• Title/Summary/Keyword: Polymeric effect

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Effect of Powder Synthesis Method on the Microstructure of Oxide Dispersion Strengthened Fe-Cr-Al Based Alloys (Fe-Cr-Al 기 산화물 분산강화 합금의 미세조직에 미치는 분말제조 공정 영향)

  • Park, Sung Hyun;Oh, Sung-Tag
    • Korean Journal of Materials Research
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    • v.27 no.9
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    • pp.507-511
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    • 2017
  • An optimum route to fabricate oxide dispersion strengthened ferritic superalloy with desired microstructure was investigated. Two methods of high energy ball milling or polymeric additive solution route for developing a uniform dispersion of $Y_2O_3$ particles in Fe-Cr-Al-Ti alloy powders were compared on the basis of the resulting microstructures. Microstructural observation revealed that the crystalline size of Fe decreased with increases in milling time, to values of about 15-20 nm, and that an FeCr alloy phase was formed. SEM and TEM analyses of the alloy powders fabricated by solution route using yttrium nitrate and polyvinyl alcohol showed that the nano-sized Y-oxide particles were well distributed in the Fe based alloy powders. The prepared powders were sintered at 1000 and $1100^{\circ}C$ for 30 min in vacuum. The sintered specimen with heat treatment before spark plasma sintering at $1100^{\circ}C$ showed a more homogeneous microstructure. In the case of sintering at $1100^{\circ}C$, the alloys exhibited densified microstructure and the formation of large reaction phases due to oxidation of Al.

Effect of solids retention time on membrane fouling in membrane bioreactors at a constant mixed liquor suspended solids concentration

  • Hao, L.;Liss, S.N.;Liao, B.Q.
    • Membrane and Water Treatment
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    • v.8 no.4
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    • pp.337-353
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    • 2017
  • Membrane fouling at different solids retention times (SRT) (7, 12 and 20 days) was studied under well-controlled conditions in a laboratory-scale aerobic submerged membrane bioreactor under constant biomass concentration using a synthetic high strength wastewater. An increase in SRT was found to improve membrane performance and this correlated to changes in the total production of bound extracellular polymeric substances (EPS), and the composition and properties of bound EPS using X-ray photoelectron spectroscopy (XPS) and Fourier transform-infrared spectroscopy (FTIR) and floc sizes. A larger amount of total bound EPS was found at the lowest SRT (7 days) tested but the ratio of proteins (PN) to carbohydrates (CH) in bound EPS increased with an increase in SRT. Similarly, the quantity of soluble microbial products (SMP) decreased with an increase in SRT and the SMP PN/CH ratio increased with an increase in SRT. SMP concentrations positively correlated to the percentage of membrane pore blocking resistance. The quantity of total bound EPS and total SMP positively corresponded to the membrane fouling rate, while the PN/CH ratio in the bound EPS and SMP negatively correlated to the membrane fouling rate. The results show that both the quantity and composition of bound EPS and SMP and floc sizes are important in controlling membrane fouling.

Polymer-waveguide Bragg-grating Devices Fabricated Using Phase-mask Lithography

  • Park, Tae-Hyun;Kim, Sung-Moon;Oh, Min-Cheol
    • Current Optics and Photonics
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    • v.3 no.5
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    • pp.401-407
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    • 2019
  • Polymeric optical waveguide devices with Bragg gratings have been investigated, for implementing tunable lasers and wavelength filters used in wavelength-division-multiplexed optical communication systems. Owing to the excellent thermo-optic effect of these polymers, wavelength tuning is possible over a wide range, which is difficult to achieve using other optical materials. In this study the phase-mask technology, which has advantages over the conventional interferometeric method, was introduced to facilitate the fabrication of Bragg gratings in polymeric optical waveguide devices. An optical setup capable of fabricating multiple Bragg gratings simultaneously on a 4-inch silicon wafer was constructed, using a 442-nm laser and phase mask. During fabrication, some of the diffracted light in the phase mask was totally reflected inside the mask, which affected the quality of the Bragg grating adversely, so experiments were conducted to solve this issue. To verify grating uniformity, two types of wavelength-filtering devices were fabricated using the phase-mask lithography, and their reflection and transmission spectra were measured. From the results, we confirmed that the phase-mask method provides good uniformity, and may be applied for mass production of polymer Bragg-grating waveguide devices.

Effects on the Stability of Aerobic Granular Sludge (AGS) at Different Carbon/Nitrogen Ratio (C/N비 변화가 호기성 그래뉼 슬러지의 안정성에 미치는 영향)

  • Kim, Hyun-Gu;Ahn, Dae-Hee
    • Journal of Environmental Science International
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    • v.28 no.9
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    • pp.719-727
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    • 2019
  • In this study, the effect on the stability of Aerobic Granular Sludge (AGS) with different Carbon/Nitrogen (C/N) ratios was investigated. The C/N ratios were controlled to 10.0, 7.5, 5.0, and 2.5 using the sequencing batch reactor, and the results showed that the removal efficiency of organic matter and total nitrogen decreased simultaneously with the decrease of C/N ratio. The removal efficiency of organic matter and total nitrogen at C/N ratio of 2.5 was 70.7% and 52.3% respectively. In addition, the AGS/mixed liquor suspended solids (MLSS) ratio showed a tendency to decrease from 85.7% to 73.7%, while the sludge volume index showed a tendency to increase from 82 mL/g to 102 mL/g as the C/N ratio decreased. At the same time, the apparent deviation of polysaccharide (PS) content in extracellular polymeric substances was observed, and polysaccharides/protein (PS/PN) ratio decreased from 0.62 to 0.31 as the C/N ratio decreased. Optical microscope observations showed that the reduction in C/N ratio caused the growth of filamentous bacteria and significantly affected the stability of AGS.

Preparation and Properties of Polymer PTC Composites for Process Safety (공정안전용 Polymer PTC 소재의 제조 및 특성)

  • 강영구;조명호
    • Journal of the Korean Society of Safety
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    • v.18 no.3
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    • pp.101-108
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    • 2003
  • Polymeric positive temperature coefficient(PTC) composites have been prepared by incorporating carbon black(CB) into high density polyethylene(HDPE), polyphenylene sulfide(PPS) and polybutylene terephthalate(PBT) matrices. A PTC effect was observed in the composite, caused by the large thermal expansion due to He consecutive melting of HDPE, PPS and PBT crystallites. This theory is based upon the premise that the PTC phenomenon is due to a critical separation distance between carbon particles in the polymer matrix at the higher temperature. The influence of PTC characteristics of the PPS/CB composite can be explained by DSC result. HDPE, one of prepared composition, exhibit the higher performance PTC behavior that decreaseing of negative temperature coefficient(NTC) effect and improved reproducibility by chemically crosslinking. Also, PBT/CB and PPS/CB composites exhibit the higher PTC peack temperature than HDPE/CB PTC composite, individually $200^{\circ}C$ and $230^{\circ}C$. These PTC composite put to good use in a number of safety application, such as self$.$controlled heater, over-current protectors, auto resettable switch, high temperature proctection sensor, etc.

The Effect of Back Electrode on the Surface Discharge of polymeric Materials (고분자절연재료에서 배후전극이 연면방전에 미치는 영향)

  • 조기선;신태현;김영조
    • Electrical & Electronic Materials
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    • v.3 no.1
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    • pp.29-35
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    • 1990
  • 원통형 및 평판형 유전체에 임펄스전압을 인가하는 경우 나타나는 50%의 Flash over전압 (F.O.V)특성 및 Lichtenberg 도형에 미치는 배후전극의 영향을 관측하였다. F.O.V는 배후전극이 있는 경우가 없을 때보다 인가전압을 저하시킬 수 있었고 Lichtenberg도형에서 방전로의 진전상태는 배후전극의 존재로 인하여 크게 신장함을 알았다.

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Interfacial Effects in Filled and Reinforced Polymeric Composites

  • Xie, Hengkun
    • Electrical & Electronic Materials
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    • v.11 no.10
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    • pp.24-31
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    • 1998
  • Interfacial effect in polymetric composites have been studied extensively. This report deals mainly with the effects of interfacial space charge and interface structure. A model for the dynamic process of interfacial space charge accumulation is proposed. The new model might interpret some interface phenomena which is difficult to be explained in terms of traditional Maxwell-Wagner theory. An interface structure is also presented, by which the importance of surface treatment of glass Fiber for improving the properties of FRP could be well understood.

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Effect of Annealing and Polymeric Additives on Permeation Properties of Asymmetric Polyacrylonitrile Membranes

  • Yoon, Joon-Ki;Bumsuk Jung;Rhee, Hee-Woo;Kang, Yong-Soo
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05a
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    • pp.161-165
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    • 2004
  • Since Loeb and Souriajan first introduced phase inversion method [1], much investigation has been made for understanding the mechanism of formation of asymmetric membranes. Phase inversion is the most extensively used technique for the preparation of asymmetric membranes, which is that cast solution film on a substrate is immersed and is precipitated in water bath.(omitted)

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Changes of serum immunoglobulin in the subacute oral administration of Mancozeb

  • Chung, Ae-Hee;Pyo, Myoung-Yun
    • Proceedings of the PSK Conference
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    • 2002.10a
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    • pp.280.1-280.1
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    • 2002
  • Mancozeb. a polymeric complex of zinc and manganese salts of ethylean bisdithiocarbamate(EBDC). is used widely in agriculture as fungicides. and herbicides. Macozeb has been reported to induce teratogenic and carcinogenic effect. But the immunomodulating effects of Mancozeb exposure have not been systemically evaluated. The purpose of this study was to investigate the effects of Mancozeb on immunoglobulin production. (omitted)

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A Study on the Stabilization of Monomeric MDI and Purification of Crude MDI (Crude MDI의 정제 및 Monomeric MDI의 안정화에 관한 연구)

  • Jung, Jong-Won;Kim, Young-Chul;Park, Nam-Cook
    • Applied Chemistry for Engineering
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    • v.7 no.3
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    • pp.588-596
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    • 1996
  • The optimum conditions of the 1st and 2nd distillation had been investigated to obtaine a high quality monomeric MDI and fire reactive polymeric MDI by purification of crude MDI. Effect of additives on the monomeric MDI's color change, dimerization and the reactivity of polymeric MDI with standard polyol system has been tested. When the monomeric MDI yield is approximately 32%, 4,4'-MDI content is above 98% in the monomeric MDI at the 1st distillation. When the separation ratio of initial portion and residue percentage, reflux ratio are set at respectively, approximately 20wt%, 9wt%, above 2 in order to minimize the content of 2,4'-MDI in monomeric MDI, the freezing point of final distilled monomeric MDI is above $38.4^{\circ}C$. Since the monomeric MDI is inherently unstable in the room condition, monomeric MDI easily changes it's color and conducts self-polymerization reaction. To increase the stability of monomeric MDI, the composition of antioxidant, which is composed of phenolic 1st antioxidant, phosphorus 2nd antioxidant, UV absorbent and Hindered amine light stabilizer are used, and benzoyl chloride as antipolymerization agent test are that APHA color is less than 20, dimer content is remained less than 0.36wt% after 45 days storage of monomeric MDI.

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