• Title/Summary/Keyword: Polymer support

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Preparation of electro-catalysts supported on the bimodal porous carbon for polymer electrolyte fuel cell (Bimodal 다공성 탄소지지체에 담지된 고분자전해질연료전지용 전극촉매 제조)

  • Hwang, So-hee;Park, Gu-Gon;Yim, Sung-Dae;Park, Seok-Hee;Kim, Han-Sung;Yang, Tae-Hyun;Kim, Chang-Soo
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.652-655
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    • 2009
  • The bimodal porous carbons were synthesized by using imprinting method with templates of SBA-15 particle and silica sphere and applied as supporting materials for the electro-catalyst of polymer electrolyte fuel cell (PEFC). The silica spheres with diameter size of 100 nm and SBA-15 particle having 200 nm -250 nm diameter and 700 nm -900 nm length were synthesized in this work. The bimodal porous carbons (S100) were prepared by using the silica spheres and SBA-15 as templates and mesophase pitch as a carbon source. The PtRu nanoparticle of ca. 1.9 nm were supported on the bimodal porous carbon support and the resulting PtRu/S100 catalysts was tested by the cyclic voltammetry. The use of bimodal porous carbon showed in comparable electro-catalytic activities with commercial catalyst. Though unclear effects of bimodal porosity of supports could be obtained in the scope of this study, morphological advantage in electrical conductivity can be considered on the electro-catalytic activity.

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Nanoporous Membrane with Ultrahigh Selectivity and Flux Suitable for Filtration of Viruses

  • Yang, Seung-Yun;Ryu In-Cheol;Jang, Sung-Key;Kim, Jin-Kon;Russell Thomas P.
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.313-313
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    • 2006
  • In this study, we describe a new double layered nanoporous membrane suitable for virus filtration. One layer is an 80 nm thick film having cylindrical pores with diameters of 15 nm and a narrow pore size distribution. This layer is prepared by using a thin film of the mixture of a block copolymer and a homopolymer, and mainly acts to separate viruses. The support layer (${\sim}150\;microns\;thick$) is a conventional micro-filtration membrane with a broad pore size distribution. This asymmetric membrane showed very high selectivity and flux for the separation of human rhinovirus type 14 (HRV 14) which has a diameter of ${\sim}30\;nm$ and is a major pathogen of the common cold in humans.

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Use and advantage of Red algae fiber as reinforcement of Biocomposite (홍조류 섬유를 보강재로 사용한 바이오복합재료의 특성)

  • Lee, Min-Woo;Seo, Yung-Bum;Han, Seong-Ok
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2007.11a
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    • pp.93-102
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    • 2007
  • Biocomposite was organized with biodegradable polymer and natural fiber that has potential to be used as replacement for glass fiber reinforced polymer composite with the benefits of low cost, low density, acceptable specific strength, biodegradability, etc. Until now, non-wood fibers have been used as reinforcements of biocomposite which are all plant-based fibers. The present study focused on investigating the fabrication and characterization of biocomposite reinforced with red algae fiber. The bleached red algae fiber(BRAF) showed very similar crystallinity to the cellulose. It has high stability against thermal degradation (maximum thermal decomposition temperature of 359.3$^{\circ}C$) and thermal expansion. Biocomposites reinforced with BRAF have been fabricated by a compression molding method and their mechanical and thermal properties have been studied. The storage modulus and the thermomechanical stability of PBS matrix are markedly improved with reinforcing the BRAF. These results support that the red algae fiber can be used as an excellent reinforcement of biocomposites as "green-composite" or "eco-composite".

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Evaluation of interaction between organic solutes and a membrane polymer by an inverse HPLC method

  • Kiso, Yoshiaki;Hosogi, Katsuya;Kamimoto, Yuki;Jung, Yong-Jun
    • Membrane and Water Treatment
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    • v.5 no.3
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    • pp.171-182
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    • 2014
  • Organic compounds are adsorbed on RO/NF membranes, and the adsorption may influence the rejection of organic compounds by the membranes. Because almost RO/NF membranes are composite membranes, the results obtained by adsorption experiment with using membrane pieces are unable to avoid the influence by the support membrane. In this work, the interaction between membrane polymer and organic solutes was examined by an inverse HPLC methodology. Poly (m-phenylenetrimesoylate), the constituent of skin layer of RO/NF membranes, was coated on silica gel particles and used as a stationary phase for HPLC. When water was used as a mobile phase, almost hydrophilic aliphatic compounds were not effectively adsorbed on the stationary phase, although hydrophobic compounds were slightly adsorbed. The results indicated that the hydrophilic aliphatic compounds are useful probe solutes to examine the molecular sieving effect of a membrane. When water was used as a mobile phase, the aromatic compounds were strongly retained, and therefore $CH_3CN/H_2O$ (30/70) was used as a mobile phase. It was revealed that the adsorption of aromatic compounds was controlled by stacking between solute and polymer and was hindered by non-planar structure and substituents.

The Laminating process for Single Substrate Flexible LCD

  • Bae, Kwang-Soo;Choi, Yoon-Seuk;Kim, Hak-Rin;Kim, Jae-Hoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1125-1128
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    • 2007
  • The laminating technique for developing flexible liquid crystal display was demonstrated by using a thin UV curable polymer film and a plastic substrate with patterned polymer wall structure. We adopted the rigid wall structure to provide a solid mechanical support for the stable molecular alignment of liquid crystals (LCs) in the device. The cover film was prepared to have an ability of aligning LC molecules by patterning a micro-groove structure using the soft-lithographic process. These two substrates can be assembled tightly by the laminating and one-step UV irradiation process because of the adhesive nature of the used UV curable polymers. Proposed method can be used to fabricate the flexible LC display with simplicity and also be applicable for a cost-effective roll-to-roll process.

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Polymers for Microfluidic Chips

  • Song Simon;Lee Kuen-Yong
    • Macromolecular Research
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    • v.14 no.2
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    • pp.121-128
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    • 2006
  • Microfluidic systems have attracted much research attention recently in the areas of genomics, proteomics, pharmaceutics, clinical diagnostics, and analytical biochemistry, as they provide miniaturized platforms for conventional analysis techniques. The microfluidic systems allow faster and cheaper analysis using much smaller amounts of sample and reagent than conventional methods. Polymers have recently found useful applications in microfluidic systems due to the wide range of available polymeric materials and the relative ease of chemical modification. This paper discusses the fundamentals of microfluidic systems and the roles, essential properties and various forms of polymers used as solid supports in microfluidic systems, based on the recent advances in the use of polymers for microfluidic chips.

Measurement of Viscoelastic Properties of Damping Materials using Beam Transfer Function Method (보 전달함수법을 이용한 제진재의 점탄성 특성 측정)

  • Kim, Seung-Joon;Lee, Je-Pil;Park, Jun-Hong;Jeon, Jin-Yong
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2008.04a
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    • pp.286-289
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    • 2008
  • Damping materials are widely used to reduce vibration or noise generation of structures. To understand their damping capability and for use in numerical simulations, their viscoelastic properties should be measured in the frequency range of interest. In this study, experimental setup is proposed to measure materials properties of very compliant polymer materials. The polymer materials used in this study are difficult to form into rod shapes, and typical resonance methods are not applicable. In the proposed measurement setup, the damping materials were modeled as a simple viscoelastic support at one end of the beam. Their properties were measured through analysis of their effects on the wave propagation characteristics of the beam structure.

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A dragonfly inspired flapping wing actuated by electro active polymers

  • Mukherjee, Sujoy;Ganguli, Ranjan
    • Smart Structures and Systems
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    • v.6 no.7
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    • pp.867-887
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    • 2010
  • An energy-based variational approach is used for structural dynamic modeling of the IPMC (Ionic Polymer Metal Composites) flapping wing. Dynamic characteristics of the wing are analyzed using numerical simulations. Starting with the initial design, critical parameters which have influence on the performance of the wing are identified through parametric studies. An optimization study is performed to obtain improved flapping actuation of the IPMC wing. It is shown that the optimization algorithm leads to a flapping wing with dimensions similar to the dragonfly Aeshna Multicolor wing. An unsteady aerodynamic model based on modified strip theory is used to obtain the aerodynamic forces. It is found that the IPMC wing generates sufficient lift to support its own weight and carry a small payload. It is therefore a potential candidate for flapping wing of micro air vehicles.

Technology of Electrical Barrier Material (전기차단성 소재 기술)

  • Shin, Eun-Mi
    • Elastomers and Composites
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    • v.46 no.1
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    • pp.22-28
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    • 2011
  • Various materials are used as electrical barrier materials, such as glass, insulating oil, gas, paper and polymer. These materials shut off electricity from conductor as a barrier and separate as well as support conductor from outside environment while using electrical equipment. Polymers are generally used for cable insulation material. Recently environmental regulation are reinforced and eco-friendly materials are in trend.

The Application of Perfluorinated Cation-exchange Membrane in the Catalytic Process (촉매공정에서 양이온 교환 분리막의 응용)

  • 변홍식
    • Membrane Journal
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    • v.2 no.1
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    • pp.49-58
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    • 1992
  • Functionalized organic polymers have been used as supports for heterogenized homogeneous catalytic process[1]. Sprcific advantages of using these resins as support reagents have been reviewed[2-4]. These include: -ease of by-product separation from the main reaction product usuallyby simple filtration. -prevention of intermolecular reaction of reactive species or functional groups by simulating high dilution conditions[5]. -utility of the "fish-hook" principle in which a minor component in fished out of a large excess substrate by the insoluble polymer[6]. -the possibility of reusing recovered reagents as well as eliminating the use of volatile or noxious substances[7]. Catalysis by ion-exchange membranes is perhaps one of the latest examples of the use of a polymer-supported species. Conceptually, catalysts on membrane supports offer several possible advantages over traditional powder type systems. They are: (1) Membranes immobilize the catalyst, preventing agglomeration. (2) Filtration is unnecessary for the catalyst separation and so complete catalyst recovery is facilitated. (3) Catalytyic and separation processes can be combined, allowing membrane supported catalysts for the continous flow reactors. reactors.

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