• Journal of the Korean Ceramic Society
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• v.42 no.1
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• pp.50-55
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• 2005

New fast proton-conducting organic-inorganic nanocomposite membranes were successfully fabricated using polymer matrix obtained through proper oxidation of thiol ligands in (3-Mercaptopropyl) trimethoxysilane (MPTS) and hydrolysis/condensation reaction of (3-glycidoxypropyl) trimethoxysilane (GPTS). The obtained nanocomposite membranes showed relatively hirh proton-conductivity over $10^{-2}S/cm$ at $ 25^{circ}C$. The proton conductivities of the fabricated composite membranes increased up to $3.6{\times}10^{-1}$ S/cm cm by increasing temperature and relative humidity to $70^{circ}C$ and 100 $100RH\%$. The high proton conductivity of the composites Is due to the proton conducting path through the GPTS-derived 'pseudo-polyethylene oxide 'network in which sulfonic acid ligands work as a proton donor.

• Journal of Powder Materials
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• v.19 no.2
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• pp.117-121
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• 2012

Tool steels serve a large range of applications including hot and cold workings of metals and injection mouldings of plastics or light alloys. The high speed steels (HSS) are specifically used as cutting tools and wear parts because it has high strength, wear resistance and hardness along with appreciable toughness and fatigue resistance. From the view of HSS microstructure, it can be described as metallic matrix composites formed by a ferrous with a dispersion of hard and wear resistant carbides. The experimental specimens were manufactured using the PIM with T42 powders (50~80 vol.%) and polymer (20~50 vol.%). The green parts were debinded in n-hexane solution at $60^{\circ}C$ for 8 hours and thermal debinded at an $N_2-H_2$ mixed gas atmosphere for 8 hours. Specimens were sintered in high vacuum ($10^{-5}$ Torr) and various temperatures.

• Steel and Composite Structures
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• v.35 no.1
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• pp.77-92
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• 2020

The present paper outlined a procedure for geometrically nonlinear dynamic analysis of functionally graded graphene platelets-reinforced (GPLR-FG) nanocomposite cylinder subjected to mechanical shock loading. The governing equation of motion for large deformation problems is derived using meshless local Petrov-Galerkin (MLPG) method based on total lagrangian approach. In the MLPG method, the radial point interpolation technique is employed to construct the shape functions. A micromechanical model based on the Halpin-Tsai model and rule of mixture is used for formulation the nonlinear functionally graded distribution of GPLs in polymer matrix of composites. Energy dissipation in analyses of the structure responding to dynamic loads is considered using the Rayleigh damping. The Newmark-Newton/Raphson method which is an incremental-iterative approach is implemented to solve the nonlinear dynamic equations. The results of the proposed method for homogenous material are compared with the finite element ones. A very good agreement is achieved between the MLPG and FEM with very fine meshing. In addition, the results have demonstrated that the MLPG method is more effective method compared with the FEM for very large deformation problems due to avoiding mesh distortion issues. Finally, the effect of GPLs distribution on strength, stiffness and dynamic characteristics of the cylinder are discussed in details. The obtained results show that the distribution of GPLs changed the mechanical properties, so a classification of different types and volume fraction exponent is established. Indeed by comparing the obtained results, the best compromise of nanocomposite cylinder is determined in terms of mechanical and dynamic properties for different load patterns. All these applications have shown that the present MLPG method is very effective for geometrically nonlinear analyses of GPLR-FG nanocomposite cylinder because of vanishing mesh distortion issue in large deformation problems. In addition, since in proposed method the distributed nodes are used for discretization the problem domain (rather than the meshing), modeling the functionally graded media yields to more accurate results.

• Elastomers and Composites
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• v.52 no.1
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• pp.22-26
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• 2017

The thermal conductivity and the adhesive properties were measured, after synthesis of thermal conductive composite which was obtained as a result of mixing alumina or graphite with acrylic adhesive synthesized by UV polymerization. The adhesive properties of the composite were evaluated measuring the peel strength at 180 degrees, the retention, and the initial tack;the thermal conductivity was estimated using laser flash analysis. As the filler contents increased, a decrease in peel strength and initial tack and an increase in retention and thermal conductivity were observed. When compared to alumina, the adhesion of graphite showed a dramatic decrease, whereas the thermal conductivity was further enhanced. It was found out that the small size of graphite increased the mechanical interlocking between the polymer and the filler, and it was easier for graphite to come into contact with other graphite in the matrix.

• Journal of the Korean Society for Nondestructive Testing
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• v.28 no.1
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• pp.46-53
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• 2008

Ultrasonic C-scan technique is one of very popular techniques being used for detection of flaws in polymer matrix composite(PMC). However, the application of this technique is very limited for evaluation of defects in PMC fabricated by the automated fiber placement process. The purpose of this study is to develop a novel ultrasonic hybrid system based on nondestructive and non-contact ultrasonic techniques for evaluation of delamination in carbon/epoxy and carbon/PPS composite laminates. It was shown that the newly developed ultrasonic hybrid system based on dual air-coupled pitch-catch technique with ultrasonic scattering reflection concept could provide excellent image with higher resolution of delamination in PMC compared with the conventional pitch-catch method. It is expected that this ultrasonic hybrid technique can be applied for on-line inspection of flaws in PMC during the fabrication process.

• Journal of the Korean Society for Nondestructive Testing
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• v.21 no.4
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• pp.425-433
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• 2001

A correlation between fatigue damage and acousto-ultrasonic (AU) parameters has been obtained from signals acquired during fatigue loading of the single-lap joints of a carbon-fiber reinforced plastic (CFRP) laminates and A16061 plate. The correlation showed an analogy to those representing the stiffness reduction $(E/E_0)$ of polymer matrix composites by the accumulation of fatigue damage. This has been attributed to the transmission characteristics of acoustic wave energy through bonded joints with delamination-type defects and their influence on the change of spectral content of AU signals. Another correlation between fatigue cycles and the spectral magnitude of acoustic emission (AE) signals has also been found during the final stage of fatigue loading. Both AU and AE can be applied almost in real-time to monitor the evolution of damage during fatigue loading.

• Journal of the Korean Society for Nondestructive Testing
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• v.19 no.6
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• pp.439-447
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• 1999

One of the problems for practical use of fiber-reinforced plastics is the performance degradation by fatigue damage in the joints. The study is to develop a nondestructive technique for real-time evaluation of adhesively bonded composite-metal joints. From the prior study we confirmed that the bonding strength can be estimated from the correlation between the qualify of bonded parts and AUP's. We obtained a curve showing the correlation between the degree of fatigue damage and AUP's calculated from signals acquired during fatigue loading of single-lap and double-lap joints of CFRP and Al6061. The curve is an analogy to the one showing stiffness reduction ($E/E_o$) of polymer matrix composites by fatigue damage. From those facts, it is plausible to predict the degree of fatigue damage in real-time. Amplitude and AUP2 appeared to be optimal parameters to provide more reliable results for single-lap joints whereas Amplitude and AUP2 did for double-lap joints. It is recommended to select optimal parameters for different geometries in the application for real structures.

• Advanced Composite Materials
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• v.17 no.1
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• pp.57-73
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• 2008

The present paper focuses on experimental verification of the ply-by-ply basis inelastic analysis of multidirectional laminates. First of all, rate dependence of the tensile behavior of balanced symmetric cross-ply T800H/epoxy laminates with a $[0/90]_{3S}$ lay-up under off-axis loading conditions at $100^{\circ}C$ is examined. Uniaxial tension tests are performed on plain coupon specimens with various fiber orientations $[{\theta}/(90-{\theta})]_{3S}$ ($\theta$ = 0, 5, 15, 45 and $90^{\circ}C$) at two different strain rates (1.0 and 0.01%/min). The off-axis stress.strain curves exhibit marked nonlinearity for all the off-axis fiber orientations except for the on-axis fiber orientations $\theta$ = 0 and $90^{\circ}$, regardless of the strain rates. Strain rate has significant influences not only on the off-axis flow stress in the regime of nonlinear response but also on the apparent off-axis elastic modulus in the regime of initial linear response. A macromechanical constitutive model based on a ply viscoplasticity model and the classical laminated plate theory is applied to predictions of the rate-dependent off-axis nonlinear behavior of the cross-ply CFRP laminate. The material constants involved by the ply viscoplasticity model are identified on the basis of the experimental results on the unidirectional laminate of the same carbon/epoxy system. It is demonstrated that good agreements between the predicted and observed results are obtained by taking account of the fiber rotation induced by deformation as well as the rate dependence of the initial Young's moduli.

• Elastomers and Composites
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• v.48 no.1
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• pp.18-23
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• 2013

Nylon 12 elastomer was slightly crosslinked in molten state by the addition of small amount of dicumyl peroxide (DCP) as a crosslink agent and triallycyanuate (TAC) as a co-agent during melt compounding at $160^{\circ}C$ in an internal mixer. The effect of the peroxide crosslinking on mechanical, dynamic mechanical and rheological properties of the nylon 12 elastomer was investigated by means of tensile testing, dynamic mechanical analysis (DMA) and small amplitude oscillating rheometer, respectively. With modification, there is an improvement in tensile modulus and Young's modulus with decease in elongation at break. DMA results for peroxide modified nylon 12 elastomers demonstrated that the glass transiaiton temperature of PTMG segment shifted to higher temperature and the storage modulus remained constant above the melting temperature of nylon 12 segments. Melt rheological studies revealed that the peroxide modified nylon 12 elastomer exhibited a more solid like behavior and stronger shear thinning behavior compared to neat nylon 12 elastomer, which was more prominent at higher TAC content in the polymer matrix. The peroxide modified nylon 12 elastomer exhibited good elastic recoverability and improved mechanical properties without sacrificing melt processibilty, and especially the service temperature range increased as compared to neat nylon 12 elastomer.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.37 no.12
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• pp.1465-1471
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• 2013

The electrical and mechanical properties of room temperature vulcanized (RTV) silicone rubber composites are investigated as functions of multi-walled carbon nanotube (CNT), carbon black (CB), and thinner content. The thinner is used to improve the CNT and CB dispersion in the matrix. The electrical and mechanical properties of the composite with CNT are improved when compared to the composite with CB at the same content. As the thinner content is 80 phr, the electric resistance of the composite decreases significantly with the CNT content and shows contact point saturation of CNT at 2.5 phr. As the thinner content increases, the dispersion of conductive particles improves; however, the critical CB content increases because of the reduction in the CB weight ratio. It is believed that an electrode that needs good flexibility and excellent electrical properties can be manufactured when the amount of CNT and CB are increased with the thinner content.