• Title/Summary/Keyword: Polymeric Film

검색결과 213건 처리시간 0.031초

플렉시블한 폴리머 기판위에 증착된 ZnO:Al 투명전도막의 전기 및 광학적 특성 (Electrical and optical properties of ZnO:Al transparent conducting films deposited on flexible polymeric substrate)

  • ;박병욱;성열문;곽동주
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2008년도 제39회 하계학술대회
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    • pp.1262-1263
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    • 2008
  • Recently film-typed dye sensitized solar cell(DSC) attracts much attention with increasing applications for its flexibility and transparency. The ZnO:Al thin film, which serves mainly as transparent conducting electrode, Aluminium-doped zinc oxide(ZnO:Al) thin film has emerged as one of the most promising transparent conducting films since it is inexpensive, mechanically stable, and highly resistant to deoxidation. In this paper ZnO:Al thin film was deposited on the polyethylene terephthalate(PET) substrate by the capacitively coupled r. f. magnetron sputtering method. The effects of gas pressure and r. f. discharge power on the morphological, electrical and optical properties of ZnO:Al thin film were studied. Especially the variation in substrate thickness after sputtering and surface morphology of the substrate were investigated and clarified. The results showed that the film deposited on the PET substrate at r. f. discharge power of 180 W showed the minimum resistivity of about $1.5{\times}10^{-3}{\Omega}-cm$ and a transmittance of about 93%.

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유기발광소자의 광추출 향상을 위한 미세 반구형 유연 필름 연구 (Development of Micro-hemisphere Flexible PDMS Film for Enhancing Light Extraction in Organic Light-emitting Devices)

  • 백동현;배은정;맹형규;신지수;박영욱
    • 반도체디스플레이기술학회지
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    • 제21권4호
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    • pp.1-5
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    • 2022
  • We presented a micro hemi-sphere structure flexible film to improve the external quantum efficiency (EQE) in OLEDs. The micro hemi-sphere flexible film was fabricated with breath figure (BF) method and replica process. At 45 mg/mL of concentration, the size of the hemi-spheres was approximately 6.2 ㎛ were obtained which are the most circular shape. So, it was possible to yield the best performance with an improvement of 33 % in the EQE and the widest viewing angle ranging from 0° to 70°. As a result, the hemi-sphere film's size and distribution seem to play important roles in enhancing the EQE in OLEDs. Furthermore, the flexible hemi-sphere film based on polymeric materials could offer an effective, large-scale, mass-produced product and a simple process and approach to achieve high efficiency in flexible OLEDs.

졸-겔법을 이용한 고체산화물연료전지의 전해질 박막 제조 및 가스 투과도 (Preparation of Thin Film Electrolyte for Solid Oxide Fuel Cell by Sol-Gel Method and Its Gas Permeability)

  • 손희정;이혜종;임탁형;송락현;백동현;신동열;현상훈
    • 한국세라믹학회지
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    • 제42권12호
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    • pp.827-832
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    • 2005
  • In this study, thin electrolyte layer was prepared by 8YSZ ($8mol\%$ Yttria-Stabilized Zirconia) slurry dip and sol coating onto the porous anode support in order to reduce ohmic resistance. 8YSZ polymeric sol was prepared from inorganic salt of nitrate and XRF results of xerogel powder exhibited similar results $(99.2\pm1wt\%)$ compared with standard sample (TZ-8YS, Tosoh Co.). The dense and thin YSZ film with $1{\mu}m$ thickness was synthesized by coating of 0.7M YSZ sol followed by heat-treatment at $600^{\circ}C$ for 1 h. Thin film electrolyte sintered at $1400^{\circ}C$ showed no gas leakage at the differential pressure condition of 3 atm.

Effect of Hydroxyl Ethyl Cellulose Concentration in Colloidal Silica Slurry on Surface Roughness for Poly-Si Chemical Mechanical Polishing

  • Hwang, Hee-Sub;Cui, Hao;Park, Jin-Hyung;Paik, Ungyu;Park, Jea-Gun
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.545-545
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    • 2008
  • Poly-Si is an essential material for floating gate in NAND Flash memory. To fabricate this material within region of floating gate, chemical mechanical polishing (CMP) is commonly used process for manufacturing NAND flash memory. We use colloidal silica abrasive with alkaline agent, polymeric additive and organic surfactant to obtain high Poly-Si to SiO2 film selectivity and reduce surface defect in Poly-Si CMP. We already studied about the effects of alkaline agent and polymeric additive. But the effect of organic surfactant in Poly-Si CMP is not clearly defined. So we will examine the function of organic surfactant in Poly-Si CMP with concentration separation test. We expect that surface roughness will be improved with the addition of organic surfactant as the case of wafering CMP. Poly-Si wafer are deposited by low pressure chemical vapor deposition (LPCVD) and oxide film are prepared by the method of plasma-enhanced tetra ethyl ortho silicate (PETEOS). The polishing test will be performed by a Strasbaugh 6EC polisher with an IC1000/Suba IV stacked pad and the pad will be conditioned by ex situ diamond disk. And the thickness difference of wafer between before and after polishing test will be measured by Ellipsometer and Nanospec. The roughness of Poly-Si film will be analyzed by atomic force microscope.

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기상 UV 그라프트 반응에 의한 고분자 필름의 표면 개질 (Surface Modification of Polymer Films by Vapor Phase Photografting of Functional Monomers)

  • 오승희;오세행;이진호
    • 접착 및 계면
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    • 제1권1호
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    • pp.23-29
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    • 2000
  • 소수성 고분자 재료 표면의 친수화 처리 및 기능성 작용기 도입은 재료의 응용성을 상당히 확장할 수가 있기 때문에 중요성이 인지되고 있다. 본 연구에서는 기상 UV 그라프트 반응(vapor phase photografting)에 의해 서로 다른 이온성을 가지는 비닐계 단량체들을 PE 표면에 도입하여 표면 친수성을 향상시켰다. 이를 위해 acrylic acid(음이온성), acrylamide(중성), allylalcohol(중성), allylamine(양이온성) N,N-dimethyl aminopropyl acrylamide(양이온성) 등 서로 다른 기능성 작용기를 갖는 친수성 단량체들을 본 실험실에서 고안한 기상 UV 그라프트 반응장치를 이용하여 기체상태에서 PE 표면에 도입하였다. 이들 단량체들이 도입된 PE 표면을 물 접촉각 측정과 ATR-FTIR을 이용하여 분석한 결과, 각 기능성 단량체들이 효과적으로 PE 표면에 그라프트되어 표면의 친수성이 향상되었음을 확인할 수 있었다. 본 연구에 사용한 기상 UV 그라프트 반응은 고분자 표면에 다양한 작용기를 도입하여 표면을 개질할 수 있는 효과적인 방법으로 생각되어진다.

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Properties and Structure of Poly(vinyl Alcohol) Film Containing Electrolytes

  • Iwaseya, Masato;Yamaura, Kazuo;Dai, Lixing
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2003년도 The Korea-Japan Joint Symposium
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    • pp.99-99
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    • 2003
  • We have investigated the properties of poly (vinyl alcohol)-film obtained by casting from the solution PVA/electrolytes (NaCl, KCl, MgCl$_2$, CaCl$_2$)/water systems at room temperature. The removed electrolytes films have got high crystallinity as well as high draw ratio. The removed electrolytes films had layer-structure while a film without electrolytes didn't have it. A relation between draw ratio and thickness or number of layers, were recognized.

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고하중과 고속 미끄럼 베어링 시스템의 경계윤활에 대한 연구 (Study on Boundary Lubrication in the Sliding Bearing System under High Load and Speed)

  • 장시열
    • Tribology and Lubricants
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    • 제15권3호
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    • pp.248-256
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    • 1999
  • Many tribological components in automobile engine undergo high load and sliding speed with thin film thickness. The lubrication characteristics of the components are regarded as ether hydrodynamic lubrication or boundary lubrication, whereas in a working cycle they actually have both characteristics. Many modem engine lubricants have various additives for better performance which make boundary film formation even under hydrodynamic lubrication regime. Conventional Reynolds equation with the viewpoints of continuum mechanics concerns only bulk viscosity of lubricant, which means that its simulation does not give insights on boundary lubrication characteristics. However, many additives of modern engine lubricant provide mixed modes of boundary lubrication characteristics and hydrodynamic lubrication. Especially, high molecular weight polymeric viscosity index improvers form boundary film on the solid surface and cause non-Newtonian fluid effect of shear thinning. This study has performed the investigation about journal bearing system with the mixed concepts of boundary lubrication and hydrodynamic lubrication which happen concurrently in many engine components under the condition of viscosity index improver added.

폴리에틸렌글리콜이 그라프트된 폴리우레탄 막에 ${\alpha}$-아밀라제의 고정화 (Immobilization of ${\alpha}-amylase$ on Polyethylene Glycol Grafted Polyurethane Film)

  • 김성호;하정헌
    • Journal of Pharmaceutical Investigation
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    • 제21권3호
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    • pp.143-147
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    • 1991
  • ${\alpha}-amylase$ was immobilized on the surface of polyethylene glycol(M.W. 2000) grafted polyurethane film using diisocyanate in an attemp to develop enzyme immobilized polymeric materials. The surface morphology of the modified polyurethane film was examined by SEM. Effects of pH and temperature on the activity of the immobilized ${\alpha}-amylase$ were investigated. The optimal pH range of the activity was $7.0{\sim}7.5.$ The immobilized ${\alpha}-amylase$ demonstrated high thermal stability and maintained consistent activity during long-term storage.

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Uniform Grafting of Poly(1,5-dioxepan-2-one) by Surface-Initiated, Ring-Opening Polymerization

  • Yoon Kuk-Ro;Yoon Ok-Ja;Chi Young-Shik;Choi Insung-S.
    • Macromolecular Research
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    • 제14권2호
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    • pp.205-208
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    • 2006
  • A polymeric film of a biodegradable poly(1,5-dioxepan-2-one) (PDXO) was formed on a gold surface by a combination of the formation of self-assembled monolayers (SAMs) presenting hydroxyl groups and the surface-initiated, ring-opening polymerization (SI-ROP) of 1,5-dioxepan-2-one (DXO). The SI-ROP of DXO was achieved by heating a mixture of $Sn(Oct)_2$, DXO, and the SAM-coated substrate in anhydrous toluene at $55^{\circ}C$. The resulting PDXO film was quite uniform. The PDXO film was characterized by polarized infrared external reflectance spectroscopy, X-ray photoelectron spectroscopy, time-of-flight secondary ion mass spectrometry, atomic force microscopy, ellipsometry, and contact angle goniometry.

Effect of Channel Scaling on Zinc Oxide Thin-Film Transistor Prepared by Atomic Layer Deposition

  • Choi, Woon-Seop
    • Transactions on Electrical and Electronic Materials
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    • 제11권6호
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    • pp.253-256
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    • 2010
  • Different active layer thicknesses for zinc oxide (ZnO) bottom-contact thin-film transistors (TFTs) were fabricated with a poly-4-vinyphenol polymeric dielectric using injector type atomic layer deposition. The properties of the ZnO TFTs were influenced by the active thickness and width-to-length (W/L) ratio of the device. The threshold voltage of ZnO TFTs shifted positively as the active layer thickness decreased, while the subthreshold slope decreased. The W/L ratio of ZnO TFTs also affected the mobility and subthreshold slope. An optimized TFT structure exhibited an on-tooff current ratio of above 106 with solid saturation.