• 제목/요약/키워드: Polymeric Composite

검색결과 293건 처리시간 0.027초

폴리머 현수애자의 신뢰성 평가 및 복합가속열화 방법 (Reliability Evaluation Criteria and Multi-Stress Aging Test for Polymer Insulator)

  • 박효열;강동필;안명상
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 하계학술대회 논문집 Vol.5 No.1
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    • pp.469-472
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    • 2004
  • There have been numerous accelerated aging laboratory tests for evaluating suitability of polymeric materials and devices. Aging test for materials and its full scale device has been conducted, but poor correlation of aging test such as service experience were observed. Service experience plays a key role in the utility section of composite insulators. A meaningful and reliable accelerated aging test is needed for evaluating composite insulator. During the service these insulators are subjected to aging stress such as humidity, pollution, and electrical field, and erosion and tracking of the weathershed occurs. This paper presents the criteria of reliability evaluation and evaluation facilities for 22.9 kV suspension composite insulator. We adopt the criteria of reliability evaluation consist of two test methods. One is CEA tracking wheel test for examining the tracking and erosion performance of composite insulator. The other is multi-stress aging test for examining effects of environmental factors such as UV, temperature, humidity, etc on composite insulator.

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응집 영역 요소를 이용한 고분자 접착 테이프의 박리거동 모사 (Numerical Simulation of the Delamination Behavior of Polymeric Adhesive Tapes Using Cohesive Zone Element)

  • 장진혁;성민창;유웅열
    • Composites Research
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    • 제29권4호
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    • pp.203-208
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    • 2016
  • 금속/고분자 샌드위치 복합재는 경량성과 제진, 방음 등의 다기능성의 측면에서 기존의 스틸 강판을 대체할 후보 중 하나로서 연구되고 있다. 금속/고분자 복합재의 활용하기 위해서는 접착력을 바탕으로 한 박리 거동 예측이 매우 중요한 요소이다. 본 연구에서는 응집요소를 사용하여 유한요소 해석을 통해 접착제를 사용한 고분자 테이프의 박리거동 해석을 수행하였다. 응집요소의 특성은 박리시험과 역학 관계로부터 도출한 파괴인성을 통해 정의하였고 이를 해석에 적용하였다. 스틸 강판에서 고분자 테이프를 박리하는 시험을 모사하였고, 해석결과와 시험결과를 비교하여 박리 거동 모사가 가능함을 확인하였다.

Li과 B이 포함된 폴리머 전구체의 열처리에 의한 Li7La3Zr2O12 고체전해질의 소결조제 합성 (Preparation of Sintering Aid for Li7La3Zr2O12 Solid Electrolyte by Heat-treatment of Polymeric Precursors Containing Li and B)

  • 신란희;류성수
    • 한국분말재료학회지
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    • 제25권2호
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    • pp.151-157
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    • 2018
  • In this study, the compound $Li_3BO_3$ (LBO) is intended to be prepared by a polymeric complex method as a sintering aid for the densification of $Li_7La_3Zr_2O_{12}$ (LLZ) solid electrolyte. A polymeric precursor containing Li and B is heat-treated in an air atmosphere at a temperature range between $600^{\circ}C$ and $800^{\circ}C$. Instead of LBO, the compound $Li_{2+x}C_{1-x}B_xO_3$ (LCBO) is unexpectedly synthesized after a heat-treatment of $700^{\circ}C$. The effect of LCBO addition on sintering behavior and ion conductivity of LLZ is studied. It is found that the LCBO compound could lead to significant improvements in the densification and ionic conductivity of LLZ compared to pure LLZ. After sintering at $1100^{\circ}C$, the density of the LLZ-12wt%LBO composite is $3.72g/cm^3$, with a high Li-ion conductivity of $1.18{\times}10^{-4}Scm^{-1}$ at $28^{\circ}C$, while the pure LLZ specimen had a densify of $2.98g/cm^3$ and Li-ion conductivity of $5.98{\times}10^{-6}Scm^{-1}$.

Hydro-thermo-mechanical biaxial buckling analysis of sandwich micro-plate with isotropic/orthotropic cores and piezoelectric/polymeric nanocomposite face sheets based on FSDT on elastic foundations

  • Rajabi, Javad;Mohammadimehr, Mehdi
    • Steel and Composite Structures
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    • 제33권4호
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    • pp.509-523
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    • 2019
  • In the present work, the buckling analysis of micro sandwich plate with an isotropic/orthotropic cores and piezoelectric/polymeric nanocomposite face sheets is studied. In this research, two cases for core of micro sandwich plate is considered that involve five isotropic Devineycell materials (H30, H45, H60, H100 and H200) and an orthotropic material also two cases for facesheets of micro sandwich plate is illustrated that include piezoelectric layers reinforced by carbon and boron-nitride nanotubes and polymeric matrix reinforced by carbon nanotubes under temperature-dependent and hydro material properties on the elastic foundations. The first order shear deformation theory (FSDT) is adopted to model micro sandwich plate and to apply size dependent effects from modified strain gradient theory. The governing equations are derived using the minimum total potential energy principle and then solved by analytical method. Also, the effects of different parameters such as size dependent, side ratio, volume fraction, various material properties for cores and facesheets and temperature and humidity changes on the dimensionless critical buckling load are investigated. It is shown from the results that the dimensionless critical buckling load for boron nitride nanotube is lower than that of for carbon nanotube. It is illustrated that the dimensionless critical buckling load for Devineycell H200 is highest and lowest for H30. Also, the obtained results for micro sandwich plate with piezoelectric facesheets reinforced by carbon nanotubes (case b) is higher than other states (cases a and c).The results of this research can be used in aircraft, automotive, shipbuilding industries and biomedicine.

Antibacterial activity of florfenicol composite nanogels against Staphylococcus aureus small colony variants

  • Liu, Jinhuan;Ju, Mujie;Wu, Yifei;Leng, Nannan;Algharib, Samah Attia;Luo, Wanhe
    • Journal of Veterinary Science
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    • 제23권5호
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    • pp.78.1-78.13
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    • 2022
  • Background: Florfenicol might be ineffective for treating Staphylococcus aureus small colony variants (SCVs) mastitis. Objectives: In this study, florfenicol-loaded chitosan (CS)-sodium tripolyphosphate (TPP) composite nanogels were prepared to allow targeted delivery to SCV infected sites. Methods: The formulation screening, the characteristics, in vitro release, antibacterial activity, therapeutic efficacy, and biosafety of the florfenicol composite nanogels were studied. Results: The optimized formulation was obtained when the CS and TPP were 10 and 5 mg/mL, respectively. The encapsulation efficiency, loading capacity, size, polydispersity index, and zeta potential of the optimized florfenicol composite nanogels were 87.3% ± 2.7%, 5.8% ± 1.4%, 280.3 ± 1.5 nm, 0.15 ± 0.03, and 36.3 ± 1.4 mv, respectively. Optical and scanning electron microscopy showed that spherical particles with a relatively uniform distribution and drugs might be incorporated in cross-linked polymeric networks. The in vitro release study showed that the florfenicol composite nanogels exhibited a biphasic pattern with the sustained release of 72.2% ± 1.8% at 48 h in pH 5.5 phosphate-buffered saline. The minimal inhibitory concentrations of commercial florfenicol solution and florfenicol composite nanogels against SCVs were 1 and 0.25 ㎍/mL, respectively. The time-killing curves and live-dead bacterial staining showed that the florfenicol composite nanogels were concentration-dependent. Furthermore, the florfenicol composite nanogels displayed good therapeutic efficacy against SCVs mastitis. Biological safety studies showed that the florfenicol composite nanogels might be a biocompatible preparation because of their non-toxic effects on the renal tissue and liver. Conclusions: Florfenicol composite nanogels might improve the treatment of SCV infections.

Enhanced antibacterial activity of tilmicosin against Staphylococcus aureus small colony variants by chitosan oligosaccharide-sodium carboxymethyl cellulose composite nanogels

  • Luo, Wanhe;Liu, Jinhuan;Zhang, Shanling;Song, Wei;Algharib, Samah Attia;Chen, Wei
    • Journal of Veterinary Science
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    • 제23권1호
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    • pp.1.1-1.11
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    • 2022
  • Background: The poor bioadhesion capacity of tilmicosin resulting in treatment failure for Staphylococcus aureus small colony variants (SASCVs) mastitis. Objectives: This study aimed to increase the bioadhesion capacity of tilmicosin for the SASCVs strain and improve the antibacterial effect of tilmicosin against cow mastitis caused by the SASCVs strain. Methods: Tilmicosin-loaded chitosan oligosaccharide (COS)-sodium carboxymethyl cellulose (CMC) composite nanogels were formulated by an electrostatic interaction between COS (positive charge) and CMC (negative charge) using sodium tripolyphosphate (TPP) (ionic crosslinkers). The formation mechanism, structural characteristics, bioadhesion, and antibacterial activity of tilmicosin composite nanogels were studied systematically. Results: The optimized formulation was comprised of 50 mg/mL (COS), 32 mg/mL (CMC), and 0.25 mg/mL (TPP). The size, encapsulation efficiency, loading capacity, polydispersity index, and zeta potential of the optimized tilmicosin composite nanogels were 357.4 ± 2.6 nm, 65.4 ± 0.4%, 21.9 ± 0.4%, 0.11 ± 0.01, and -37.1 ± 0.4 mV, respectively; the sedimentation rate was one. Scanning electron microscopy showed that tilmicosin might be incorporated in nano-sized crosslinked polymeric networks. Moreover, adhesive studies suggested that tilmicosin composite nanogels could enhance the bioadhesion capacity of tilmicosin for the SASCVs strain. The inhibition zone of native tilmicosin, tilmicosin standard, and tilmicosin composite nanogels were 2.13 ± 0.07, 3.35 ± 0.11, and 1.46 ± 0.04 cm, respectively. The minimum inhibitory concentration of native tilmicosin, tilmicosin standard, and tilmicosin composite nanogels against the SASCVs strain were 2, 1, and 1 ㎍/mL, respectively. The in vitro time-killing curves showed that the tilmicosin composite nanogels increased the antibacterial activity against the SASCVs strain. Conclusions: This study provides a potential strategy for developing tilmicosin composite nanogels to treat cow mastitis caused by the SASCVs strain.

탄성지지된 3경간 연속 복합슬래브교량의 간단한 진동해석 (Simple Method of Vibration Analysis of Three Span Continuous Composite Slab Bridges with Elastic Intermediate Supports)

  • 한봉구;김덕현
    • 한국강구조학회 논문집
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    • 제17권3호통권76호
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    • pp.317-324
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    • 2005
  • 본 연구에서는 3경간연속 탄성지지된 복합슬래브교량을 특별직교이방성 판이론을 응용하여 해석하였다. 불균등단면이나 임의의 경계조건을 가진 보나 타워구조물의 고유진동수를 계산하는 방법을 탄성지지된 3경간 연속 복합슬래브교량에 적용하여 연구하였다. 슬래브 상판은 특별직교이방성 판으로 취급하였다. 진동해석에 필요한 변위의 영향계수는 여러 가지 방법으로 구할 수 있으나 본 논문에서는 유한차분법을 사용하였다. 또한 휨강성에 대한 영향과 기초의 탄성계수에 대한 영향에 대하여 연구하였다.

하이브리드 FRP-Concrete 복합말뚝의 연결부의 개발 (Development of Hybrid FRP-Concrete Composite Pile Connection)

  • 이형규;박준석
    • 복합신소재구조학회 논문집
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    • 제5권4호
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    • pp.52-57
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    • 2014
  • Due to the advantageous mechanical properties of the fiber reinforced polymeric plastics(FRP), their application in the construction industries is ever increasing trend, as a substitute of structural steel which is highly vulnerable under hazardous environmental conditions (i.e., corrosion, humidity, etc.). In this study, hybrid FRP-concrete composite pile (HCFFT) connection is suggested. The HCFFT is consisted of pultruded FRP unit module, filament wound FRP which is in the outside of mandrel composed of circular shaped assembly of pultruded FRP unit modules, and concrete which is casted inside of the circular tube shaped hybrid FRP pile. Therefore, pultruded FRP can increase the flexural load carrying capacity, filament wound FRP and concrete filled inside can increase axial load carrying capacity. In the study, connection capacity of HCFFT(small and mid size) is investigated throughout experiments and finite element method. From the results of experiments, we suggested the connection methods about HCFFT pile connection.

배전용 FRP 전주 설계 및 성능시험 (Performance Test and Design of Distribution FRP Pole)

  • 한동희;조한구;박기호;송일근;이웅선
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
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    • pp.295-298
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    • 2001
  • This paper presents mechanical properties and weatherability of FRP pole used for a distribution line about high strength and good insulation properties. The experiment strength obtained in cantilever beam test are comparable to ES standards. The environmental factors, such as elevated temperatures, high humidity, and corrosive fluids, and ultraviolet(UV) rays, influence on the performance of Polymeric matrix composite.

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Ordered Hybrid Nanomaterials from Self-Assembled Polymeric Building Blocks

  • Kim, Dong-Ha
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.309-309
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    • 2006
  • Latest developments on hybrid nanostructured materials fabricated by applying self-assembly strategies on organic/inorganic nanotemplates are discussed. Within this frame, numerous functional nanomaterials including arrays of composite metal/semiconductor nanoparticles, planar waveguides and functional multilayer thin films are generated using self-assembled polymers as templates or building blocks. In particular, surface plasmon resonance based optical sensing is employed to investigate nanofabrication processes occurring in nanoscale dimention. We also suggest unprecedented pathways to hybrid supramolecular multilayer nanoarchitectures in 1D or 2D geometry via layer-by-layer self-assembly.

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