• Title/Summary/Keyword: Polymer stabilization

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Direct Tooth Restoration,State-of-Art : II (Composite Resin Restoration의 최신경향)

  • Park, Jin-Sun
    • Journal of the Korean Academy of Esthetic Dentistry
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    • v.10 no.1
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    • pp.16-27
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    • 2001
  • Composite resin have very important roles as a esthetic fillng material. Today we are confusing by a numerous number of the polymer options in the market. Are there any complications such as tooth sensitivity? Do they have stabilization in the long term aspect? These are the reasons why many dentists don't use composite resin in my country. But the problems can be overcome by choosing the best suited materials and meticulous clinical procedures. So that we are able to expand our clinical boundary. I would like to introduce the clinical techniques of Dr.Gordon Christensen in Utah, and overall clinical cases under the base of CRA newsletter.

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A Study on Preparation of Industrial Polyaluminium Sulfate (공업용 포리황산알미늄의 제조에 관한 연구)

  • 육창규;이내우
    • Journal of Environmental Science International
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    • v.5 no.2
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    • pp.203-210
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    • 1996
  • To improve coagulation characteristics and to reduce dossage of chemicals in watertreatment, polyaluminium sulfate was manufactured by reaction of polymerization between aluminium sulfate and sodium aluminate. As the results of affirmation and performance test, the yield of product was about 24% from molecular cut on levels by ultrafilteration method. The type of molecular is nearly affirmated as a kind of complex like AIm(OH)n(3m-n)+ from Scanning Electron Microscopy (S.E.M.) and X-ray diffraction test. Since the synthesized polymer was supposed to be quasi, further study for stabilization was required.

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The Steric Repulsion Properties of Polyethylene Oxide

  • Jeon, Sang Il;Joseph D. Andrade
    • Bulletin of the Korean Chemical Society
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    • v.13 no.3
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    • pp.245-248
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    • 1992
  • Polyethylene oxide (PEO) surfaces are recognized as having an effective steric stabilization character. A theoretical scaling analysis involves the osmotic and elastic coefficients of the polymer as a function of molecular weight, in a good solvent. The calculated results show that PEO in water may exhibit the greatest flexibility among water soluble polymers, probably due to its lowest elastic contribution.

Enhancement of Electrocatalytic Activity upon the Addition of Single Wall Carbon Nanotube to the Redox-hydrogel-based Glucose Sensor

  • Kim, Suk-Joon;Quan, Yuzhong;Ha, Eunhyeon;Shin, Woonsup
    • Journal of Electrochemical Science and Technology
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    • v.12 no.1
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    • pp.33-37
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    • 2021
  • In electrochemical glucose sensing, the enhancement of the sensitivity and the response time is essential in developing stable and reliable sensors, especially for continuous glucose monitoring. We developed a method to increase the sensitivity and to shorten the response time for the sensing upon the appropriate addition of single wall carbon nanotube onto the osmium polymer-based hydrogel electrode. Also, the background stabilization is dramatically enhanced.

Study on Electric characteristics of Optically Compensated Bend formed initially bend state by Reactive Mesogen monomer (RM 단분자를 이용한 초기 밴드 상태 OCB 셀의 전기적 특성 연구)

  • Jeon, Eun-Jeong;Kim, Seong-Su;Lim, Young-Jin;Lee, Myoung-Hoon;Lee, Seung-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.04a
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    • pp.49-50
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    • 2008
  • OCB mode has advantages such as fast response time and wide viewing angle. But it has inevitable shortcoming which initial splay state must be changed to bend state. To overcoming this problem, OCB cell filled LC with RM monomer was cured by UV when voltage applied. Through previously mentioned methods, even if electric field is none, bend state was made by stabilized LC director. In this paper, we investigated the electric characteristics of polymer stabilized OCB mode.

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Temperature Stabilization of Group Index in Silicon Slotted Photonic Crystal Waveguides

  • Aghababaeian, Hassan;Vadjed-Samiei, Mohammad-Hashem;Granpayeh, Nosrat
    • Journal of the Optical Society of Korea
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    • v.15 no.4
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    • pp.398-402
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    • 2011
  • In this paper, we have proposed a principle to design wideband, low dispersion and temperature stabilized slow light structure in slotted photonic crystal waveguide (SPCW). The infiltration of the silicon photonic crystal with polymer will enhance the slow light and increase the group index, whereas the different signs of thermo-optic coefficients of polymer and silicon make the proposed structure stable on temperature variation over $60^{\circ}C$ and improves the group index-bandwidth products of the designed structure. The SPCW structure is modified to maximize the slow light effect and minimize the dependence of the group index and hence the group velocity dispersion to temperature.

Epoxidized Polybutadiene as a Thermal Stabilizer for Poly(3-hydroxybutyrate). II. Thermal Stabilization of Poly(3-hydroxybutyrate) by Epoxidized Polybutadiene

  • Choi, Ju-Yol;Lee, Jong-Keun;You, Young;Park, Won-Ho
    • Fibers and Polymers
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    • v.4 no.4
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    • pp.195-198
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    • 2003
  • Epoxidized polybutadiene (EPB) was prepared by polybutadiene (PB) with m-chloroperbenzoic acid (MCPBA) in homogeneous solution. EPB was blended with poly(3-hydroxybutyrate) (PHB) up to 30 wt% by solution-precipitation procedure. The thermal decomposition of PHB/EPB blends was studied by thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and differential thermal analysis (DTA). The thermograms of PHB/EPB blends contained a two-step degradation process, while that of pure PHB sample exhibited only one-step degradation process. This degradation behavior of PHB/EPB blends, which have a higher thermal stability as measured by maximum decomposition temperature and residual weight, is probably due to crosslinking reactions of the epoxide groups in the EPB component with the carboxyl chain ends of PHB fragments during the degradation process, and the occurrence of such reactions can be assigned to the exothermic peaks in their DTA thermograms.

The Effect of Ions on Thermal Behaviors of Water in Poly(acrylic acid)/Water Mixtures (폴리아크릴산/$H_2O$ 혼합물에서 $H_2O$ 열적 거동에 미치는 이온의 영향)

  • Guan, Lan;Xu, Hongyan;Huang, Dinghai
    • Polymer(Korea)
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    • v.34 no.4
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    • pp.386-389
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    • 2010
  • Thermal behaviors of water in the poly(acrylic acid) (PAA)/water mixtures with 0.1 M NaCl, HCl, and NaOH were investigated by DSC. It showed that adding ions in the mixtures affected the crystallization of water evidently. Compared with the PAA/water mixtures, the $T_m$ of freezable bound water in the mixtures with ions moved to lower values and varied with different cations and anions, due to the stabilization or destabilization of the hydrogen-bonding hydration between polymers and water molecules through ionic hydration. The content of non-freezable bound water in the non-crystalline phase of the PAA/water mixtures with ions was not constant, it increased with total water content gradually, owing to the more binding sites created by ions. The ions could change the distribution of different states of water in the polymer aqueous solutions evidently.

Glass Transition Temperature of Poly(methyl methacrylate) Obtained with Ferrocene-Based Diimine Pd(II) Catalyst (Ferrocene-Based Diimine Pd(II) 촉매로 얻은 폴리(메틸메타크릴레이트)의 유리전이온도)

  • 박태학;이동호;김태정;박동규
    • Polymer(Korea)
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    • v.26 no.3
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    • pp.410-414
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    • 2002
  • The late transition Pd catalyst of low oxophilicity that has ferrocene -based diimine ligand for stabilization of center metal had been synthesized and applied for the polymerization of methyl methacrylate (MMA). In the presence of triisobutylaluminium (TIBA) for impurity scavenger, the effects of polymerization temperature and [TIBA]/[Pd] mole ratio on the yield and glass transition temperature ($T_g$) of PMMA had been examined. For 40~$50^{\circ}C$ of polymerization temperature and 2000~3000 of [TIBA]/[Pd] mole ratio, higher polymer yields were obtained. It was observed that ($T_g$) of PMMA is almost independent to the polymerization temperature but influenced by the [TIBA]/[Pd] mole ratio. With the examination of($T_g$) of PMMA with the structure of polymer, it had been found that T$_{g}$ of PMMA exhibits a linear relationship with the isotacticity of polymer.r.

Synthesis of Well-Defined Block Copolymer Dispersants with (2-Dimethylamino)ethyl Methacrylate and Oligo(ethylene oxide)methyl Ether Methacrylate via ATRP for Dispersing Copper Phthalocyanine Pigment (Copper Phthalocyanine Pigment의 분산을 위한 (2-Dimethylamino)ethyl Methacrylate와 Oligo(ethylene oxide)methyl Ether Methacrylate를 포함하는 잘 규정된 블록 공중합체형 분산제의 원자 이동 라디칼 중합을 이용한 합성)

  • Kim, Eun-Hee;Kim, Bong-Soo;Jung, Ki-Suk;Kim, Jin-Goo;Paik, Hyun-Jong
    • Polymer(Korea)
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    • v.36 no.1
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    • pp.104-110
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    • 2012
  • The dispersion of pigment particles is important because it is capable of increasing the color strength, contrast, and transmittance of color-LCD products. Pigment dispersion properties are very important factors for the quality of LCD color filters. The chemical structure of polymeric dispersants for pigment is important to improve dispersion stability and prevent aggregation or flocculation of pigment in organic or aqueous systems. Polymeric dispersants should contain both anchoring group that interacts with pigment surface and stabilizing group that provides steric stabilization. Moreover, the molecular weight and composition of block copolymer have the an effect on pigment dispersion. In this study, adequate dispersants, block copolymers containing (2-dimethylamino)ethyl methacrylate as anchoring group and oligo(ethylene oxide)methyl ether methacrylate as a stabilizing group were designed and synthesized by atom transfer radical polymerization in order to prepare well-defined structure, molecular weight and composition.