• Title/Summary/Keyword: Polymer thin film

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Thermally Induced Mesophase Development in Ethanesilica Films via Macromolecular Templating Approach

  • Cho, Whirang;Char, Kook-Heon;Kwon, Su-Yong
    • Macromolecular Research
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    • v.17 no.9
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    • pp.697-702
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    • 2009
  • Mesoporous ethanesilica thin film was prepared using PEO-PLGA-PEO triblock copolymers as structure-directing agents and (1,2-bis(triethoxysilyl) ethane BTESE; bridged organosilicates) as inorganic precursors via one-step sol-gel condensation of ethanesilica precursors. The mesostructure of ethanesilica films is critically dependent on the processing experimental parameters after the hydrolyzed silica sol mixture was spin-cast. This study examined the effects of the block copolymer template/organosilica precursor ratio in the casting solution and aging period before calcination of the mesostructure. It was further demonstrated that mesoscopic ordering of organosilicate thin films is induced by the rearrangement of block copolymer template/organosilica hybrid during thermal decomposition of the PEO-PLGA-PEO triblock copolymer. The mesoporous structure and morphology were characterized by SAXS, TEM and solid-state NMR measurement.

Investigate Electronic Property of N-doped Plasma-Polymer Thin Films for Applied Biosensors

  • Seo, Hyeon-Jin;Hwang, Gi-Hwan;Nam, Sang-Hun;Ju, Dong-U;Lee, Jin-Su;Yu, Jeong-Hun;Bu, Jin-Hyo;Yun, Sang-Ho
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.159-159
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    • 2013
  • In this studying, we investigated the basic properties of N-doped plasma polymer. The N-doped plasma polymer thin films were deposited by radio frequency (13.56 MHz) plasma-enhanced chemical vapor deposition method. Various carbon-source were used as organic precursor with hydrogen gas as the precursor bubbler gas. Additionally, ammonia gas [NH3] was used as nitrogen dopant. The as-grown polymerized thin films were analyzed using cyclic voltammetry, ellipsometry, Fourier-transform infrared [FT-IR] spectroscopy, Raman spectroscopy, FE-SEM, and water contact angle measurement. Electronic property of N-doped plasma thin film is changed as flow rate of the NH3 gas.

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A Study on Electroluminescence Device with Polymer (고분자를 이용한 전계발광소자에 관한 연구)

  • Lee, Jong-Chan;Lee, Cheong-Hak;Park, Su-Gil;Lim, Kee-Joe;Park, Dae-Hee
    • Proceedings of the KIEE Conference
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    • 1997.07d
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    • pp.1219-1221
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    • 1997
  • Poly(1,4-phenylene(1-methoxyenthylene)), organic water soluble PPV precursor was synthesized for polymer electroluminescence(EL) device. To control the molecular array, deposition method of emitter was Langmuir-Blodgett(LB). PPV precursor layer was treated thermally to conversion of PPV. Optical, electrical and EL properties of PPV LB thin film was estimated. Homogeneous light emission of greenish-yellow in PPV LB thin film can be easily confirmed under normal lighting even at low driving voltage. Polymer EL device using PPV LB thin film as emitter materials had a possibility to apply to next generation display device.

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Flexible audible display(VizDio$^{TM}$) using polymer dispersed liquid crystal on film speaker

  • Bae, Byeong-Taek;Park, Dong-Hee;Jeong, Kwang-Ho;Choi, Won-Kook
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.877-878
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    • 2009
  • To realize the flexible audible display (FAD), polymer dispersed liquid crystal(PDLC) is deposited on PVDF(Poly-vinylidene fluoride) film with piezoelectric property. With applied audio signal, it makes sound more than 70 dB in 700 Hz-10kHz. In case of transparency it is opaque and transmittance is less than 10% at 550nm wavelength without bias voltage. It is turned to be transparent and show transmittance of 66% with driving voltage of 60V.

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Characteristics of Pentacene Organic Thin-Film Transistors with Different Polymer Gate Insulators (Polymer Gate Insulators에 따른 Pentacene Organic Thin-Film Transistors의 특성 분석)

  • Kim, Jung-Min;Her, Hyun-Jung;Yoon, J.H.;Kim, Jae-Wan;Choi, Y.S.;Kang, C.J.;Jeon, D.;Kim, Yong-Sang
    • Proceedings of the KIEE Conference
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    • 2006.07c
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    • pp.1434-1435
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    • 2006
  • 본 연구에서는 polymer gate insulators에 따른 pentacene 유기 박막 트랜지스터 (Organic Thin-Film Transistors)의 전기적 특성을 atom force microscope (AFM), x-ray diffraction (XRD) 그리고 I-V 측정을 이용하여 분석하였다. Pentacene 박막 트랜지스터의 전기적 특성은 pentacene의 증착 조건뿐만 아니라 polymer gate insulator에 따라 크게 영향을 받는다. 따라서 다양한 polymer 기판 위에 온도, 두께 그리고 증착 속도에 따라 pentacene을 증착 하였다. 그리고 증착된 pentacne을 AFM, XRD를 이용하여 pentacene의 구조, 결정화 그리고 grain 크기 등을 분석하였다. 또한 inverted stagger며 구조의 pentacene 박막 트랜지스터 소자를 제작하고 I-V 측정하여 그 결과를 분석하였다.

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Flow Behavior of Thin Polymer Film in Spinning Coating Process of Blu-ray Disc Cover layer (블루레이 디스크의 커버레이어 스핀코팅 시 폴리머 거동에 관한 연구)

  • Ban J. H.;Shin H. G.;Kim B. H.;Kim H. Y.;Lee H. G.;Son S. G.;Shin J. K.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2005.05a
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    • pp.113-116
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    • 2005
  • In this paper, a computational and experimental analysis about the flow behavior of thin polymer film in the spin coating process for stable cover layer coating of a blu-ray disc is described. The blu-ray disc, a next-generation optical disc format over 25GB, consists of a 1.1mm thick substrate and a 0.1mm tick cover layer. Generally, cover layer on the blu-ray disc is made by the polymer spin coating process. However, it is hard to secure sufficient coating uniformity around the rim on the cover layer. In order to get the uniform thickness deviation and to minimize the bead around the rim, the edge of the disc substrate can be modified into various shapes around the rim on the disc and analyzed with various parameters, such as surface tension, viscosity, and rotation speed, etc. The optimal shape of the rim was tried to get by 3 dimensional computer simulation of the polymer expulsion process.

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A Study on the Surface Properties of Polymer Insulators for Improving Electrical Insulation Performance (전기 절연성능 향상을 위한 폴리머 애자의 표면 특성 연구)

  • Park, Yong Seob;Bae, Jae Sung;Hong, Byungyou;Lee, Jae Hyeong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.34 no.1
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    • pp.63-67
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    • 2021
  • In this paper, we investigated the surface properties of polymer insulators to improve electrical insulation performance. First, after washing the polymer insulator in various ways, its contact angle was increased, thereby improving the hydrophobic properties and electrical insulation properties. In addition, TiO2 thin films, which have been used as a photocatalytic material and have been applied to the polymer insulator surface of to enhance the surface and electrical insulating properties. For the sputtering method, the contact angle after coating the TiO2 thin film increased with increasing RF power, but it was lower compared to that before coating, indicating that the hydrophobic properties of the surface were slightly deteriorated. Consequently, the electrical properties of the polymer-insulating material were maintained or improved after the TiO2 thin-film coating.

Study on Poly(3,4-ethylenedioxythiophene) Thin Film Vapour Phase-Polymerized with Iron(III)Tosylate on AcOH-Catalyzed 3-Aminopropyltriethoxysilane Self-Assembled Monolayer

  • Choi, Sangil;Kim, Wondae;Kim, Sungsoo
    • Journal of Integrative Natural Science
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    • v.5 no.4
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    • pp.233-236
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    • 2012
  • In this study, PEDOT thin films polymerized with Iron(III)tosylate ($Fe(PTS)_3$) and grown on acetic acid-catalyzed 3-aminopropyltriethoxysilane self-assembled monolayer (APS-SAM) surfaces by VPP method have been investigated. PEDOT thin films were synthesized on APS self-assembled $SiO_2$ wafer surface at two different concentrations (20 wt% and 40 wt%) and growth time (3 and 30 minutes), and then they were compared. PEDOT vapour phase-polymerized with 40 wt% $Fe(PTS)_3$ oxidant completely formed a thin film on acetic acid-catalyzed APS-SAM surface while with 20 wt% $Fe(PTS)_3$ did not at all. It means that the oxidant can be uniformly coated on acetic acid-catalyzed APS-SAM surface at the 40 wt% concentration, which gives rise to the uniform growth of PEDOT thin film on it.