• Title/Summary/Keyword: Polymeric film

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Waterborne Core-shell Pressure Sensitive Adhesive (PSA) Based on Polymeric Nano-dispersant (고분자 분산제를 이용한 Core-shell 수성 감압점착제)

  • Lee, Jin-Kyoung;Chin, In-Joo
    • Journal of Adhesion and Interface
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    • v.17 no.3
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    • pp.89-95
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    • 2016
  • An environmentally friendly water-based pressure sensitive adhesive (PSA) was designed in an attempt to replace the solvent-based adhesive for dry lamination used in flexible food packaging films. Instead of using a low molecular weight surfactant, which may have variable material properties, a high molecular weight dispersant was used for emulsification. A polymeric nano-dispersant (PND) was synthesized using solution polymerization, and it was used as a micelle seed in the surfactant, resulting in the synthesis of a core/shell grafted acrylic adhesive. The shell and core exhibited different $T_g$ values, so that the initial adhesion strength and holding power were complemented by the film's flexibility, which is required to provide good adhesion of thin films. Results showed that the PSA designed in this study using the PND instead of traditional low molecular weight surfactant had adhesive properties applicable to the flexible packaging with appropriate tack.

Humidity Dependence of the Residual Stress of Diamond-like Carbon Film (습도에 따른 다이아몬드성 카본필름의 잔류응력 변화에 대한 연구)

  • Lee Young-Jin;Kim Tae-Young;Lee Kwang-Ryeol;Yang In-Sang
    • Journal of the Korean Vacuum Society
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    • v.13 no.4
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    • pp.157-163
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    • 2004
  • Dependence of residual compressive stress of diamond-like carbon (DLC) films on relative humidity was investigated. Polymeric, graphitic and diamond-like carbon films were prepared by r.f.-PACVD using methane or benzene with the negative self bias voltage of the substrate ranging from -100 to -800 V. In-situ measurements of the residual stress were carried out in an environment chamber where the relative humidity was varied from 10% to 90%. In dense DLC film of high residual compressive stress and hardness, we could not observe any change in the residual compressive stress with relative humidity. However, in the cases of graphitic and polymeric DLC films, abrupt change in the residual stress occurred by changing the relative humidity. The quantity of the stress change was inversely proportional to the film thickness, which means that the stress change with humidity is not due to the penetration of the water molecule into the film structure, but due to surface interaction between water molecules and film surface.

Crystallization of Yttria-Stabilized-Zirconia Film by Sol-Gel Process (졸-겔법에 의한 이트리안 안정화 지프코니아박막의 결정화)

  • 서원찬;조차제;윤영섭;황운석
    • Journal of the Korean institute of surface engineering
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    • v.30 no.3
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    • pp.183-190
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    • 1997
  • Fabrication and crystallization characteristics of yttria($T_2O_3$) stabilized zirconia(YSZ) thin film by sol-gel process were studied. YSZ sol was synthesized with zirconium n-propoxide($Zr(OC_3H_7)_4)$) and yttrium nitrate pentahydrate ($Y(NO_3)_3.5H_2O$). YSZ film was prepared by depositing the polymeric sol on porous $Al_2O_3$ substrate by spin-coating, and the film characteristics were investigated by FRIR, TG-DTA, XRD, DSC, optical microscopy and SEM. The film topology was uniform and cracks were not found. It was found that the annealing temperature and the concentration of stabilizer affect the crystallization of YSZ film. The YSZ film began to crystallize from amorphous to tetragonal phase at 40$0^{\circ}C$, and it was not converted to cubic structure until $1100^{\circ}C$. It seemed that the grains were formed over $700^{\circ}C$and the average grain size was obtained about 0.2$\mu\textrm{m}$.

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Viscoelastic Analysis of Osmotic Blistering Behavior of Coating Film

  • Lee, Sang Soon;Park, Myung Kyu
    • Corrosion Science and Technology
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    • v.8 no.1
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    • pp.11-14
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    • 2009
  • The osmotic blistering behavior of polymeric coating film which is in contact with an aqueous environment has been investigated. In this study, the coating film has been assumed to be linearly viscoelastic. Interfacial stresses induced in a laminate model consisting of the viscoelastic film and the elastic substrate as the film absorbs moisture from the ambient environment have been investigated using the time-domain boundary element method. The overall stress intensity factor for interfacial cracks subjected to a uniform osmotic pressure has been computed using the tractions at the crack tip node. The magnitude of stress intensity factors decreases with time due to viscoelastic relaxation, but remains constant at large times.

Recent Advances in Scanning Acoustic Microscopy for Adhesion Evaluation of Thin Films

  • Ju, Hyeong-Sick;Tittmann, Bernhard R.
    • Journal of the Korean Society for Nondestructive Testing
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    • v.29 no.6
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    • pp.534-549
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    • 2009
  • As the thin film technology has emerged in various fields, adhesion of the film interface becomes an important issue in terms of the longevity and durability of thin film devices. Diverse nondestructive methods utilizing acoustic techniques have been developed to assess the interfacial integrity. As an effective technique based on the ultrasonic wave focusing and the surface acoustic wave(SAW) generation, scanning acoustic microscopy(SAM) has been investigated for adhesion evaluation. Visualization of film microstructures and quantification of adhesion weakness levels by SAW dispersion are the recent achievements of SAM. To overcome the limitations in the theoretical dispersion model only suitable for perfectly elastic and isotropic materials, a new model has been more recently developed in consideration of film anisotropy and viscoelasticity and applied to the adhesion evaluation of polymeric films fabricated on semiconductive wafers.

Porous Ceramic Fibers: Materials and Applications

  • Kim, Il-Du
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.10a
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    • pp.4-4
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    • 2011
  • Extensive research efforts are directed toward the development of highly sensitive gas sensors using novel nanostructured materials. Among the different strategies for producing sensor devices based on nanosized building blocks, polymeric fiber templating approach which is combined by chemical and physical synthesis routes was attracted much attention. This unique morphology increases the surface area and reduces the interfacial area between film and substrate. Consequently, the surface activity is markedly enhanced while deleterious interfacial effects between film and substrate are significantly reduced. Both effects are highly advantageous for gas sensing applications. In this presentation, facile synthesis of hollow and porous metal oxide nanostructures and their applications in chemical sensors will be discussed.

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Frictional and Wear Characteristics of Non-Asbestos Materials at Elevated Temperature (고온에서 비석면 마찰재의 마찰$cdot$마모특성)

  • 안병길;최웅수;권오관
    • Tribology and Lubricants
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    • v.7 no.2
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    • pp.61-66
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    • 1991
  • The frictional and wear characteristics of non-asbestos friction materials made of four different fibers (carbon, aramid, ceramic and glass) have been investigated at elevated temperature using High Frequency Friction Tester. On the basis of the experimental results, friction and wear phenomena of four different non-asbestos fibers were caused by lattice layer film of carbon, polymeric transfer film of aramid, abrasion of ceramic and adhesion of glass fiber under each contact junction. The surface analysis of the worn specimens and counter parts after tests were observed using Scanning Electron Microscope and Optical Microscope.

ZnO Thin Film Transistor Prepared from ALD with an Organic Gate Dielectric

  • Choi, Woon-Seop
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.543-545
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    • 2009
  • With injection-type source delivery system of atomic layer deposition (ALD), bottom-contact and bottom-gate thin-film transistors (TFTs) were fabricated with a poly-4-vinyphenol polymeric dielectric for the first time. The properties of the ZnO TFT were greatly influenced by the device structure and the process conditions. The zinc oxide TFTs exhibited a channel mobility of 0.43 $cm^2$/Vs, a threshold voltage of 0.85 V, a subthreshold slope of 3.30 V/dec, and an on-to-off current ratio of above $10^6$ with solid saturation.

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Effects of processing temperature and optical anisotropy of a polymeric insulator on organic thin-film transistors

  • Bae, Jin-Hyuk;Kim, Won-Ho;Na, Jun-Hee;Lee, Sin-Doo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1107-1110
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    • 2006
  • We investigate the effect of processing temperature of gate insulator and optical anisotropy on organic thin-film transistors (OTFTs). The insulator film which was processed lower temperature than solvent boiling temperature can lead more aligned pentacne molecules compare to higher processed insulator film. It finally gives rise to the big increase of carrier mobility in OTFTs, although there are little difference at the seriously affecting properties to device performance, for example roughness of gate insulator film.

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Fabrication of a Polymeric Film with Nanofiber-based Porous Window and Its Application to Co-culture (섬유 기반의 다공성 윈도우를 가지는 박막 제작 및 공배양에의 활용)

  • Jeong, Young Hun;Lee, Jongwan;Jin, Songwan
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.13 no.2
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    • pp.21-27
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    • 2014
  • Recently, various biochip environments have been presented. In this study, a novel transparent film with porous membrane windows, which is an essential component in a co-cultured biochip environment, is fabricated using spin-coating, 3D printing, and electrospinning processes. In detail, a transparent polystyrene film was fabricated by means of the spin-coating process followed bywindow cutting, after which apolycaprolactone-chloroform solution was deposited along the window edge to introduce an adhesion layer between the PS film and the PCL nanofibers. Nanofibers were electrospun into the window region using a direct-write electrospinning method. Consequently, it was demonstrated that the fabricated window film could be used in a co-culture biochip environment.