• Title/Summary/Keyword: Polymer membrane

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A Study on Examination of Application in Waste Filled Land and Performance Evaluation as Waterproofing Material by the Spray Water-Soluble Rubber Asphalt (뿜칠형 수용성 고무화 아스팔트 차수재의 성능평가 및 폐기물 매립지 적용성 검토에 관한 연구)

  • 오상근;김형무;정문정;최은수
    • Journal of the Korea Institute of Building Construction
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    • v.1 no.2
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    • pp.165-173
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    • 2001
  • This study examinated the application in construction field and the development of waterproofing material system by the spray water-soluble rubber asphalt to solve the problems of synthetic polymer sheet and gio membrane(A mat sheet of Bentonite) that had been used domestic waterproofing material in advance. As the result of study, characters of study water-soluble rudder asphalt are the follows: 1) The amount of water absorption was '0.06'g and the seepage quality was '0'g in result. 2) The tensile strength was about 30.7kgf/$\textrm{cm}^2 and the elongation was about 72.4% in result. 3) After reliance of temperature test had been ended, the tensile strength was about 72.4kgf/$\textrm{cm}^2 in low temperature and about 30.7kgf/$\textrm{cm}^2 in normal temperature. 4) After acid and alkaline treatment had been ended, the tensile strength was about 19.7kgf/$\textrm{cm}^2$ and about 21.9kgf/$\textrm{cm}^2 in result. 5) After chlorine ion treatment had been ended, the tensile strength was 28.5kgf/$\textrm{cm}^2$ and the elongation was 250% in result. 6) The impact performance was subsided at 1.5m height. 7) After promotion weathering had been ended, the tensile and elongation was about 26.0kgf/$\textrm{cm}^2, 214% in result. So, this study can propose the spray water-soluble rubber asphalt to satisfy the and durability of waste filled land.

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Characteristics of Fluorine-Doped Tin Oxide Film Coated on SUS 316 Bipolar Plates for PEMFCs (ECR-MOCVD를 이용하여 연료 전지 분리판에 코팅된 FTO막의 특성 연구)

  • Park, Ji-Hun;Hudaya, C.;Jeon, Bup-Ju;Byun, Dong-Jin;Lee, Joong-Kee
    • Journal of Hydrogen and New Energy
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    • v.22 no.3
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    • pp.283-291
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    • 2011
  • Polymer electrolyte membrane fuel cells (PEMFCs) use the bipolar plate of various materials between electrolyte and contact electrode for the stable hydrogen ion exchange activation. The bipolar plate of various materials has representatively graphite and stainless steel. Specially, stainless steels have advantage for low cost and high product rate. In this study, SUS 316 was effectively coated with 600 nm thick F-doped tin oxide (SnOx:F) by electron cyclotron resonance-metal organic chemical vapor deposition and investigated in simulated fuel cell bipolar plates. The results showed that an F-doped tin oxide (SnOx:F) coating enhanced the corrosion resistance of the alloys in fuel cell bipolar plates, though the substrate steel has a significant influence on the behavior of the coating. Coating SUS 316 for fuel cell bipolar plates steel further improved the already excellent corrosion resistance of this material. After coating, the increased ICR values of the coated steels compared to those of the fresh steels. The SnOx:F coating seems to add an additional resistance to the native air-formed film on these stainless steels.

Commercializing Technology Development of Bipolar Plates for Polymer Electrolyte Membrane Fuel Cell (고분자연료전지용 분리판 상용화 기술개발)

  • Kim, Jeong-Heon
    • Journal of Hydrogen and New Energy
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    • v.22 no.3
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    • pp.409-414
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    • 2011
  • To promote the industry of PEMFC, the commercialization of its parts especially bipolar plate is needed. The bipolar plate is one of key parts for PEMFC, which occupies cost portion of 5~8% in the system. To replace the bipolar plate of machined graphite highly costly, the stamped thin matal or the molded carbon composite has been developed. According to the merits and demerits of each material and its forming process, the stamped metallic plate has been considered to the bipolar plate of PEMFC for automotive, and on the other hand, the molded composite plate has been considered to one for building applications. Hankook Tire Co., Ltd. has developed the carbon composite material and the manufacturing process for the bipolar plates. The developed bipolar plates were proved to be fully applicable to PEMFC of building applications in characteristics and performance, and so government strategic project to develop the mass-production technology for bipolar plates was started and is being conducted by the company. Through the government project for obtaining both the commercialization technology and production capacity for the bipolar plates, the price and the performance of domestic PEMFCs are expected to become competitive in international market.

Analysis of Homogenized Laser Beam Display by a Polymeric Stretchable Diffuser (스트레쳐블 폴리머 디퓨저를 이용한 균질 레이저 디스플레이 해석)

  • Lee, Jae-Won;Lee, Seon-Bong;Choi, Hae-Woon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.1
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    • pp.1-7
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    • 2014
  • A stretchable polymeric membrane shaped diffuser was used to homogenize the coherent laser beam. The developed RGB module was used to focus and defocus test by beam combiners. Average oscillation frequency was set at 180Hz~300Hz and it resulted in the best homogenization effect in visual range. The blue laser module turned out to be the worst case for the transmission and primary reason is believed to be the short length of irradiated laser beam. The developed system removed the speckling and the brightness was decreased by 10 ~ 20% for the RGB laser. Overall the brightness was decreased by 13% and homogenity with respect to the temporal axis was improved from 30fs to 110fs.

A Study on the Safety Performance Evaluation Method of Blowers for 1kW Class Stationary Fuel Cell System (1kW급 건물용 연료전지시스템 블로워의 안전성능 평가방법에 관한 연구)

  • Lee, Jungwoon;Seo, Wonseok;Kim, Younggyu
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.127.2-127.2
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    • 2010
  • 우리나라는 기후변화 대응을 준비하기위해 2008년도에 수립한'국가에너지기본계획(2008-2030)'에 따라 2030년까지 신재생에너지 비중을 2.4%에서 11%까지 달성을 목표로 정하고 신재생에너지 분야를 성장시키기 위해 국가기술개발 및 산업화 전략을 수립해 추진하고 있다. 이에 발맞추어 건물용 연료전지시스템의 경우, 2006년도부터 1kW급 가정용 연료전지시스템 모니터링 사업의 일환으로 3년간 210대가 도시가스사 및 지자체 등을 중심으로 설치되어 운전되어지고 있다. 특히, 2010년부터 시범보급사업이 추진되어 올해 200대를 시작으로 2011년에 300대, 2012년에 500대가 일반가정에 보급되어질 예정이다. 하지만 현재 6천만원인 연료전지시스템 가격을 실제 보급가능한 가격인 5백만원 이하로 저감시키는 것이 현 시점에서 가장 시급한 문제로 대두되어지고 있는 실정이다. 본 연구에서는 그린홈 보급확대를 위한 건물용 연료전지의 보조기기인 블로워의 가격저감을 위한 연구의 일환으로 블로워의 안전성능 평가방법을 개발하여 보조기기의 가격저감 및 안전성을 확보하고자 한다. 1kW급 건물용 연료전지시스템의 여러 블로워 중 도시가스용 연료승압 블로워, 선택산화 공기 블로워, 버너 공기 블로워 및 캐소드 공기 블로워의 안전성능 평가방법을 제시함으로서, 국내 블로워 제조사의 설계방향을 제시하고 연료전지시스템의 안전성을 확인하고자 한다. 특히, 내구성, 기밀, 가혹조건시험 및 소음, 진동, 습도, 온도와 같은 내주위환경시험 등의 평가결과를 제조사에 feedback하여 안전성능 개선에 이바지하고자 한다.

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A Comparison Study of CFD Analysis and Flow Visualization on Behavior of Liquid Water in Cathode Channels of PEM Fuel Cells (PEM 연료전지 공기극 유로에서 물의 거동에 대한 CFD 해석과 가시화 실험의 비교 연구)

  • Kim, Hyun-Il;Nam, Jin-Hyun;Shin, Dong-Hoon;Chung, Tae-Yong;Kim, Young-Gyu;Seo, Won-Seok;Lee, Jung-Woon
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2008.04a
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    • pp.101-108
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    • 2008
  • Polymer electrolyte membrane (PEM) fuel cells are promising power generation devices which are ideal for residential and automobile applications, thanks to their fast transient characteristics. However, liquid water produced in PEM fuel cells should be properly managed to enhance the performances and durabilities of the cells. In this study, a visualization experiment was conducted to investigate the flow behavior of water droplets in cathode channels. The visualization experiment was done with four different model flow channels which were made by varying the material (Acrylic and Teflon) and the channel width (1 mm and 2 mm). Acrylic is hydrophilic (contact angle is about $80^{\circ}$) while Teflon is hydrophobic (contact angle is about $120^{\circ}$). A computational fluid dynamics (CFD) analysis was also performed to compare the observed and the simulated two-phase water/air flow characteristics in cathode channels. The computational models were made to be consistent with the geometries and surface properties of the model flow channels. Both the experimental and numerical results showed that the Teflon cathode channel with 1 mm width has the best water management performance among four model flow channels considered. A close correlation was found between the experimental visualization results and the numerical CFD simulation results.

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The Preparation of Mask-pack Sheet Blended with Styela clava tunics and Natural Polymer (미더덕껍질과 천연고분자 혼합물을 이용한 마스크팩시트의 제조방법)

  • Yun, Woobin;Lee, Yechan;Kim, Dasom;Kim, Jieun;Sung, Jieun;Lee, Hyunah;Son, Hongju;Hwang, Daeyoun;Jung, Youngjin
    • Textile Coloration and Finishing
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    • v.29 no.1
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    • pp.45-54
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    • 2017
  • Ultraviolet radiation have much influenced with a deep wrinkles, roughness, laxity of skin damage and pigmentation through oxidative stress and oxidative photo-damage. This study investigates the functional properties of hydrogel facial mask sheets made from agar, Styela clava tunics and Broussonetia papyrifera tunics. The skin of S. clava is covered with a hard cellulose containing glycoprotein, glycosaminoglycan and chondroitin sulfate. B. papyrifera is better known as Paper mulberry. It contains kazinol which serves as a tyrosinase inhibitor and skin whitening agent. The tensile strength of facial mask sheet was measured by universal testing machine, and the water absorption and moisture permeability of facial mask sheet were measured by dryer. Additionally, the DPPH assay and MTT assay were conducted for anti-oxidative activity and cytotoxicity of facial mask sheet. The whitening effect of the facial mask sheet was measured by tyrosinase inhibitor assay. These tests showed that the three ingredients are suitable cosmetic materials. The results reveal that they produce a high quality hydrogel facial mask sheet when the membrane contains 1%(W/V) of agar, 0.1%(W/V) of B. papyrifera tunics and 0.05%(W/V) of S. clava tunics.

Preparation and Electrical Properties of Carbon Paper Using Chopped Carbon Fiber (탄소 단섬유를 이용한 탄소종이 제조 및 전기전도도 특성)

  • Lee, Ji-Han;Yoo, Yoon-Jong;Park, Soo-Jin
    • Applied Chemistry for Engineering
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    • v.24 no.2
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    • pp.121-125
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    • 2013
  • In this work, we prepared the carbon paper from chopped carbon fibers using a gas diffusion matrix in polymer electrolyte membrane fuel cells by wet processing. The process of making carbon paper using wet processing is consisted of the three steps involving the dispersion of chopped carbon fibers, the preparation of the carbon fiber web, the impregnating of phenol resin. This work was focused on finding the optimal surfactant to make the carbon paper with 2D orientation of carbon fibers by investigating the dispersion state of carbon fibers in different dispersion solutions. Furthermore, the effect of phenol resin and carbon black contents on properties of electric conductivity was analyzed. As a result, it is confirmed that the carbon fiber was well dispersed when using sodium dodecyl sulfate as a surfactant, and the carbon paper with 8 wt% of phenol and 5 wt% of carbon black contents showed the most excellent electrical property.

Control of Molecular Weight, Stereochemistry and Higher Order Structure of Siloxane-containing Polymers and Their Functional Design

  • Yusuke Kawakami;Yuning Li;Yang Liu;Makoto Seino;Chitsakon Pakjamsai;Motoi Oishi;Cho, Yeong-Bee;Ichiro Imae
    • Macromolecular Research
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    • v.12 no.2
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    • pp.156-171
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    • 2004
  • We describe the precision synthesis schemes of siloxane-containing polymers, i.e., the control of their molecular weight, stereoregularity, and higher-order structures. First, we found a new catalytic dehydrocoupling reaction of water with bis(dimethylsilyl)benzene to give poly(phenylene-disiloxane). Together with this reaction, we applied hetero-condensations to the synthesis of thermally stable poly(arylene-siloxane)s. The dehydrocoupling reaction was applied to the synthesis of syndiotactic poly(methylphenylsiloxane) and poly(silsesquioxane)s, which we also prepared by hydrolysis and deaminative condensation reactions. We discuss the tendency for loop formation to occur in the synthesis of poly(silsesquioxane) by hydrolysis, and provide comments on the design of functionality of the polymers produced. By taking advantage of the low energy barrier to rotation in the silicon-oxygen bond, we designed selective oxygen-permeable membrane materials and liquid crystalline materials. The low surface free energy of siloxane-containing systems allows surface modification of a blend film and the design of holographic grating materials.

Experimental Study of Freeze and Thaw Effect on Gas Diffusion Layer Using XRay Tomography (X-선 단층 촬영을 이용한 동결과 융해가 기체확산층에 미치는 영향에 대한 실험적 연구)

  • Je, Jun-Ho;Kim, Jong-Rok;Doh, Sung-Woo;Kim, Moo-Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.5
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    • pp.487-490
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    • 2011
  • We used X-ray tomography to carry out an experimental study to visualize the effect of freeze and thaw cycles on the gas diffusion layer (GDL) in a polymer electrolyte membrane fuel cell (PEMFC). A PEMFC has freeze and thaw cycles if the fuel cell is operating at a below-freezing ambient temperature. The cycle permanently deforms the fuel-cell capillary structures and reduces the ability of the cell to generate electric power and also reduces its service life. The GDL is the thickest capillary layer in the fuel cell, so it experiences the most deformation. The X-ray tomography facility at the Pohang Accelerator Laboratory was used to observe the structural changes in GDLs induced by a freeze and thaw cycle. We discuss the effects of these structural changes on the power production and service life of PEMFCs.