• 공업화학
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• 제34권4호
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• pp.421-425
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• 2023

Polymethyl methacrylate (PMMA), polycarbonate (PC), polyvinyl chloride (PVC), 그리고 polyacetal을 포함하는 일부 플라스틱류에 대한 연기특성을 조사하였다. 연기밀도는 ISO 5659-2의 기준에 의해 연기밀도시험기를 이용하여 정적인 연기 특성의 관련 값을 측정하였다. 또한 불꽃을 동반하는 연소와 불꽃을 동반하지 않는 연소를 구분하여 측정하였다. 불꽃방식의 복사열 50 kW/m² 의 조건하에서 연기의 최대비광학밀도(D_m) 측정값은 PMMA (401.26)가 최저로, PVC (1345.04)가 최대로 나타났다. 또한 비불꽃방식의 복사열 50 kW/m² 의 조건하에서 연기의 D_m 측정값은 PMMA (262.82) 가 최저로, PVC (1385.43)가 최대로 나타났다. 대상물의 연소 시 연기발생은 복사열 유속의 영향을 상당히 받으며, 탄화성 플라스틱은 연소 시 비탄화성 플라스틱보다 높은 연기 발생량을 나타내었다. 주 고분자 사슬에 방향족 그룹이 있는 폴리머는 열분해로 인해 다량의 숯이 생성되므로 다량의 연기를 발생시켰다.

• 한국분말재료학회지
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• 제16권4호
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• pp.262-267
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• 2009

Disk type porous nickel membrane was fabricated by in-situ reduction/sintering process using compacted NiO/PMMA (PMMA; Polymethyl methacrylate) mixture at $800^{\circ}C$ in hydrogen atmosphere. The porosity (49$\sim$58%) of these membrane was investigated as an amount of PMMA additive. The thermal decomposition and reduction behavior of NiO/PMMA were analyzed by TG/DTA in hydrogen atmosphere and the activation energy for the hydrogen reduction of NiO and thermal degradation of PMMA was calculated as 61.1 kJ/mol, evaluated by Kissinger method. Finally, the filtering performance and pressure drop were measured by particle counting system.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2003년도 International Meeting on Information Display
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• pp.675-678
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• 2003

We studied the electrical characteristics of pentacene-based organic field-effect transistors (FETs) with polymethyl methacrylate (PMMA) or poly-4-vinylphenol (PVP) as the gate insulator. PMMA or PVP was spin-coated on the indium tin oxide glass substrate that serves as gate electrodes. The source-drain current dependence on the gate voltage shows the FET characteristics of the hole accumulation type. The transistor with PVP shows a higher field-effect mobility of 0.14 $cm^{2}/Vs$ compared with 0.045 $cm^{2}/Vs$ for the transistor with PMMA. The atomic force microscope (AFM) images indicate that the grain size of the pentacene on PVP is larger than that on PMMA. X-ray diffraction (XRD) patterns for the pentacene deposited on PVP exhibit a new Bragg reflection at $19.5{\pm}0.2^{\circ}$, which is absent for the pentacene on PMMA. This peak corresponds to the flat-lying pentacene molecules with less intermolecular spacing.

• 대한치과보철학회지
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• 제55권3호
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• pp.305-310
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• 2017

최근, CAD/CAM 기술이 발전하면서 하이브리드 보철물의 제작에 이용되고 있다. Double scanning technique은 시적용 납의치와 주모형을 스캔 후 중첩하여, 가상 디자인의 현실화와 보철 기공 과정의 간소화를 이루었다. 본 증례에서는 금속 혹은 지르코니아 대신 고성능 중합체인 Polyetherketoneketone (Pekkton, Cendres+$M{\acute{e}}taux$, Biel, Switzerland)를 framework의 재료로 사용했으며, 콤포짓이나 세라믹 혹은 의치용 치아 대신 Polymethyl methacrylate (PMMA) 비니어링 치아(Visio-lign, Bredent, Senden, Germany)를 최종 보철물로 사용하였다. Pekkton과 Visio-lign을 사용한 본 증례에서 만족할만한 치료 결과와 환자의 만족을 얻었으며, 추후 주기적인 유지관리 및 평가가 필요할 것으로 사료된다.

• Computers and Concrete
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• 제27권2호
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• pp.111-130
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• 2021

In the present work, an extensive study for predicting efficiency parameters (��i) of various simulated nanocomposites including Polymethyl methacrylate (PMMA) as matrix and different structures including various sizes of graphene platelets (GPLs), single, double, and multi-walled carbon nanotubes (SWCNTs-DWCNTs-MWCNTs), and single and double-walled boron nitride nanotubes (SWBNNTs-DWBNNTs) are investigated. It should be stated that GPLs, carbon and boron nitride nanotubes (CNTs, BNNT) with different chiralities (5, 0), (5, 5), (10, 0), and (10, 10) as reinforcements are considered. In this research, molecular dynamics (MDs) method with Materials studio software is applied to examine the mechanical properties (Young's modulus) of simulated nanocomposite boxes and calculate η1 of each nanocomposite boxes. Then, it is noteworthy that by changing length (6.252, 10.584, and 21.173 nm) and width (7.137, 10.515, and 19.936) of GPLs, ��1, ��2, and ��3 approximately becomes (0.101, 0.114, and 0.124), (1.15, 1.22, and 1.26), (1.04, 1.05, and 1.07) respectively. After that efficiency parameters of SWCNTs, DWCNTs, and MWCNTs are calculated and discussed separately. Finally efficiency parameters of SWBNNTs and DWBNNTs with different chiralities by PMMA as matrix are determined by MD and discussed separately. It is known that the accurate efficiency parameters helps a lot to calculate the properties of nanocomposite analytically. In particular, the obtained results from this research can be used for analytical work based on the extended rule of mixture (ERM) in bending, buckling and vibration analysis of structure in future study.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2007년도 춘계학술대회A
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• pp.332-336
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• 2007

Temperature is an essential process variable in nanoimprint lithography(NIL) where the temperature varies between room temperature and above the glass transition temperature. To simulate NIL process, we employ both the Nose-Poincare method for temperature controlled molecular dynamics(MD) and force field for polymer material i.e. polymethyl methacrylate(PMMA), which is most widely selected as NIL resist. Nose-Poincare method, which convinces the conservation of Hamiltonian structure and time-reversal symmetry, overcomes the drawbacks inherent in the conventional methods such as Nose thermostat and Nose-Hoover thermostat. Thus, this method exhibits enhanced numerical stability even when the temperature fluctuation is large. To describe PMMA, we adopt the force field which account for bond stretch, bending, torsion, inversion, partial charge, and van der Waals energy.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2007년도 추계학술대회 논문집
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• pp.63-64
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• 2007

Polystyrene-block-polymethyl methacrylate (PS-b-PMMA) can pattern nanoscale structures over large areas. However these patterns have a short-range order. These short-range order limits their utility in some applications. Consequently, we have to overcome this limitation of block-copolymer. In this study we added a electrical field to the standard block-copolymer patterning method for long-range ordered arrays of nanostructures. This method is conformed by annealing a block copolymer with applied voltages. It is very simple method that do not have any additional hour. In this reason it can be applied easily for other nanostructure fabrications. This method opens up a new route to the controlled phase separation of block copolymers with precise place of the nanostructures.

• Journal of Electrical Engineering and Technology
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• 제4권1호
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• pp.118-122
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• 2009

Organic thin film transistors with a pentacene active layer and various polymer gate insulators were fabricated and their performances were investigated. Characteristics of pentacene thin film transistors on different polymer substrates were investigated using an atomic force microscope (AFM) and x-ray diffraction (XRD). The pentacene thin films were deposited by thermal evaporation on the gate insulators of various polymers. Hexamethyldisilazane (HMDS), polyvinyl acetate (PVA) and polymethyl methacrylate (PMMA) were fabricated as the gate insulator where a pentacene layer was deposited at 40, 55, 70, 85, 100 oC. Pentacene thin films on PMMA showed the largest grain size and least trap concentration. In addition, pentacene TFTs of top-contact geometry are compared with PMMA and $SiO_2$ as gate insulators, respectively. We also fabricated pentacene TFT with Poly (3, 4-ethylenedioxythiophene)-Polysturene Sulfonate (PEDOT:PSS) electrode by inkjet printing method. The physical and electrical characteristics of each gate insulator were tested and analyzed by AFM and I-V measurement. It was found that the performance of TFT was mainly determined by morphology of pentacene rather than the physical or chemical structure of the polymer gate insulator

• Tribology and Lubricants
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• 제39권4호
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• pp.148-153
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• 2023

Laser surface dimple patterning is a method of laser surface texturing to reduce lubrication sliding friction. The dimple pattern improves friction properties by reserving lubricant and trapping worn particles. This surface texturing technology can reduce coefficients of friction and extend the service life by applying a uniform load to the surface of the material. This study investigates the friction properties using PMMA, a highly compatible polymer material, as a specimen. We observe the friction properties of untextured specimens by processing specimens with dimple pattern densities of 5 and 10 on the surface area using laser. Dimple pattern density affects the coefficient of friction. We present the following friction property results using a pin-on-disc sliding friction test under saline lubrication. The coefficients of friction for the dimple patterned specimens are lower than those for the untextured specimens. As the normal load and sliding speed increase, the coefficients of friction of the dimple pattern specimens decrease differently from those of the untextured specimens. The specimen with a dimple pattern density of 5 at a normal load of 24.5 N and a sliding speed of 0.22 m/s has the best friction properties. Notably, different friction properties are exhibited depending on the dimple pattern densities.

• 대한환경공학회지
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• 제35권8호
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• pp.592-597
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• 2013

방음패널의 차음특성은 재료의 면밀도와 소음의 주파수와 높은 상관관계가 있으므로 방음패널의 두께 및 재료의 선택에 있어 실제 도로소음의 특성을 반영하는 것은 매우 중요하다. 본 연구에서는 재료의 경량 및 시공측면에서 수요가 증가하고 있는 플라스틱 소재 중 방음패널로 활용 가능한 소재를 선정하여 도로교통 소음의 주파수에 따른 차음특성을 평가하였다. 대상 패널은 물리적 특성을 조사하여 효율성 및 경제성 평가를 통해 polypropylene (PP)과 high-density polyethylene (HDPE)를 선정하였고 현재 방음패널의 재료로 사용되고 있는 polycarbonate (PC)와 polymethyl methacrylate (PMMA)와의 재료 및 두께에 따른 차음특성을 비교하였다. 그 결과 방음패널의 차음특성은 재료의 면밀도에 비례하여 PC, PMMA, HDPE, 그리고 PP순으로 높은 투과손실치를 나타내었다. 두께별 차음특성의 경우, 방음패널 두께에 비례하여 투과손실이 증가하나 일치효과로 인해 투과손실이 감소하는 주파수가 낮아짐을 확인할 수 있었다. 결론적으로, 저감하고자 하는 소음의 주파수대역을 먼저 파악하고 방음패널의 재질과 두께에 따른 주파수별 차음특성을 파악하여 적용한다면 효과적으로 소음을 저감할 수 있을 것으로 판단된다.