• Title/Summary/Keyword: Polymer wall

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Softening Related Changes in Cell Wall Polysaccharides of Persimmon (감의 연화와 관련된 세포벽다당류의 변화)

  • Kim, Soon-Dong;Park, Nam-Sook;Kang, Meung-Su
    • Korean Journal of Food Science and Technology
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    • v.18 no.2
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    • pp.158-162
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    • 1986
  • Various cell wall polysaccharides such as ionically associated pectin (IAP), covalently bounded pectin (CBP),4N potassium hydroxide soluble hemicellulosic fraction (HF,) and 0-3N soluble hemicellulosic fraction (HF,) were fractionated from crude cell wall of the fresh and soft persimmon by chemical method. The changesin cell wall polysaccharides were studied by gel filteration chromatography . The content of crude cell wall remarkably decreased in the soft persimmon. The decreasing rates of IAP, CBP and $HF_2$ were 59, 60 and 74%, respectively, while $HF_1$ and cellulose changed only a little during softening. Sugar compositions of IAP and CBP were 72-84% uronic acid, 5-1% hexose and 11-16% pentose, and also the hemicellulose was composed of uronic acid besides hexose and pentose that was hemicellulosic components. The loss rate of pentose in IAP, of hexose in CBP, of hexose and uronic acid in $HF_2$, of pentose in $HF_1$ increased during softening. Though apparent average molecular freight of all polysaccharides shifted from high molecular freight to low molecular weight polymer, the shifting degree of CBP and $HF_2$ was especially remarkable during softening. It is suggested that the severe softening phenomenon of persimmon involved the degradation and dissolution of wall bound-CBP and $HF_2$ which were associated with each other.

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A Study on The Optimization of Pre-treatment for the Brine Wastewater from the Epoxy-resin Process by the Coagulation and Sedimentation Reactions (에폭시수지 생산 공정에서 발생되는 brine 폐수의 전처리를 위한 응집 및 침전 반응의 최적화 연구)

  • Cho, Wook Sang;Lee, Eun Young;Kang, Seong Wook;Lee, Jang Su;Jin, Su Ik
    • Clean Technology
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    • v.11 no.2
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    • pp.57-67
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    • 2005
  • Epoxy resins are produced by the dehydro condensated reaction with ECH (Epichlorohydrin) and BPA(Bisphenol-A) as raw reactants under sodium hydroxide(NaOH) as a catalyst, and from this reaction, salted water named of brine, which contains ECH derivatives in condition of emulsion as likely as glycidol and polymer resins, is produced as an undesired side product. This brine water is alkaline wastewater and causes process fouling problems by plugging and chemically depositing polymer particles on the surface of inner wall of reactors and pipes, and decreases the biodegradable efficiency in the wastewater process. In this study, the optimization of coagulation and sediment reactions, using inorganic and organic polymer coagulants, were performed to remove the causes occurring the process fouling phenomena. And also, based on this study, the methodologies applicable to the commercial processes including economical analysis were presented.

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The Characteristics of Two Phase Flow by Non-Newtonian Fluid for Vertical Up-ward in a Tube (수직 상향유동 배관에서 비뉴톤유체에 의한 2상류의 유동특성)

  • Cha K.O.;Kim J. G.;Che K.S.
    • Journal of the Korean Institute of Gas
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    • v.2 no.4
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    • pp.53-59
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    • 1998
  • Flow pattern of air-water two phase flow depends on the conditions of pressure drop, void fraction, and channel geometry. Drag reduction in the two phase flow can be applied to the transport of crude oil, phase change systems such as chemical reactor, pool and boiling flow, and to present cavitation which occurs in pump impellers. But the research on drag reduction in two phase flow is not intensively investigated. Therefore, experimental investigations have been carried out to analyze the drag reduction produced and void fraction by Co-polymer(A611p) addition in the two phase flow system. We find that the maximum point position of local void friction moves from the wall of the pipe to the center of the pipe when polymer concentration increases. Also we find that the polymer solution changes the characteristics of the two phase flow. And then we predict that it is closely related with the drag reduction.

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Effect of Lactococcus lactis 1370 on the Formation of Artificial Plaque (Lactococcus lactis 1370가 인공치태 형성에 미치는 영향)

  • Chung, Jin;Yim, Sung-Yee;Oh, Jong-Suk
    • The Journal of the Korean Society for Microbiology
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    • v.35 no.1
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    • pp.77-85
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    • 2000
  • Streptococcus mutans is the most important causative bacteria of dental caries among the oral bacteria. Lactococcus lactis 1370 was isolated from the oral cavity of child. The effect of Lactococcus lactis 1370 on the formation of artificial plaque by Streptococcus mutans was studied. 1. The insoluble substances and bacteria were much more attached on the wall of disposable cuvette in the culture of Streptococcus mutans than in the combined culture of Streptococcus mutans and Lactococcus lactis 1370. 2. The mean weight of produced artificial plaque on the wires in the beaker was 131.7 mg in the culture of Streptococcus mutans only, whereas being reduced to 6.4 mg in the combined culture of Streptococcus mutans and Lactococcus lactis 1370 (p<0.05). The viable cell didn't show the significant difference between them after culturing. 3. When Streptococcus mutans was cultured in the media containing culture supernatant of Lactococcus lactis 1370 cultured in M17 broth containing 0.5% yeast extract and 5% sucrose, the mean weight of produced artificial plaque was 8.0 mg on the wires, whereas being 125.4 mg in the media without culture supernatant of Lactococcus lactis 1370 (p<0.05). The viable cell didn't show the significant difference between them after culturing. 4. When Streptococcus mutans was cultured in the media containing soluble polymer produced by Lactococcus lactis 1370, the mean weight of produced artificial plaque was significantly reduced compared with being cultured in the media without soluble polymer (p<0.05). The viable cell didn't show the significant difference between them after culturing. 5. The soluble polymer produced by Lactococcus lactis 1370 was glucan. 6. The glucan produced by Lactococcus lactis 1370 was water-soluble glucan containing ${\alpha}$-1,6-glucose linkage as the main linkage. These results suggest that the artificial plaque formed by Streptococcus mutans is inhibited by water-soluble glucan produced by Lactococcus lactis 1370.

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Finite Element Analysis of the Monoleaflet Polymer to Minimize Stress and Displacement (응력 및 변위를 최소화하기 위한 단엽식 고분자 판막의 유한 요소 해석)

  • 한근조;안성찬
    • Journal of Biomedical Engineering Research
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    • v.17 no.1
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    • pp.85-92
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    • 1996
  • A monoleaflet polymer artificial heart valve which showed the remarkable improvement in pressure drop compared with other types of artificial valve was designed to minimize the deflection in vertical direction and the displacement of the valve tip in horizontal direction obtained by using finite element method as the location of the supporting members of the valve frame changed stress distribution change was also studied on each model generated by changing the distance between the frame and supporting members. It was found that by using the valve tip horizontal displacement the minimum valve thickness could be obtained in order to prevent the gap between the valve tip and the frame wall.

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A Study on The Improvement of Profile Tilting or Bottom Distortion in HARC (높은 A/R의 콘택 산화막 에칭에서 바닥모양 변형 개선에 관한 연구)

  • Hwang, Won-Tae;Kim, Gli-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.5
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    • pp.389-395
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    • 2005
  • The etching technology of the high aspect ratio contact(HARC) is necessary at the critical contact processes of semiconductor devices. Etching the $SiO_{2}$ contact hole with the sub-micron design rule in manufacturing VLSI devices, the unexpected phenomenon of 'profile tilting' or 'bottom distortion' is often observed. This makes a short circuit between neighboring contact holes, which causes to drop seriously the device yield. As the aspect ratio of contact holes increases, the high C/F ratio gases, $C_{4}F_{6}$, $C_{4}F_{8}$ and $C_{5}F_{8}$, become widely used in order to minimize the mask layer loss during the etching process. These gases provide abundant fluorocarbon polymer as well as high selectivity to the mask layer, and the polymer with high sticking yield accumulates at the top-wall of the contact hole. During the etch process, many electrons are accumulated around the asymmetric hole mouth to distort the electric field, and this distorts the ion trajectory arriving at the hole bottom. These ions with the distorted trajectory induce the deformation of the hole bottom, which is called 'profile tilting' or 'bottom distortion'. To prevent this phenomenon, three methods are suggested here. 1) Using lower C/F ratio gases, $CF_{4}$ or $C_{3}F_{8}$, the amount of the Polymer at the hole mouth is reduced to minimize the asymmetry of the hole top. 2) The number of the neighboring holes with equal distance is maximized to get the more symmetry of the oxygen distribution around the hole. 3) The dual frequency plasma source is used to release the excessive charge build-up at the hole mouth. From the suggested methods, we have obtained the nearly circular hole bottom, which Implies that the ion trajectory Incident on the hole bottom is symmetry.

Effect of glass beads on dispersion properties of EVA/MWCNT foams (유리비드가 EVA/MWCNT 발포체의 분산특성에 미치는 영향)

  • Kim, Taeyoon;Lee, Seunghyun;Ching, Ildoo
    • Journal of Adhesion and Interface
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    • v.19 no.2
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    • pp.68-73
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    • 2018
  • In this study, conductive EVA foams including multi-wall carbon nanotubes (MWCNT), glass beads were prepared. The electrical conductivity and physical properties of the foams were confirmed with varying amount of MWCNT, mixing time, and amount of glass beads. The electrical conductivity increased with the amount of MWCNT. Dispersity of MWCNT in EVA foams were improved with glass beads. It can be suggested that conductive EVA foams can be successfully prepared with improved dispersity of MWCNT in ethylene-vinyl acetate by using glass beads.

Improvement of Flexural Structural Performance and Applied Section Shape for Sound Proof Wall Structures Using Glass Fiber Reinforced Polymer(GFRP) (GFRP를 활용한 도로 방음벽 구조물의 구조성능 및 단면형상 개선에 관한 연구)

  • Jung, Woo-Young;Choi, Hyun-Kyu
    • International Journal of Highway Engineering
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    • v.11 no.4
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    • pp.9-15
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    • 2009
  • This research presents the structural performance and an improving technique for flexural capacity of road safety facilities based on the damage cases by wind pressure. Among road safety facilities, a support frame of soundproofing walls is considered as a prototype structure and its corresponding structural behaviors and section design are performed mainly by analytical and experimental studies. On the basis of analytical results, glass fiber reinforced polymer(GFRP) with an epoxy matrix which is high stiffness-to-weight ratio was used for applied one of strengthening techniques and their results shows that support frame strengthened by GFRP is the most effective compared to other cases proposed in this research for advancing its flexural improvement, Finally, optimum section design was performed analytically to evaluate wind-resistance capacity and its result would be very useful for developing a practical design guideline for Road safety facilities under strong wind.

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Effects of Gas Chemistries on Poly-Si Plasma Etching with I-Line and DUV Resist (I-Line과 DUV Resist에서 Poly-Si 플라즈마 식각시 미치는 개스의 영향)

  • 신기수;김재영
    • Journal of the Korean Vacuum Society
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    • v.7 no.2
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    • pp.155-160
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    • 1998
  • It is necessary to use Arc layer and DUV resist to define 0.25 $\mu \textrm{m}$ line and space for 256 MDRAM devices. Poly-Si etching with Arc layer and different resists has been performed in a TCP-9408 etcher with variation of gas chemistries; $Cl_2/O_2, Cl_2/N_2, Cl_2$/HBr . DUV resist causes more positive etch profile and CD gain compared to I-line resist because the sidewall passivation is more stimulated by increasing polymerization through the loss of resist. When Arc layer is applied, CD hain also increases due to the polymeric mask formed after thching Arc layer. From the point of gas chemistry effects, the etch profile and CD gain is not improved using $Cl_2/O_2$ gas, since polymerization is accelerated in this gas. however, the vertical profile and less CD gain is obtained using $Cl_2$/HBr gas. Furthermore, HBr gas is very effective to suppress the difference of profile and CD variation between dense pattern and isolated pattern by minimizing non-uniformity of side wall passivation with pattern density.

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PDMS-based pixel-wall bonding technique for a flexible liquid crystal display (플렉서블 액정 디스플레이를 위한 PDMS 기반 pixel-wall bonding 기술)

  • Kim, Young-Hwan;Park, Hong-Gyu;Oh, Byeong-Yun;Kim, Byoung-Yong;Paek, Kyeong-Kap;Seo, Dae-Shik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.04a
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    • pp.42-42
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    • 2008
  • Considerable attention has been focused on the applications of flexible liquid crystal (LC)-based displays because of their many potential advantages, such as portability, durability, light weight, thin packaging, flexibility, and low power consumption. To develop flexible LCDs that are capable of delivering high-quality moving images, like conventional glass-substrate LCDs, the LC device structure must have a stable alignment layer of LC molecules, concurrently support uniform cell gaps, and tightly bind two flexible substrates under external tension. However, stable LC molecular alignment has not been achieved because of the layerless LC alignment, and consequently high-quality images cannot be guaranteed. To solve these critical problems, we have proposed a PDMS pixel-wall based bonding method via the IB irradiation was developed for fasten the two substrates together strongly and maintain uniform cell gaps. The effect of the IB irradiation on PDMS with PI surface was also evaluated by side structure configuration and a result of x-ray photoelectron spectroscopic analysis of PDMS interlayer as a function of binder with substrates. large number of PDMS pixel-walls are tightly fastened to the surface of each flexible substrate and could maintain a constant cell gap between the LC molecules without using any other epoxy or polymer. To enhance the electro-optical performance of the LC device, we applied an alignment method that creates pretilt angle on the PI surface via ion beam irradiation. Using this approach, our flexible LCDs have a contrast ratio of 132:1 and a response time of about 15 ms, resulting in highly reliable electro-optical performance in the bent state, comparable to that of glass-substrate LCDs.

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