12, no.2, 2011 , pp. 62-66 More about this Journal
Abstract
In this study, we synthesized a excellent adhesive chlorinated polyolefin (CPO)-g-$\beta$-carboxy ethyl acid ($\beta$-CEA) by radical polymerization. Also, we prepared low-level toxic primer for polypropylene (PP) using CPO-g-$\beta$-CEA and studied toxic and adhesion property. We identified the graft structure and properties of the prepared chlorinated polyolefin-g-$\beta$ CEA using FT-IR, DSC, UTM. Graft ratio were optimum value at 5 wt% $\beta$-CEA contents in CPO-g-$\beta$ CEA. And the primer for PP was prepared with CPO-g-$\beta$ CEA and adhesive builder PX-95 content. Finally, optimum peel strength obtained when PX-95 contents was 3 wt%.
Keywords
poly propylene; primer; adhesion; CPO; $\beta$-CEA;
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