• Title/Summary/Keyword: Polymer wall

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Experimental Study on the Effect of Drilling Fluid with Different Mix Designs for Bore Hole Collapse Prevention (시추 안정액 배합설계에 따른 공벽 붕괴방지 효과에 관한 실험적 연구)

  • Yoo, Chung-Sik;Choi, Jung-Hyuk;Han, Yun-Su
    • Journal of the Korean Geotechnical Society
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    • v.31 no.1
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    • pp.15-24
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    • 2015
  • This paper presents the results of a reduced-scale physical model investigation into the effect of drilling fluid with different mix designs for bore hole collapse prevention. The bore hole collapse prevention mechanism for the bentonite based drilling fluid was first discussed together with the effect of conditioning with different additives on engineering characteristics of bentonite based drilling fluid. Reduced-scale model tests were then carried out considering field procedures for cases with a decomposed granitic soil with 20% fines and a sand with various drilling fluids with different mix designs. The results indicated that the addition of polymer to the bentonite based drilling fluid decreases the amount of drilling fluid injected, the drilling fluid infiltration thickness and increases the final depth of excavation. Also revealed is that the effect of polymer on the performance of drilling fluid is more pronounced in the decomposed granite soil with 20% fines than the sand. Practical implications of the findings from this study are discussed in great detail.

The Developing Trend in Bioresorbable Stent for Treatment of Coronary Artery Disease (관상동맥질환 치료를 위한 생체흡수형스텐트의 개발 동향)

  • Jeong, Gyeong-Won;Kim, Tae-Hoon;Nah, Jae-Woon;Park, Jun-Kyu
    • Applied Chemistry for Engineering
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    • v.29 no.5
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    • pp.497-502
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    • 2018
  • The coronary artery disease (CAD) is rapidly increasing such as angina pectoris and atherosclerosis. The CAD is induce by cholesterol and calcium like plaque absortion to artery wall. The percutaneouss coronary intervention is non-invasive treatment that narrowed-artery is expand by using balloon catheter and bare metallic stent. The metallic stents have been effective in reducing the dead by coronary artery disease, but the permanent presence of the metallic stent has been associated with persistent inflammation, and incidence of late thrombosis. Therefore, development bioresorbable vascular scaffold (BRS) is rapidly increasing for treatment of long-term complications and arterial restenosis by permanentmetal prosthesis such as stent. The review discusses the BRS trend for successfully development.

Stabilization of Enzyme in "Solvophobically" Controlled Polymer Microcapsules ("솔보포빅"한 고분자 마이크로 캡슐을 이용한 효소 안정화에 관한 연구)

  • Kim, Yong-Jin;Kim, Jin-Woong;Kim, Jin-Oh;Kim, Jin-Woo;Chang, Ih-Seop
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.32 no.1 s.55
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    • pp.29-33
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    • 2006
  • This article describes an enzyme stabilization method that allows the use of enzymes irrespective of environmental factors, especially heat, while maintaining their activity for a long time. We have designed enzyme microcapsules that consist of papain enzyme cores, poly(propylene glycol) interlayers, and poly(${\epsilon}-caprolactone$) walls. By confocal laser scanning microscopy measurements and the thermal stability of papain-loaded microcapsules, it is demonstrated that the papain is surrounded by a hydrophobic polyol layer and stabilized by the exclusive volume effect. In our study, improved thermal stability can be obtained by using more hydrophobic long-chained polyols, which is understood to be attributed to the effective formation of a hydrophobic polyol layer between the papain and the polymer wall by means of conformational anchoring in the interface.

Preparation and Characterization of Calcium Alginate Microcapsules by Emulsification-Internal Gelation (에멀션-내부 젤화에 의한 알긴산 칼슘 마이크로캡슐의 제조 및 특성)

  • Park Soo-jin;Kang Jin-Young
    • Polymer(Korea)
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    • v.29 no.4
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    • pp.369-374
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    • 2005
  • In this work, the calcium alginate microcapsules containing lemon oil were prepared by emulsification-internal gelation and their potential use as aromatherapy was examined by the controlled release system. The lemon oil encapsulated in the alginate was successfully observed by Fourier transform (FT-IR) spectroscopy and differential scanning calorimeter (DSC) measurements. Analysis of the diameters and shapes of microcapsules was conducted by scanning electron microscopy (SEM). The mean diameters ranging from 4 to 7 um and encapsulation yield ranging from 50 to $85\%$ were obtained. The controlled release of the lemon oil at $37^{circ}$ was demonstrated by the infrared moisture determination (IMDB). It was found that the amount of released lemon oil decreased with increasing concentrations of alginate and $CaCl_2$ due to the higher the cross-linking density of the capsules prepared. The oil release from the capsule was measured as a function of physical force. We confirmed that the external factor could control the collapse of capsule wall and the release rate.

Finite Element Analysis of Powder Injection Molding Filling Process Including Yield Stress and Slip Phenomena (항복응력과 미끄럼현상을 고려한 분말사출성형 충전공정의 유한요소해석)

  • 박주배;권태헌
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.17 no.6
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    • pp.1465-1477
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    • 1993
  • Powder Injection Molding(PM) is an advanced and complicated technology for manufacturing ceramic or metal products making use of a conventional injection molding process, which is generally used for plastic products. Among many technologies involved in the successful PIM, injection molding process is one of the key steps to form a desired shape out of powder/binder mixtures. Thus, it is of great importance to have a numerical tool to predict the powder injection molding filling process. In this regard, a finite element analysis system has been developed for numerical simulations of filling process of powder injection molding. Powder/polymer mixtures during the filling pro cess of injection molding can be rheologically characterized as Non-Newtonian fluids with a so called yield phenomena and have a peculiar feature of apparent slip phenomena on the wall boundaries surrounding mold cavity. Therefore, in the present study, a physical modeling of the filling process of powder/polymer mixtures was developed to take into account both the yield stress and slip phenomena and a finite element formulation was developed accordingly. The numerical analysis scheme for filling simulation is accomplished by combining a finite element method with control volume technique to simulate the movement of flow front and a finite difference method to calculate the temperature distribution. The present study presents the modeling, numerical scheme and some numerical analysis results showing the effect of the yield stress and slip phenomena.

A Study on the Drag and Heat Transfer Reduction Phenomena and Degradation Effects of the Viscoelastic Fluids (점탄성유체의 저항 및 열전달 감소현상과 퇴화의 영향에 관한 연구)

  • Eum, C.S.;Jeon, C.Y.;Yoo, S.S.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.2 no.1
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    • pp.37-48
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    • 1990
  • The drag and heat transfer reduction phenomena and degradation effects of drag reducing polymer solutions which are known as the viscoelastic fluids are investigated experimentally for the turbulent circular tube flows. Two stainless steel tubes are used for the experimental flow loops. Aqueous solutions of Polyacrylamide Separan AP-273 with concentrations from 300 to 1000 wppm are used as working fluids. Flow loops are set up to measure the friction factors and heat transfer coefficients of test tubes in the once-through system and the recirculating flow system. Test tubes are heated by power supply directly to apply constant heat flux boundary conditions on the wall. Capillary tube viscometer and falling ball viscometer are used to measure the viscous characteristics of fluids and the characteristic relaxation time of a fluid is determined by the Powell-Eyring model. The order of magnidude of the thermal entrance length of a drag reducing polymer solution is close to the order of magnitude of the laminar entrance length of Newtonian fluids. Dimensionless heat transfer coefficients of the viscoelastic non-Newtonian fluids may be represented as a function of flow behavior index n and newly defined viscoelastic Graetz number. As degradation continues viscosity and the characteristic relaxation time of the testing fluids decrease and heat transfer coefficients increase. The characteristic relaxation time is used to define the Weissenberg number and variations of friction factors and heat transfer coefficients due to degradation are presented in terms of the Weissenberg number.

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Investigation of the Filling Unbalance and Dimensional Variations in Multi-Cavity Injection Molded Parts (다수 캐비티의 사출성형품에서 충전의 불균형과 성형품 치수 편차의 교찰)

  • Kang, Min-A;Lyu, Min-Young
    • Polymer(Korea)
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    • v.32 no.6
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    • pp.501-508
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    • 2008
  • Small injection molded articles such as lens and mobile product parts are usually molded in multi-cavity mold. The problem occurring in multi-cavity molding is flow unbalance among the cavities. The flow unbalance affects the dimensions and physical properties of molded articles. First of all, the origin of flow unbalance is geometrical unbalance of the delivery system. However, even the geometry of the delivery system is well balanced, cavity unbalance occurs. This comes from the temperature distributions in the cross-section of runner. Temperature distribution depends upon injection speed because heat generation near runner wall is high at high injection speed. Among the operational conditions, injection speed is the most significant process variable affecting the filling unbalances in multi-cavity injection molding. In this study, experimental study of flow unbalance has been conducted for various injection speeds and materials. Also, the filling unbalances were compared with CAE results. The dimensions and weights of multi-cavity molded parts were examined. The results showed that the filling unbalances vary according to the injection speeds and resins. Subsequently, the unbalanced filling and pressure distribution in the multi-cavity affect the dimensions and physical states of molded parts.

The Preparation of Chiral Separation Membranes by UV Polymerization and its Properties (UV 중합에 의한 이성질체 분리막 제조와 특성)

  • Chang, Eun-Jeong;Hong, Joo-Hee;Heo, Kwang-Beom;Kim, Min;Kim, Byoung-Sik
    • Applied Chemistry for Engineering
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    • v.19 no.3
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    • pp.287-294
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    • 2008
  • Molecularly imprinted polymer (MIPs) membranes were prepared by UV polymerization to separate racemates with opposite physiological activity, and then its separation selectivity of racemates was carried out. Likewise, their properties were examined. Polycarbonate (PC) membrane was polymerized as small spot form in pore inner wall, but anodisc (AD) membrane was polymerized as film form with thickness 500~700 nm onto the membrane surface. Also the study on the separation selectivity of prepared MIPs membranes was carried out in L-Tryptophane (Trp) racemate solution. The results showed that AD MIPs membrane polymerized as a film form, which was achieved by solution polymerizaion consisting of over 90% cross-linking agent (ethylene glycol dimethacrylate; EGDMA) and under 30% dispersing agent (methanol; MeOH), had predominant 3.5 selectivity.

Seismic and vibration tests for assessing the effectiveness of GFRP for retrofitting masonry structures

  • Michelis, Paul;Papadimitriou, Costas;Karaiskos, Grigoris K.;Papadioti, Dimitra-Christina;Fuggini, Clemente
    • Smart Structures and Systems
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    • v.9 no.3
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    • pp.207-230
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    • 2012
  • Full-scale shake table seismic experiments and low-amplitude vibration tests on a masonry building are carried out to assess its seismic performance as well as study the effectiveness of a new multifunctional textile material for retrofitting masonry structures against earthquakes. The un-reinforced and the retrofitted with glass fiber reinforced polymer (GFRP) strips masonry building was subjected to a series of earthquake excitations of increasing magnitude in order to progressively induce various small, moderate and severe levels of damage to the masonry walls. The performance of the original and retrofitted building states is evaluated. Changes in the dynamic characteristics (lowest four modal frequencies and damping ratios) of the building are used to assess and quantify the damage states of the masonry walls. For this, the dynamic modal characteristics of the structure states after each earthquake event were estimated by performing low-amplitude impulse hammer and sine-sweep forced vibration tests. Comparisons between the modal results calculated using traditional accelerometers and those using Fiber Bragg Grating (FBG) sensors embedded in the reinforcing textile were carried on to investigate the reliability and accuracy of FBG sensors in tracking the dynamic behaviour of the building. The retrofitting actions restored the stiffness characteristics of the reinforced masonry structure to the levels of the original undamaged un-reinforced structure. The results show that despite a similar dynamic behavior identified, corresponding to reduction of the modal frequencies, the un-reinforced masonry building was severely damaged, while the reinforced masonry building was able to withstand, without visual damage, the induced strong seismic excitations. The applied GFRP reinforcement architecture for one storey buildings was experimentally proven reliable for the most severe earthquake accelerations. It was easily placed in a short time and it is a cost effective solution (covering only 20% of the external wall surfaces) when compared to the cost for full wall coverage by GFRPs.

Thermal Degradation Analyses of Epoxy-Silica Nano Composites (에폭시-실리카 나노 복합소재의 열화 특성 및 거동 분석)

  • Jang, Seo-Hyun;Han, Yusu;Hwang, Do Soon;Jung, Joo Won;Kim, Yeong K.
    • Composites Research
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    • v.33 no.5
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    • pp.268-274
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    • 2020
  • This paper analyzed the degradation behaviors of silica nano epoxy composite based on the isoconversional method. The size of the silica nano particle was about 12 nm and the particles were mixed by three different weight ratios to make the degradation test samples. The thermogravimetric analyses were performed under six different temperature increase rates to measure the weight changes. Four different methods, Friedman, Flynn-Wall-Ozawa, Kissinger and DAEM (Distributed Activation Energy Method), were employed to calculate the activation energies depending on the conversion ratios, and their calculation results were compared. The results represented that the activation energy was increased when the silica nano particles were mixed up to 10%, indicating the definite contribution of the particles to the degradation behavior enhancements. However, the enhancement was not proportional to the particle mixture ratio by demonstrating the similar activation energies between 10% and 18% samples. The calculation results by the different methods were also compared and discussed.